Method of Evaluating Corrosion Rate of Formates to Casing and Tubing Strings and the Influencing Factors
-
摘要: 由于目前还没有关于甲酸盐腐蚀速率评价标准,借鉴国内外金属腐蚀速率评价方法,提出甲酸盐对石油钻完井用的套管/油管腐蚀速率评价方法。实验采用金属挂片失重法,使用CGF-Ⅱ高温高压静态腐蚀仪,研究了甲酸盐种类、甲酸盐生产工艺、pH值、钢材材质、密度、缓冲剂等因素对腐蚀速率的影响。结果表明,甲酸钠对TP140钢材腐蚀速率是甲酸钾的2倍多,因为甲酸钠中Cl元素含量(0.619%)大于甲酸钾(0.024 3%);由于生产工艺不同,甲酸钾A中S元素含量(0.18%)大于甲酸钾B(0.047 7%)与C(0.04 6%),因而前者的腐蚀速率远高于后2者;酸性条件下甲酸盐对钢材腐蚀程度较为严重,现场应用的甲酸盐盐水需使用碳酸钠/碳酸氢钠或碳酸钾/碳酸氢钾进行缓冲;TP140在甲酸钾盐水中的腐蚀速率是BG13Cr、JFE13Cr中腐蚀速率的20倍,表明甲酸钾对不锈钢的腐蚀速率远低于对碳钢的腐蚀速率;因为高浓度的HCOO-离子才对钢材腐蚀有一定保护作用,所以TP140钢材在1.20 g/cm3甲酸钾盐水中的腐蚀速率是1.40~1.57 g/cm3甲酸钾盐水的2倍多,因此在使用低密度甲酸盐体系时需加入缓蚀剂。上述实验结果为石油钻完井过程中使用甲酸盐水时的防腐工作提供了实验依据。Abstract: Standard method for evaluating the corrosion rate of formatesis not presently available. A method of evaluating the corrosion rate of formates to casing/tubing strings has been presented with an idea borrowed from the methods of evaluating the corrosion rate of metals. In laboratory experiment, metal coupon weight loss method and a CGF-II HTHP static corrosion tester were used to study the influencing factors such as the type of the formate, production technique, pH, steel material quality, density, and retarder etc. It has been found that using TP140 steel coupon, the corrosion rate of sodium formate was more than 2 times that of potassium formate, because the Cl content in sodium formate (0.619%) was greater than the Cl content in potassium formate (0.0243%). For potassium formate, different production processes resulted in different sulfur contents; potassium formate A contained 0.18% sulfur, far more than that of potassium formate B (0.0477%) and potassium formate C (0.046%), and thus, the corrosion rate of potassium formate A was much higher than that of the latter two. The corrosion of formate salts to steel is much severe under acidic conditions. Water solutions of formate salts taken from a well site needed to be buffered with sodium carbonate and sodium bicarbonateor potassium carbonate and potassium bicarbonate. The corrosion rate of TP140 steel in potassium formate solution was 20 times of the steel BG13Cr or JFE13Cr, indicating that potassium formate had lower corrosion rate to stainless steel than to carbon steel. Since high concentration of HCOO- is good for the protection of steel, the corrosion rate of TP140 steel in 1.20 g/cm3 potassium formate solution was more than 2 times of the corrosion rate of TP140 in potassium formation solution of 1.40-1.57 g/cm3. Thus, corrosion inhibitors should be used when low density formate muds are used. Based on these experimental data, the use of corrosion inhibition measures can be justifed when using formate drilling fluids.
-
Key words:
- Formate drilling fluid /
- Corrosion rate /
- Casing /
- Tubing
-
[1] HOWARD, SIV.Formate brines-compatibility with metals[J]. Report December, 2006. [2] LETH-OLSEN H. CO2 corrosion of steel in formate brines for well applications[C]//CORROSION 2004. NACE International, 2004. [3] LETH-OLSEN H. CO2 corrosion in bromide and formate well completion brines[C]//SPE international symposium on oilfield corrosion, Society of Petroleum Engineers, 2005. [4] 朱世东, 尹成先, 白真权, 等. 有机盐钻井完井液对套管油管钢腐蚀速率的影响[J]. 钻井液与完井液. 2008, 25(6):62-64.ZHU Shidong, YIN Chengxian, BAI Zhenquan, et al.The effect of organic salt drill-in fluid on the corrosion rate of casing and tubing steels[J]. Drilling Fluid & Completion Fluid, 2008, 25(6):62-64. [5] 金属和合金的腐蚀点蚀评定方法[S].GB/T 18590-2001. Corrosion of metals and alloys-evaluation of pitting corrosion[S].GB/T 18590-2001. [6] RP0775 N S. Preparation, installation, analysis, and interpretation of corrosion coupons in oilfield operations[J]. Houston, TX:NACE International, 2005. [7] 何茜. 甲酸钾市场及生产工艺浅析[J]. 广州化工, 2011, 39(6):191-193.HE Qian. Market and production technology of potassium formate[J]. Guangzhou Chemical Industry,2011,39(6):191-193. [8] 焦延滨. 甲酸钠生产工艺及优化[J]. 山东化工, 2015, 44(16):160-163.JIAO Yanbing. Process and optimization of sodium formateproduction[J]. Shandong Chemical Industry, 2015, 44(16):160-163. [9] 刘菊泉, 王洪福, 卢思华, 等. pH缓冲剂在酸性气田甲酸盐完井液中的应用[J]. 河北能源职业技术学院学报, 2012, 45(2):39-41.LIU Juquan, WANG Hongfu, LU Sihua, et al.The application of p h buffer in well completion fluid of formate brine in acid gas field[J]. Journal of Hebei Energy Institute of Vocationand Technology, 2012, 45(2):39-41.
点击查看大图
计量
- 文章访问数: 763
- HTML全文浏览量: 219
- PDF下载量: 396
- 被引次数: 0