Volume 40 Issue 6
Dec.  2023
Turn off MathJax
Article Contents
XIA Yulei, LAN Jianping, YAO Wei.The development and characterization of a high efficiency pyrimidine derivatives corrosion inhibitor for acid jobs[J]. Drilling Fluid & Completion Fluid,2023, 40(6):827-834 doi: 10.12358/j.issn.1001-5620.2023.06.018
Citation: XIA Yulei, LAN Jianping, YAO Wei.The development and characterization of a high efficiency pyrimidine derivatives corrosion inhibitor for acid jobs[J]. Drilling Fluid & Completion Fluid,2023, 40(6):827-834 doi: 10.12358/j.issn.1001-5620.2023.06.018

The Development and Characterization of a High Efficiency Pyrimidine Derivatives Corrosion Inhibitor for Acid Jobs

doi: 10.12358/j.issn.1001-5620.2023.06.018
  • Received Date: 2023-07-10
  • Rev Recd Date: 2023-08-22
  • Publish Date: 2023-12-30
  • Using the environmentally friendly biomaterial 4-amino-6-hydroxy-2-mercaptopyrimidine (AMSN) and the anhydrous N,N-dimethylformamide (DMF), a high performance pyrimidine derivative ASMF, which is a corrosion inhibitor for acid job, has been developed through one-step reaction. Characterization by IR spectroscopy and element analysis show that the reaction gave high purity product. Studies on the factors affecting the yield of ASMF show that the optimum molar ratio of AMSN and DMF is 1:1, the reaction temperature should not be higher than 170 °C, and the reaction time should be at least 4 h. The yield of ASMF is relatively high under these conditions. An ASMF sample produced in an experimental production showed excellent corrosion inhibitive capacity in high concentration (>20%) acid solutions, and it functioned at temperatures as high as 170 °C. ASMF shows superior corrosion inhibitive performance even at concentrations less than 0.2%. The electrochemical polarization curve of ASMF shows that ASMF can effectively inhibit the electrode reactions taken place at the cathode and anode during a corrosion process, and it is a mixed corrosion inhibitor which shows cathode inhibition property. Impedance test results show that ASMF has good corrosion inhibition efficiency, at a concentration of 0.2%, the corrosion inhibition efficiency of ASMF is 99.85%. Core damage evaluation test results show that ASMF shows only weak damage to the permeability of cores flooded with the ASMF solution, and ASMF is environmentally friendly. It can be concluded that the product developed is an environmentally friendly high performance pyrimidine derivative corrosion inhibitor for acid jobs

     

  • loading
  • [1]
    成涛,刘鹏超,欧志鹏,等. 累积工况下CO2对稠油热采水泥石的修复作用[J]. 钻井液与完井液,2021,38(5):628-633.

    CHENG Tao, LIU Pengchao, OU Zhipeng, et al. Remediation of set cement in heavy oil thermal production wells with CO2 under cumulative working conditions[J]. Drilling Fluid & Completion Fluid, 2021, 38(5):628-633.
    [2]
    HARUNA K, OBOT I B, ANKAH N K, et al. Gelatin: a green corrosion inhibitor for carbon steel in oil well acidizing environment[J]. Journal of Molecular Liquids, 2018, 264:515-525. doi: 10.1016/j.molliq.2018.05.058
    [3]
    OLAJIRE A A. Corrosion inhibition of offshore oil and gas production facilities using organic compound inhibitors-A review[J]. Journal of Molecular Liquids, 2017, 248:775-808. doi: 10.1016/j.molliq.2017.10.097
    [4]
    果常旺,李善建,崔国涛,等. 一种酸化缓蚀剂的合成与性能评价[J]. 化工技术与开发,2022,51(09):1-5. doi: 10.3969/j.issn.1671-9905.2022.09.001

    GUO Changwang, LI Shanjian, CUI Guotao, et al. Synthesis and performance evaluation of an acidizing corrosion inhib-itor[J]. Technology & Development of Chemical Industry, 2022, 51(09):1-5. doi: 10.3969/j.issn.1671-9905.2022.09.001
    [5]
    王国瑞,刘峥,刘二喜,等. 绿色缓蚀剂研究现状与展望[J]. 腐蚀与防护,2009,30(10):732-737.

    WANG Guorui, LIU Zheng, LIU Erxi, et al. Research and development status of the environmental corrosion inhibitors[J]. Corrosion & Protection, 2009, 30(10):732-737.
    [6]
    侯保山. 新型高效嘧啶类缓蚀剂的开发、缓蚀性能及理论计算[D]. 武汉: 华中科技大学, 2021.

    HOU Baoshan. Development, corrosion inhibition performance and theoretical calculation of novel high-efficient pyrimidine inhibitors[D]. Wuhan: Huazhong University of Science and Technology, 2021.
    [7]
    SINGH P, SINGH A, QURAISHI M A. Thiopyrimidine derivatives as new and effective corrosion inhibitors for mild steel in hydrochloric acid: Electrochemical and quantum chemical studies[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016, 60:588-601. doi: 10.1016/j.jtice.2015.10.033
    [8]
    涂胜,汤琪,王孝华,等. 嘧啶硫酮缓蚀剂的合成及其性能评价[J]. 西南大学学报(自然科学版),2018,40(11):168-174. doi: 10.13718/j.cnki.xdzk.2018.11.022

    TU Sheng, TANG Qi, WANG Xiaohua, et al. Synthesis of pyrimidin thione and evaluation of its corrosion inhibition[J]. Journal of Southwest University (Natural Science Edition), 2018, 40(11):168-174. doi: 10.13718/j.cnki.xdzk.2018.11.022
    [9]
    范雨. 一种硝酸缓蚀剂合成及性能评价[D]. 西南石油大学, 2014.

    FAN Yu. Synthesis and performance evaluation of a nitric acid corrosion inhibitor[D]. Chengdu: Southwest Petroleum University, 2014.
    [10]
    REZNIK V S, AKAMSIN V D, KHODYREV Y P, et al. Mercaptopyrimidines as inhibitors of carbon dioxide corrosion of iron[J]. Corrosion science, 2008, 50(2):392-403. doi: 10.1016/j.corsci.2007.06.021
    [11]
    张兴德,原励,王川,等. 一种耐200 ℃ 高温缓蚀剂[J]. 钻井液与完井液,2020,37(5):664-669.

    ZHANG Xingde, YUAN Li, WANG Chuan, et al. A high temperature corrosion inhibitor for use at 200 ℃[J]. Drilling Fluid & Completion Fluid, 2020, 37(5):664-669.
    [12]
    OU H H, TRAN Q T P, LIN P H. A synergistic effect between gluconate and molybdate on corrosion inhibition of recirculating cooling water systems[J]. Corrosion Science, 2018, 133:231-239. doi: 10.1016/j.corsci.2018.01.014
    [13]
    HE X, MAO J, MA Q, et al. Corrosion inhibition of perimidine derivatives for mild steel in acidic media: electrochemical and computational studies[J]. Journal of Molecular Liquids, 2018, 269:260-268. doi: 10.1016/j.molliq.2018.08.021
    [14]
    EL FAYDY M, TOUIR R, TOUHAMI M E, et al. Corrosion inhibition performance of newly synthesized 5-alkoxymethyl-8-hydroxyquinoline derivatives for carbon steel in 1 M HCl solution: experimental, DFT and Monte Carlo simulation studies[J]. Physical Chemistry Chemical Physics, 2018, 20(30):20167-20187. doi: 10.1039/C8CP03226B
    [15]
    PAREEK S, JAIN D, HUSSAIN S, et al. A new insight into corrosion inhibition mechanism of copper in aerated 3.5 wt. % NaCl solution by eco-friendly Imidazopyrimidine Dye: experimental and theoretical approach[J]. Chemical Engineering Journal, 2019, 358:725-742. doi: 10.1016/j.cej.2018.08.079
    [16]
    EDWARDS H G M, JOHNSON A F, LAWSON E E. Structural determination of substituted mercaptothiadiazoles using FT-Raman and FT-IR spectroscopy[J]. Journal of molecular structure, 1995, 351(94):51-63.
    [17]
    李向红. 嘧啶衍生物对冷轧钢在 HCI 和 H2SO4 介质中的缓蚀性能及机理研究[D]. 云南大学, 2015.

    LI Xianghong. Inhibition effect and mechanism of pyrimidine derivatives on the corrosion of cold rolled steel in HCl and H2SO4 solutions[D]. Kunming: Yunnan University, 2015.
    [18]
    薛丹,张硕硕,朱明明,等. 一种新型高温酸化缓蚀剂的制备及性能[J]. 腐蚀与防护,2022,43(3):36-41. doi: 10.11973/fsyfh-202203006

    XUE Dan, ZHANG Shuoshuo, ZHU Mingming, et al. Preparation and properties of a new high-temperature acidified corrosion inhibitor[J]. Corrosion & Protection, 2022, 43(3):36-41. doi: 10.11973/fsyfh-202203006
    [19]
    仝方超,李善建,董晓军,等. 一种油田酸化用醛酮胺缓蚀剂的合成及缓蚀机理研究[J]. 西安石油大学学报(自然科学版),2015,30(4):87-90.

    TONG Fangchao, LI Shanjian, DONG Xiaojun, et al. Synthesis and Corrosion Inhibition Mechanism of an Aldehyde-Ketamine Corrosion Inhibitor for Oilfield Acidification[J]. Journal of Xi'an Shiyou University (Natural Science Edition), 2015, 30(4):87-90.
    [20]
    GUO L, ZHU S, ZHANG S. Experimental and theoretical studies of benzalkonium chloride as an inhibitor for carbon steel corrosion in sulfuric acid[J]. Journal of Industrial and Engineering Chemistry, 2015, 24:174-180. doi: 10.1016/j.jiec.2014.09.026
    [21]
    GITE V V, TATIYA P D, MARATHE R J, et al. Microencapsulation of quinoline as a corrosion inhibitor in polyurea microcapsules for application in anticorrosive PU coatings[J]. Progress in Organic Coatings, 2015, 83:11-18. doi: 10.1016/j.porgcoat.2015.01.021
    [22]
    SOLMAZ R, KARDAŞ G, ÇULHA M, et al. Investigation of adsorption and inhibitive effect of 2-mercaptothiazoline on corrosion of mild steel in hydrochloric acid media[J]. Electrochimica Acta, 2008, 53(20):5941-5952. doi: 10.1016/j.electacta.2008.03.055
    [23]
    曹楚南. 腐蚀电化学原理[M]. (第三版). 北京: 化学工业出版社, 2008: 165-165.

    CAO Chunan. Principles of electrochemistry of corrosion[M]. Beijing: Chemical Industry Press, 2008: 165-165.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(3)

    Article Metrics

    Article views (150) PDF downloads(46) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return