Study on Enhancing Borehole Wall Stability by Micro Emulsion
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摘要: 泥页岩微裂缝发育、封堵难度大,滤液在渗透压、毛细管力和化学势差等驱动力的作用下,会迅速进入地层深处,最终导致井壁失稳。研制了一种微乳液配方,通过粒度分布实验考察了微乳液的稳定性,并通过压力传递和页岩膨胀实验研究了其稳定井壁机理。所配制的微乳液具有良好的稳定性,在考察的静置时间内粒度保持稳定,虽稀释后液滴粒径略有增大,但当稀释倍数超过20倍后液滴粒径不再发生变化,微乳液还具有良好的抗温性,抗温达150℃。稀释后的微乳液液滴粒径中值在30 nm左右,能够进入泥页岩内部,而且在一定矿化度下会发生聚合形成大颗粒,当NaCl浓度增大到5.0%时纳米尺度的液滴已经消失,当CaCl2浓度超过0.2%时液滴粒径中值达数百纳米,并通过吸附聚结停留在孔道内部,从而提高封堵效果。接触角实验表明,该微乳液可以显著改变泥页岩的润湿性,使其亲水性转变为具有一定疏水性,微乳液还能够降低表面张力,加量2%为时表面张力降低到31.4 mN/m,因此其具有一定的抑制能力。制备的微乳液与现场钻井液具有良好的适用性,对钻井液流变性影响不明显,能够提高泥饼质量,改善钻井液的滤失性。Abstract: Mud shales have plenty of micro-fractures which are difficult to plug and seal. Mud filtrates infiltrate swiftly deep into the formation under the action of osmotic pressure, capillary force and differential chemical potential, causing the formation to become unstable. A micro emulsion has been developed. Measurement of the size distribution of the emulsion droplets showed that the micro emulsion was stable, and the droplet sizes remained stable during a certain period of time in laboratory experiment. The size of the emulsion droplet became slightly bigger after dilution. When the dilution factor reached 20, the size of the droplet did not change anymore. The micro emulsion also had good high temperature stability; it remained stable at 150℃. Diluted micro emulsion had median droplet size of about 30 nm, and was able to enter into shale formations. The droplets can coalesce to form droplets with bigger diameters at certain salinities. In micro emulsion containing 5% NaCl, droplets sized in nanometers disappeared. When the concentration of CaCl2 in the micro emulsion exceeded 0.2%, the median droplet size was several nanometers. These enlarged droplets can be adsorbed inside pores of fractures in mud shale formations and stay there, becoming coalesced, thereby improving the plugging performance of the micro emulsion. Contact angle measurement showed that the micro emulsion remarkably changed the wettability of shales, altering the wettability of the surface of shale from hydrophilicity to some hydrophobicity. In surface tension measurement, addition of 2% of the micro emulsion reduced the surface tension to 31.4 mN/m, indicating that the micro emulsion had some inhibitive capacity. The micro emulsion developed had good compatibility with drilling fluid used and showed only slight effect on the rheology of the drilling fluid. It also helped improve the quality of mud cake and the filtration property of drilling fluid.
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Key words:
- Borehole stabilization /
- Mud shale /
- Micro emulsion /
- Plugging /
- Inhibition /
- Droplet size distribution
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