Treatment and use of Waste Drilling Fluid with Existing Solids Control Equipment
-
摘要: 为了达到环境保护要求,长庆钻井采用破胶-固液分离的技术,对废弃钻井液进行后期处理。针对常见破胶剂多为单一作用,破胶速度慢,效率低,自制一种复合型破胶剂CQPJ-1为一种破胶剂,其能够使黏土胶体和悬浮颗粒整体的电荷量减小,聚结稳定性下降,同时能够使高分子材料氧化分解,产生初级自由基,并引发连锁自动氧化反应,使分子量急剧降低。同时优选了一种分子量适中的高分子絮凝剂CQXN-1,它具有的阳离子和长分子链可将失稳的黏土颗粒包裹起来,形成的聚集体较无机絮凝剂所形成的絮凝聚集体更加紧密牢固,因而更有利于机械脱水。室内实验同时对双氧水、高锰酸钾、亚磷酸钠和CQPJ-1等破胶剂以及聚合氯化铝、聚合氯化铁、硫酸铝和CQXN-1等絮凝剂进行了对比评价。结果表明,通过调节废弃钻井液的pH值调整为6.0~6.5,加入2%破胶剂CQPJ-1,破胶3 h,最后加入0.15%絮凝剂CQXN-1,利用钻井队配备的离心机进行固液分离,选择离心机转速为2 200 r/min,分离效率和效果达到预期目标。处理后的液相污染指标大幅下降,重复利用配制钻井液后各项指标也符合钻井施工要求。Abstract: Waste drilling fluids in Changqing gas field are treated with gel-breaking and solid-liquid separation technologies to conform to the environment protection requirements. In gel-breaking the drilling fluids, a new gel-breaking agent, CQPJ-1, was developed to replace the single-purpose, slow and low-efficiency conventional gel-breaking agents. CQPJ-1 is able to reduce the quantity of electric charge of clay colloids and suspended particles, thereby decreasing the coagulation stability of the suspension system. By oxygenolysis, CQPJ-1 decomposes polymer materials, producing primary radicals and initiating a chain oxidation reaction, thereby dramatically reducing the molecular weight of polymer. CQXN-1, a cationic polymeric flocculant with moderate molecular weight, was selected to flocculate destabilized clay particles through its cationic group and long molecular chain, making the flocs much easier to mechanically dewater than flocs flocculated with inorganic flocculants. Laboratory evaluation has been conducted on the performance of gel-breaking agents, including H2O2, potassium permanganate, sodium phosphite and CQPJ-1, and the performance of flocculants such as poly aluminum chloride, poly ferric chloride, aluminum sulfate and CQXN-1. It was found that, using existing solids-control equipment, a waste drilling fluid with pH adjusted between 6.0-6.5, after treatment with 2%CQPJ-1 for 3 hours and then adding 0.15%CQXN-1, can be solid-liquid separated at 2,200 r/min. The separation efficiency and results have achieved the expected goal. Contamination index of the liquid phase from the treated waste drilling fluid was greatly reduced, and drilling fluids prepared with the liquid obtained had properties conforming to the requirements of drilling operation.
-
Key words:
- Environment protection /
- Waste drilling fluid /
- Gel breaking /
- Solid-liquid separation /
- Reuse /
- Changqing gas field
-
[1] 赖晓晴,楼一珊,孙金声,等. 废弃聚磺钻井液固液分离技术[J]. 钻井液与完井液,2010,27(1):71-74.LAI Xiaoqing, LOU Yishan,SUN Jinsheng,et al. Polysulfonate drilling fluid solid liquid separation technology of waste[J].Drilling Fluid & Completion Fluid,2010,27(1):71-74. [2] 赵雄虎,王风春. 废弃钻井液处理研究进展[J]. 钻井液与完井液,2004,21(2):43-47.ZHAO Xionghu,WANG Fengchun.Research progress of waste drilling fluid treatment[J]. Drilling Fluid & CompletionFluid,2004,21(2):43-47. [3] 罗跃,郑力军,王志龙,等.吐哈油田废钻井液脱稳固化技术研究[J]. 钻井液与完井液,2007,24(9):71-72.LUO Yue,ZHENG Lijun,WANG Zhilong,et al. Solidification treatment of waste drilling fluids in Tuha oilfield[J].Drilling Fluid & Completion Fluid,2007,24(5):71-72. [4] 李广环,吴文茹,黄达全,等. 废弃水基钻井液用新型破胶絮凝剂的研制与应用[J]. 钻井液与完井液, 2015,32(5):46-48.LI Guanghuan,WU Wenru,HUANG Daquan,et al. Development of new gel-breaking flocculant for waste water base drilling fluid treatment[J].Drilling Fluid & Completion Fluid,2015,32(5):46-48.
点击查看大图
计量
- 文章访问数: 686
- HTML全文浏览量: 189
- PDF下载量: 279
- 被引次数: 0