Development and Performance of a Water-Based Drilling Fluid Suspending Agent Resistant to 230 ℃
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摘要: 为解决在高温/超高温环境下钻井液切力下降导致钻井液的沉降稳定性能及携岩能力降低，致使钻井液固相颗粒无法均匀分散及岩屑聚集这一问题，以AMPS（2-丙烯酰胺基-2-甲基丙磺酸），SAS（烯丙基磺酸钠），SSS（对苯乙烯磺酸钠）以及MBA（亚甲基双丙烯酰胺）为主要原料设计合成了一种四元抗温达到230 ℃的钻井液悬浮剂XFJ-3#。采用红外光谱、热重分析以及核磁共振H谱对XFJ-3#进行表征。结果表明，XFJ-3#为预期产物，600 ℃时失重仅为 60%。通过其性能评价可知，加量1%XFJ-3#的5%膨润土浆，经过230 ℃、10 d老化后，其切力保持率超过70%。悬浮剂XFJ-3#可以有效提升钻井液在超高温环境下长时间维持钻井液的沉降稳定性能。Abstract: In high-temperature and ultra-high-temperature drilling operations, the decrease in drilling fluid gel strengths causes the settling stability and the sand carrying capacity of the drilling fluid to reduce, which results in uneven dispersion of the solid particles and cuttings agglomeration in the drilling fluid. To address this problem, a quaternary polymer drilling fluid suspending agent, XFJ-3#, which exhibits temperature resistance up to 230 ℃, was designed and synthesized using AMPS (2-acrylamido-2-methylpropanesulfonic acid), SAS (sodium allylsulfonate), SSS (sodium p-styrenesulfonate) and MBA (methylene bisacrylamide) as the main raw materials. Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and 1H nuclear magnetic resonance spectroscopy (1H-NMR) were used to characterize XFJ-3#. The results show that XFJ-3# is the target product. XFJ-3# loses only 60% of its weight at 600 ℃. Performance evaluation results show that a 5% Bohai drilling clay slurry treated with 1%XFJ-3# retains more than 70% of its gel strengths after aging at 230 ℃ for 10 days. The suspending agent XFJ-3# can effectively improve the ability of a drilling fluid to maintain its settling stability for a long time under ultra-high temperature environments.
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表 1 XFJ-3#悬浮剂加量与膨润土浆性能变化
XFJ-3#/
%AV/
mPa·sPV/
mPa·sYP/
PaGel/
Pa/Pa0.50 21.0 7 14.0 9.0/11.0 0.75 19.5 6 13.5 10.0/12.0 1.00 17.0 11 6.0 3.0/12.0 1.50 22.0 10 12.0 10.0/14.0 2.00 14.0 10 4.0 1.0/9.5 3.00 20.0 10 10.0 10.0/35.0 4.00 21.0 9 12.0 14.5/35.0 注：老化条件为230 ℃×72 h。 
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[1] LI W L, GAO D L, YANG J, et al. Prediction of the borehole temperature profile in ultradeep drilling under ocean deepwater conditions[J]. Oil Drilling & Production Technology, 2020, 42(5): 558-563. [2] 秦紫涵. 攻关前沿技术 进军万米深地[N]. 中国石化报, 2023-06-19(05).QIN Zihan. Tackling cutting-edge technologies and advancing to a depth of 10000 meters[N]. China Petrochemical News, 2023-06-19(05). [3] WANG M H, HE L Q, ZHUO Y, et al. Practices and understandings on safe drilling technologies for 9000m level super deep and ultra-high temperature and pressure strata, Sichuan-Chongqing area[J]. Natural Gas Exploration and Development, 2023, 46(2): 44-50. [4] 于永金, 夏修建, 王治国, 等. 深井、超深井固井关键技术进展及实践[J]. 新疆石油天然气, 2023, 19(2): 24-33.YU Yongjin, XIA Xiujian, WANG Zhiguo, et al. Progress and application of the key technologies of deep and ultra deep well cementing[J]. Xinjiang Oil & Gas, 2023, 19(2): 24-33. [5] GUO X S, HU D F, LI Y P, et al. Theoretical progress and key technologies of onshore Ultra-Deep oil/gas exploration[J]. Engineering, 2019, 5(3): 458-470. doi: 10.1016/j.eng.2019.01.012 [6] GOU B, ZHANG J S, WANG K, et al. Effect of acid viscosity on conductivity during online acid-fracturing in ultra-deep carbonate reservoir[J]. Geoenergy Science and Engineering, 2024, 243: 213381. doi: 10.1016/j.geoen.2024.213381 [7] DANG Z G, CHEN X P, YAO X Z, et al. Wellbore temperature prediction model and influence law of Ultra-Deep wells in Shunbei field, China[J]. Processes, 2024, 12(8): 1715-1715. doi: 10.3390/pr12081715 [8] 程凯, 袁翊, 何涛. 200 ℃高温抗盐高密度水基钻井液在川渝地区的研究与应用[C]// 2022油气田勘探与开发国际会议论文集Ⅳ会议论文集. 西安, 2022: 525-529.CHENG Kai, YUAN Yi, HE Tao. Research and application of 200 ℃ high temperature salt resistant high-density water-based drilling fluid in Sichuan and Chongqing area[C]//Proceedings of the 2022 International Conference on Oil and Gas Field Exploration and Development Ⅳ. Xi’an, 2022: 525-529. [9] 于永金, 薛毓铖, 夏修建, 等. 一种抗240 ℃超高温固井缓凝剂的研发与评价[J]. 天然气工业, 2023, 43(3): 107-112.YU Yongjin, XUE Yucheng, XIA Xiujian, et al. Research & development and evaluation of a cementing retarder resistant to 240 ℃ ultra-high temperature[J]. Natural Gas Industry, 2023, 43(3): 107-112. [10] 陈灿灿, 孙灵辉, 刘先贵, 等. 碱对部分水解聚丙烯酰胺分子聚集形态的转变影响[J]. 应用化工, 2023, 52(1): 295-299, 308.CHEN Cancan, SUN Linghui, LIU Xiangui, et al. Effect of alkali on transformation of aggregation morphology of partially hydrolyzed polyacrylamide[J]. Applied Chemical Industry, 2023, 52(1): 295-299,308. [11] 谢启源, 陈丹丹, 丁延伟. 热重分析技术及其在高分子表征中的应用[J]. 高分子学报, 2022, 53(2): 193-210.XIE Qiyuan, CHEN Dandan, DING Yanwei. Thermogravimetric analysis and its applications in polymer characterization[J]. Acta Polymerica Sinica, 2022, 53(2): 193-210. [12] 于永金, 张航, 夏修建, 等. 超高温固井水泥浆降失水剂的合成与性能[J]. 钻井液与完井液, 2022, 39(3): 352-358.YU Yongjin, ZHANG Hang, XIA Xiujian, et al. Synthesis and study of an Ultra-High temperature filtrate reducer for cement slurries[J]. Drilling Fluid & Completion Fluid, 2022, 39(3): 352-358. [13] 赵建胜, 代清, 霍锦华, 等. 高温固井水泥浆用降失水剂GT-1的制备及性能[J]. 钻井液与完井液, 2022, 39(2): 234-240.ZHAO Jiansheng, DAI Qing, HUO Jinhua, et al. Preparation and application of fluid loss additive GT-1 for high temperature cementing slurry[J]. Drilling Fluid & Completion Fluid, 2022, 39(2): 234-240. [14] 郭锦棠, 刘振兴, 何军, 等. 新型耐温抗盐降失水剂 LX-1 的研制与性能评价[J]. 天津大学学报(自然科学与工程技术版), 2021, 54(3): 318-323.GUO Jintang, LIU Zhenxing, HE Jun, et al. Synthesis and properties of a new high-temperature and salt-resistant fluid loss additive LX-1[J]. Journal of Tianjin University(Science and Technology), 2021, 54(3): 318-323. [15] BAI X D, LI K, HU H, et al. Synthesis and properties of poly (acrylamide-co-N-vinylpyr-rolidone-co-sodium pstyrene sulfonate) as an anionic fluid loss additive[J]. Journal of Polymer Research, 2023, 30(5): 180. doi: 10.1007/s10965-023-03558-0 [16] 黄丽, 朱慧霞, 王淮, 等. 爆聚反应对聚甲丙烯酸铵酯Ⅰ单体残留影响的研究[J]. 现代化工, 2022, 42(1): 184-188, 194.HUANG Li, ZHU Huixia, WANG Huai, et al. Study on effect of explosive polymerization on monomer residue in methacrylic acid copolymer Ⅰ[J]. Modern Chemical Industry, 2022, 42(1): 184-188,194. [17] 王茂功, 颜星, 彭洁. 爆聚法合成抗高温抗盐水基降滤失剂及性能评价[J]. 钻井液与完井液, 2019, 36(2): 148-152.WANG Maogong, YAN Xing, PENG Jie. High temperature salt resistant filter loss reducers for water base drilling fluids: synthesis with explosive polymerization method and performance evaluation[J]. Drilling Fluid & Completion Fluid, 2019, 36(2): 148-152. [18] 刘锋报, 孙金声, 王建华. 国内外深井超深井钻井液技术现状及发展趋势[J]. 新疆石油天然气, 2023, 19(2): 34-39.LIU Fengbao, SUN Jinsheng, WANG Jianhua. A global review of technical status and development trend of drilling fluids for deep and ultra-deep wells[J]. Xinjiang Oil & Gas, 2023, 19(2): 34-39. [19] LUO Y H, LIN L, LUO P Y, et al. Polymer nanocomposite ADA@SM as a high-temperature filtrate reducer for water-based drilling fluids and its filtration loss mechanism[J]. Colloids and Surfaces A, Physicochemical and Engineering Aspects, 2023, 672: 131701. doi: 10.1016/j.colsurfa.2023.131701 [20] ZHANG H, HU M M, LI P P, et al. Covalently bonded AMPS-based copolymer-C-S-H hybrid as a fluid loss additive for oilwell saline cement slurry in UHT environment[J]. Construction and Building Materials, 2023, 378: 131177. doi: 10.1016/j.conbuildmat.2023.131177 [21] 林鑫, 刘硕琼, 夏修建, 等. 热引发聚合方法制备抗240 ℃水泥浆降失水剂[J]. 钻井液与完井液, 2024, 41(1): 98-104.LIN Xin, LIU Shuoqiong, XIA Xiujian, et al. Preparation of a 240 ℃cement slurry filter loss reducer prepared through thermal initiation polymerization[J]. Drilling Fluid & Completion Fluid, 2024, 41(1): 98-104. [22] AKANNO A, GUZMÁN E, ORTEGA F, et al. Behavior of the water/vapor interface of chitosan solutions with an anionic surfactant: effect of polymer-surfactant interactions[J]. Physical Chemistry Chemical Physics : PCCP, 2020, 22(40): 23360-23373. [23] GODDARD E D. Polymer/surfactant interaction: interfacial aspects[J]. Journal of Colloid and Interface Science, 2002, 256: 228-235 . doi: 10.1006/jcis.2001.8066 [24] KANCHARLA S, ZOYHOFSKI N A, BUFALINI L, et al. Association between nonionic amphiphilic polymer and ionic surfactant in aqueous solutions: effect of polymer hydrophobicity and micellization[J]. Polymers, 2020, 12(8): 1831. doi: 10.3390/polym12081831 [25] ZHANG B, YU Z G, PENG L H, et al. An ampholytic surfactant of flotation separating quartz from silicate minerals: Insights from experiments and theory[J]. Applied Surface Science, 2025, 699: 163137. doi: 10.1016/j.apsusc.2025.163137 [26] AN B, ZHOU L T, LIU S, et al. Radical homopolymerization of linear α‐olefins enabled by 1, 4-Cyano group migration[J]. Angewandte Chemie, 2024, 136(25): e202402511. doi: 10.1002/ange.202402511 [27] 贺垠博, 梁浩, 敬玉娟, 等. 一种抗超高温配位键合型低聚物降黏剂[J]. 钻井液与完井液, 2024, 41(3): 318-324.HE Yinbo, LIANG Hao, JING Yujuan, et al. An ultra-high temperature coordinate bond oligomer thinner[J]. Drilling Fluid & Completion Fluid, 2024, 41(3): 318-324 -
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