一种抗高温梳型两性离子聚合物降黏剂

邓正强; 张涛; 黄平; 罗宇峰; 王国帅; 贺垠博; 蒋官澄

doi:10.12358/j.issn.1001-5620.2024.02.006

一种抗高温梳型两性离子聚合物降黏剂

doi: 10.12358/j.issn.1001-5620.2024.02.006

1.
中石油川庆钻探工程有限公司钻井液技术服务公司，成都 610051
2.
中国石油大学(北京)石油工程学院, 北京102200

基金项目: 中石油川庆钻探工程有限公司钻井液技术服务公司“抗温 200 ℃高密度水基钻井液体系” （CQ2022B-18-1-3）。

详细信息

作者简介:
邓正强，工程师，1989年生，毕业于中国石油大学（北京），现在从事钻井液与完井液工作。E-mail：dengzhengq_sc@cnpc.com.cn

通讯作者:
蒋官澄，教授，博士研究生导师。E-mail：m15600263100_1@163.com。

中图分类号: TE254.4
计量
- 文章访问数: 314
- HTML全文浏览量: 115
- PDF下载量: 192
- 被引次数: 0
出版历程
- 收稿日期: 2023-10-23
- 修回日期: 2023-12-03
- 刊出日期: 2024-04-02

A High Temperature Comb and Zwitterionic Polymer Thinner

1.
CCDC Drilling Fluid Technology Service Co., LTD, Chengdu, Sichuan 610051
2.
College of Petroleum Engineering, China University of Petroleum(Beijing), Beijing 102200

摘要

摘要: 针对深井超深井钻井中高密度水基钻井液黏度高、易高温增稠等流变性调控难题，以对苯乙烯磺酸钠盐、2-丙烯酰胺基-2-甲基丙磺酸、2-烯丙基-2-甲基氯化铵、烯丙基聚氧乙烯醚为单体，合成了一种抗高温梳型两性离子聚合物降黏剂ZT-1。采用红外光谱表征了降黏剂的分子结构，验证梳型两性离子聚合物合成的成功，采用热重分析表征了降黏剂的热稳定性，其分解温度达250 ℃。ZT-1具有良好的抗高温耐盐钙降黏分散性能，抗温240 ℃，可抗饱和盐，抗2%氯化钙；ZT-1加量为0.3%时，老化温度为200 ℃，在评价浆中的降黏率可达77.7%，在高密度（2.4 g/cm³）水基钻井液体系中表观黏度的降低率达33%，塑性黏度的降低率达14%，动切力降低率达67%。ZT-1性能优于阴离子降黏剂磺化丹宁以及常规线性两性离子聚合物降黏剂XY-27和ADS共聚物，这种梳型两性离子聚合物降黏剂在超高温超高密度钻井液中具有良好的应用前景。
- 降黏剂 /
- 抗高温 /
- 水基钻井液 /
- 梳型聚合物
Abstract: In deep and ultra-deep well drilling, high density water based drilling fluids are often faced with rheological problems of high viscosity and thickening at elevated temperatures. To solve these problems, a high temperature comb zwitterionic polymer thinner ZT-1 was developed with monomers including sodium p-styrene sulfonate, 2-acrylamido-2-methylpropane sulfonic acid, 2-allyl-2-methylammonium chloride and allyl polyoxyethylene ether. Characterization of the molecular structure of the thinner by IR spectrum shows that the synthesis of the comb zwitterionic polymer is successful. GTA characterization of the thinner demonstrates that ZT-1 has decomposition temperature of 250 ℃. Excellent properties of ZT-1 include high temperature stability and resistance to salt and calcium contamination; ZT-1 functions normally at temperatures up to 240 ℃, and it is resistant to salt contamination to saturation and to calcium contamination to 2% CaCl₂, respectively. A base mud treated with 0.3% ZT-1, after aging at 200 ℃, has its viscosity reduced by 77.7%. High density (2.4 g/cm³) drilling fluids can have their viscosity reduced by 33%, plastic viscosity reduced by 14% and yield point reduced by 67% with ZT-1. The performance of ZT-1 is better than that of the sulfonated tannin, XY-27 and ADS, the latter two being regular linear ionic zwitterionic polymers. This comb zwitterionic polymer thinner has good application in ultra-high density drilling fluids for ultra-high temperature drilling.
- Thinner /
- High temperature resistance /
- Water based drilling fluid /
- Comb polymer

HTML全文

图 1 降黏剂ZT-1的红外光谱图

下载: 全尺寸图片幻灯片

图 2 降黏剂ZT-1的热重图

下载: 全尺寸图片幻灯片

图 3 0.3%不同降黏剂老化前后降黏效果（200 ℃、16 h）

下载: 全尺寸图片幻灯片

图 4 0.3%不同降黏剂老化后抗盐钙性能（200 ℃、16 h）

下载: 全尺寸图片幻灯片

图 5 ZT-1在基浆中的粒径分布图对比

下载: 全尺寸图片幻灯片

图 6 ZT-1在重晶石分散液的粒径分布图对比

下载: 全尺寸图片幻灯片

表 1 ZT-1加量对评价浆流变参数的影响

ZT-1/%	AV/mPa·s	PV/mPa·s	YP/Pa	φ₁₀₀	DI/%
0	12.0	6	6.0	15.0
0.1	7.0	4	3.0	8.0	46.7
0.2	6.0	4	2.0	6.0	60.0
0.3	4.5	3	1.5	4.5	70.0
0.4	7.0	4	3.0	7.0	53.3
0.5	8.0	5	3.0	8.0	46.7

下载: 导出CSV

表 2 在评价浆中加入0.3%ZT-1前后的性能

ZT-1/ %	T_老化/ ℃	AV/ mPa·s	PV/ mPa·s	YP/ Pa	φ₁₀₀	DI/ %
0	室温	12.0	6	6.0	15.0	70.0
0.3	室温	7.0	4	3.0	4.5	70.0
0	180	13.0	6	7.0	16.0	73.3
0.3	180	7.0	4	3.0	5.0	73.3
0	200	14.0	7	7.0	18.0	77.7
0.3	200	4.5	3	1.5	4.0	77.7
0	220	16.0	8	8.0	19.0	78.9
0.3	220	5.0	4	1.0	4.0	78.9
0	240	17.0	8	9.0	19.0	68.4
0.3	240	9.0	6	3.0	6.0	68.4

下载: 导出CSV

表 3 ZT-1在不同盐水中的降黏率（200 ℃、16 h）

污染物	AV/mPa·s	PV/mPa·s	YP/Pa	φ₁₀₀	DI/%
空白	4.5	3	1.5	4.0	70.0
10%NaCl	4.0	3	1.0	4.0	73.3
15%NaCl	4.5	3	1.5	4.5	70.0
20%NaCl	6.0	4	2.0	5.0	66.6
30%NaCl	7.0	5	2.0	5.5	63.3
36%NaCl	7.0	5	2.0	5.5	63.3
0.5%CaCl₂	6.0	5	1.0	5.0	76.2
1.0%CaCl₂	6.0	3	3.0	4.0	78.6
2.0%CaCl₂	7.0	4	3.0	6.0	70.2

下载: 导出CSV

表 4 ZT-1在现场2.4 g/cm³高密度钻井液中的降黏效果

ZT-1/ %	T_老化/ ℃	φ₁₀₀	φ₆	φ₃	AV/ mPa·s	PV/ mPa·s	YP/ Pa	FL_HTHP/ mL
0	室温	50	10	9	107.0	92	15.0
0	200	83	21	18	122.5	71	51.5	12.2
0.3	室温	42	5	4	92.0	75	17.0
0.3	200	49	10	7	78.0	61	17.0	10.0

下载: 导出CSV

参考文献(16)

[1]	蒋官澄,吴学诗,鄢捷年,等. 深井水基钻井液高温高压流变特性的研究[J]. 钻井液与完井液,1994(5):18-23,71. JIANG Guancheng, WU Xueshi, YAN Jienian. Study on the rheology property of water based drilling fluid at high temperature and high pressure[J]. Drilling Fluid & Completion Fluid, 1994(5):18-23,71.
[2]	刘四海,蔡利山. 深井超深井钻探工艺技术[J]. 钻井液与完井液,2002,19(6):116-121. doi: 10.3969/j.issn.1001-5620.2002.06.037 LIU Sihai, CAI Lishan. Drilling technologies for deep wells and ultra-deep wells[J]. Drilling Fluid & Completion Fluid, 2002, 19(6):116-121. doi: 10.3969/j.issn.1001-5620.2002.06.037
[3]	贾敏,黄维安,邱正松,等. 超高温(240 ℃)抗盐聚合物降黏剂的合成与评价[J]. 化学试剂,2015,37(12):1067-1072. JIA Min, HUANG Weian, QIU Zhengsong, et al. Synthesis and evaluation of polymer viscosity reducer with ultra-high temperature (240 ℃) and salt tolerance[J]. Chemical Reagents, 2015, 37(12):1067-1072.
[4]	夏凯. 抗高温共聚物降黏剂的合成及其性能研究[D]. 武汉: 武汉理工大学, 2016. XIA Kai. Study on the synthesis and properties of copolymer viscosity agent with high temperature resistance[D]. Wuhan: Wuhan University of Technology, 2016.
[5]	张民. 钻井液用降黏剂的合成与评价[D]. 北京: 中国石油大学, 2010. ZHANG Min. Synthesis and evaluation of the thinner for drilling fluid[D]. Beijing: China University of Petroleum, 2010.
[6]	郝彬彬,李文波. 超高温耐盐型稀释剂HF-2的合成与性能评价[J]. 广东化工,2018,45(8):69-71. doi: 10.3969/j.issn.1007-1865.2018.08.033 HAO Binbin, LI Wenbo. Synthesis and performance evaluation of ultra high temperature salt-tolerant diluent HF-2[J]. Guangdong Chemical Industry, 2018, 45(8):69-71. doi: 10.3969/j.issn.1007-1865.2018.08.033
[7]	强天佩,黄凯,李竞,等. 钻井液用抗温抗盐稀释剂TX的研制与应用[J]. 石化技术,2016,23(2):154-157. doi: 10.3969/j.issn.1006-0235.2016.02.119 QIANG Tianpei, HUANG Kai, LI Jing, et al. Development and application of salt and temperature resistant diluent TX for drilling fluid[J]. Petrochemical Industry Technology, 2016, 23(2):154-157. doi: 10.3969/j.issn.1006-0235.2016.02.119
[8]	李骑伶,赵乾,代华,等. 对苯乙烯磺酸钠/马来酸酐/木质素磺酸钙接枝共聚物钻井液降黏剂的合成及性能评价[J]. 高分子材料科学与工程,2014,30(2):72-76. doi: 10.16865/j.cnki.1000-7555.2014.02.015 LI Qiling, ZHAO Qian, DAI Hua, et al. Synthesis and characterization of calcium lignosulfonate grafted with p-styrenesulfonate and maleic anhydride[J]. Polymer Materials Science & Engineering, 2014, 30(2):72-76. doi: 10.16865/j.cnki.1000-7555.2014.02.015
[9]	JARRETT M, CLAPPER D. High temperature filtration control using water based drilling fluid systems comprising water soluble polymers: US7651980 B2[P]. 2010-01-26.
[10]	王富华,王瑞和,王力,等. 钻井液用抗高温抗盐钙聚合物降黏剂JNL-1的研制与评价[J]. 油田化学,2009,26(1):1-4. doi: 10.19346/j.cnki.1000-4092.2009.01.001 WANG Fuhua, WANG Ruihe, WANG Li, et al. High temperature calcium and salt resistant polymer thinner JNL-1 for water base drilling fluids: preparation and evaluation[J]. Oilfield Chemistry, 2009, 26(1):1-4. doi: 10.19346/j.cnki.1000-4092.2009.01.001
[11]	明显森,彭新侠,李强,等. 水基钻井液降黏剂JNG-1的合成与性能评价[J]. 应用化工,2014,43(1):124-127. doi: 10.16581/j.cnki.issn1671-3206.2014.01.044 MING Xiansen, PENG Xinxia, LI Qiang, et al. Synthesis and performance evaluation of water-based drilling fluid viscosity reducer JNG-1[J]. Applied Chemical Industry, 2014, 43(1):124-127. doi: 10.16581/j.cnki.issn1671-3206.2014.01.044
[12]	赵晓非,陈娟娟,娄刚,等. MA/SAS/AMPS共聚物耐高温钻井液降黏剂的研制[J]. 化工科技,2014,22(2):38-41. doi: 10.3969/j.issn.1008-0511.2014.02.010 ZHAO Xiaofei, CHEN Juanjuan, LOU Gang, et al. Study on Ma/SAS/AMPS copolymer high temperature thinner for drilling fluid[J]. Science & Technology in Chemical Industry, 2014, 22(2):38-41. doi: 10.3969/j.issn.1008-0511.2014.02.010
[13]	王光平,吴洋,刘大海,等. 抗温耐盐型钻井液降黏剂合成与性能评价[J]. 应用化工,2015,44(10):1897-1900,1904. doi: 10.16581/j.cnki.issn1671-3206.2015.10.029 WANG Guangping, WU Yang, LIU Dahai, et al. Synthesis and performance evaluation of thinner for drilling fluid used at high temperature and salt[J]. Applied Chemical Industry, 2015, 44(10):1897-1900,1904. doi: 10.16581/j.cnki.issn1671-3206.2015.10.029
[14]	徐运波,蓝强,张斌,等. 梳型聚合物降滤失剂的合成及其在深井盐水钻井液中的应用[J]. 钻井液与完井液,2017,34(1):33-38. doi: 10.3969/j.issn.1001-5620.2017.01.006 XU Yunbo, LAN Qiang, ZHANG Bin, et al. Synthesis and application of a comb polymer filter loss reducer in deep well saltwater drilling fluid[J]. Drilling Fluid & Completion Fluid, 2017, 34(1):33-38. doi: 10.3969/j.issn.1001-5620.2017.01.006
[15]	张城,刘帅,袁翊,等. 两性离子聚合物降黏剂的制备与性能评价[J]. 油田化学,2023,40(1):7-11. ZHANG Cheng, LIU Shuai, YUAN Yi, et al. Preparation and performance evaluation of zwitterionic polymer viscosity reducer[J]. Oilfield Chemistry, 2023, 40(1):7-11.
[16]	任亚青,吴本芳. 耐盐耐高温超稠油降黏剂的研制与性能评价[J]. 油田化学,2020,37(2):318-324. doi: 10.19346/j.cnki.1000-4092.2020.02.023 REN Yaqing, WU Benfang. Development and performance evaluation of super heavy oil viscosity reducer with heat resistance and salt tolerance[J]. Oilfield Chemistry, 2020, 37(2):318-324. doi: 10.19346/j.cnki.1000-4092.2020.02.023