深共晶溶剂抑制页岩水化的应用与展望

白佳佳; 顾添帅; 陶磊; 冯枭; 陈明君

doi:10.12358/j.issn.1001-5620.2024.02.001

深共晶溶剂抑制页岩水化的应用与展望

doi: 10.12358/j.issn.1001-5620.2024.02.001

1.
常州大学石油工程学院, 江苏常州 213164
2.
中国石油集团工程技术研究院有限公司, 北京 102206
3.
西南石油大学油气藏地质及开发工程国家重点实验室, 成都 610500

基金项目: 江苏省基础研究计划自然科学基金-青年基金项目“渗吸压裂液对页岩甲烷多尺度输运的损益双重效应研究”（BK20230646）；江苏省研究生科研与实践创新计划项目“深共晶溶剂抑制黏土矿物水化机理研究”（KYCX23_3147）。

详细信息

作者简介:
白佳佳，博士，讲师，1993年生，主要从事致密油气藏储层保护与提高采收率研究工作。 E-mail：baijiajiaa@163.com。

中图分类号: TE254.4
计量
- 文章访问数: 192
- HTML全文浏览量: 60
- PDF下载量: 287
- 被引次数: 0
出版历程
- 收稿日期: 2023-11-04
- 修回日期: 2023-11-25
- 刊出日期: 2024-04-02

Application and Prospect of Deep Eutectic Solvent Inhibition in Shale Hydration

1.
School of Petroleum Engineering, Changzhou University, Changzhou，Jiangsu 213164
2.
CNPC Engineering Technology R & D Company Limited, Beijing 102206
3.
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500

摘要

摘要: 钻井过程中页岩水化常会诱发严重的井下安全事故，提高页岩井壁稳定性将极大地提高钻井成功率。深共晶溶剂（Deep eutectic solvent，DES）作为一种新型的绿色试剂，其性质与离子液体相类似，用途较为广泛。然而其作为水基钻井液添加剂在抑制页岩水化上的应用潜力尚未引起足够重视。相较于其他水基钻井液添加剂，DES具有不易燃、不易爆、无毒、易降解、电化学和热稳定性好等优点，并且DES价格便宜，来源广泛。在全面归纳总结DES的物理化学性质的基础上，讨论了DES作为水基钻井液添加剂抑制页岩水化的机理，并通过对DES的成本、对钻井液性能的影响进行分析，阐明了DES作为水化抑制剂在水基钻井液中的应用潜力。研究结果对DES在抑制页岩水化上的应用及其推广具有重要意义。
- 深共晶溶剂 /
- 页岩 /
- 水基钻井液添加剂 /
- 抑制水化
Abstract: Shale hydration during drilling often leads to serious downhole safety accidents, and improving the stability of shale borehole will greatly improve the success rate of drilling. As a new type of green reagent, deep eutectic solvent (DES) has similar properties to ionic liquids and is widely used. However, its potential as a water-based drilling fluid additive in inhibiting shale hydration has not attracted enough attention. Compared with other water-based drilling fluid additives, DES has the advantages of non-flammable, non-explosive, non-toxic, easy degradation, good electrochemical and thermal stability, and DES is cheap and comes from a wide range of sources. In this paper, on the basis of comprehensively summarizing the physical and chemical properties of DES, the mechanism of DES as a water-based drilling fluid additive to inhibit shale hydration is discussed, and the application potential of DES to inhibit shale hydration is clarified by analyzing the cost, the influence of DES on the performance of drilling fluid, and the application of DES. The results of this study are of great significance for the application and promotion of DES in inhibiting shale hydration.
- Deep eutectic solvents /
- Shale /
- Water-based drilling fluid additives /
- Inhibition of hydration

HTML全文

图 1 10 h后DES的质量损失随温度变化^[10]

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图 2 蒸馏水、3%KCl溶液和柠檬酸基DES溶液中页岩样品的线性膨胀率^[3]

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图 3 DES抑制页岩水化机制^[13]

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图 4 不同配比DES降低表面张力效果^[17]

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图 5 蒸馏水、DES浸泡后样品中伊利石黏土矿物层间距变化特征^[3]

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图 6 DES抑制黏土矿物水化机理图^[22]

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图 7 DES浓度与Zeta电位的关系^[24]

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参考文献(32)

[1]	罗东辉,赵凯,艾武昌,等. 一种实用油基钻井液冲洗效果评价方法及应用[J]. 当代化工,2019,48(12):2869-2871, 2895. LUO Donghui, ZHAO Kai, AI Wuchang, et al. A practical method for evaluating flushing effect of oil-based drilling fluids and its application[J]. Contemporary Chemical Industry, 2019, 48(12):2869-2871, 2895.
[2]	白海鹏,陈辉,刘学清,等. 低密度钻井液体系的种类及特点[J]. 石化技术,2020,27(8):112-113,111. doi: 10.3969/j.issn.1006-0235.2020.08.060 BAI Haipeng, CHEN Hui, LIU Xueqing, et al. Types and characteristics of low density drilling fluid systems[J]. Petrochemical Industry Technology, 2020, 27(8):112-113,111. doi: 10.3969/j.issn.1006-0235.2020.08.060
[3]	BAI J J, FENG X, CHEN Z W, et al. Investigation of the mechanism and effect of citric acid-based deep eutectic solvents inhibiting hydration and expansion of gas shale clay minerals[J]. Energy & Fuels, 2023, 37(4):2750-2758.
[4]	HUANG J, GUO X Y, XU T Y, et al. Ionic deep eutectic solvents for the extraction and separation of natural products[J]. Journal of Chromatography. a, 2019, 1598:1-19. doi: 10.1016/j.chroma.2019.03.046
[5]	HANSEN B B, SPITTLE S, CHEN B, et al. Deep eutectic solvents: a review of fundamentals and applications[J]. Chemical Reviews, 2021, 121(3):1232-1285. doi: 10.1021/acs.chemrev.0c00385
[6]	JIA H, HUANG P, WANG Q X, et al. Investigation of inhibition mechanism of three deep eutectic solvents as potential shale inhibitors in water-based drilling fluids[J]. Fuel, 2019, 244:403-411. doi: 10.1016/j.fuel.2019.02.018
[7]	YANG D Z, WANG Y D, PENG J B, et al. A green deep eutectic solvents microextraction coupled with acid-base induction for extraction of trace phenolic compounds in large volume water samples[J]. Ecotoxicology and Environmental Safety, 2019, 178:130-136. doi: 10.1016/j.ecoenv.2019.04.021
[8]	KUDDUSHI M, NANGALA G S, RAJPUT S, et al. Understanding the peculiar effect of water on the physicochemical properties of choline chloride based deep eutectic solvents theoretically and experimentally[J]. Journal of Molecular Liquids, 2019, 278:607-615. doi: 10.1016/j.molliq.2019.01.053
[9]	CAO Y Y, MU T C. Comprehensive investigation on the thermal stability of 66 ionic liquids by thermogravimetric analysis[J]. Industrial & Engineering Chemistry Research, 2014, 53(20):8651-8664.
[10]	JABLONSKY M, SKULCOVA A, HAZ A, et al. Long-term isothermal stability of deep eutectic solvents[J]. BioResources, 2018, 13(4):7545-7559.
[11]	ABBOTT A P, HARRIS R C, RYDER K S, et al. Glycerol eutectics as sustainable solvent systems[J]. Green Chemistry, 2011, 13(1):82-90. doi: 10.1039/C0GC00395F
[12]	MUHAMMED N S, OLAYIWOLA T, ELKATATNY S, et al. Insights into the application of surfactants and nanomaterials as shale inhibitors for water-based drilling fluid: A review[J]. Journal of Natural Gas Science and Engineering, 2021, 92:103987. doi: 10.1016/j.jngse.2021.103987
[13]	HAMMAD RASOOL M, AHMAD M, AYOUB M, et al. A review of the usage of deep eutectic solvents as shale inhibitors in drilling mud[J]. Journal of Molecular Liquids, 2022, 361:119673. doi: 10.1016/j.molliq.2022.119673
[14]	BOUL P J, REDDY B R, ZHANG J L, et al. Functionalized nanosilicas as shale inhibitors in Water-Based drilling fluids[J]. SPE Drilling & Completion, 2017, 32(2):121-130.
[15]	SALEH T A. Advanced trends of shale inhibitors for enhanced properties of water-based drilling fluid[J]. Upstream Oil and Gas Technology, 2022, 8:100069. doi: 10.1016/j.upstre.2022.100069
[16]	CAO H, ZHANG Z, BAO T, et al. Experimental investigation of the effects of drilling fluid activity on the hydration behavior of shale reservoirs in northwestern Hunan, China[J]. Energies, 2019, 12(16):3151. doi: 10.3390/en12163151
[17]	SHAFIE M H, YUSOF R, GAN C Y. Synthesis of citric acid monohydrate-choline chloride based deep eutectic solvents (DES) and characterization of their physicochemical properties[J]. Journal of Molecular Liquids, 2019, 288:111081. doi: 10.1016/j.molliq.2019.111081
[18]	HIRPARA D, PATEL B, CHAVDA V, et al. Micellization and clouding behaviour of an ionic surfactant in a deep eutectic solvent: a case of the reline-water mixture[J]. Journal of Molecular Liquids, 2022, 364:119991. doi: 10.1016/j.molliq.2022.119991
[19]	白佳佳,司双虎,陶磊,等. DES+CTAB复配驱油剂体系提高低渗致密砂岩油藏采收率机理[J]. 岩性油气藏,2024,36(1):169-177. doi: 10.12108/yxyqc.20240116 BAI Jiajia, SI Shuanghu, TAO Lei, et al. Mechanism of DES+CTAB compound oil displacement agent system to improve oil recovery in low-permeability tight sandstone reservoirs[J]. Lithologic Reservoirs, 2024, 36(1):169-177. doi: 10.12108/yxyqc.20240116
[20]	RASOOL M H, ZAMIR A, ELRAIES K A, et al. A deep eutectic solvent based novel drilling mud with modified rheology for hydrates inhibition in deep water drilling[J]. Journal of Petroleum Science and Engineering, 2022, 211:110151. doi: 10.1016/j.petrol.2022.110151
[21]	MA J Y, PANG S C, ZHOU W, et al. Novel deep eutectic solvents for stabilizing clay and inhibiting shale hydration[J]. Energy & Fuels, 2021, 35(9):7833-7843.
[22]	LEI M, HUANG W A, SUN J S, et al. Synthesis of carboxymethyl chitosan as an eco-friendly amphoteric shale inhibitor in water-based drilling fluid and an assessment of its inhibition mechanism[J]. Applied Clay Science, 2020, 193:105637. doi: 10.1016/j.clay.2020.105637
[23]	SULTANA K, RAHMAN M T, HABIB K, et al. Recent advances in deep eutectic solvents as shale swelling inhibitors: a comprehensive review[J]. ACS Omega, 2022, 7(33):28723-28755. doi: 10.1021/acsomega.2c03008
[24]	JIA H, HUANG P, HAN Y G, et al. Investigation for the novel use of a typical deep eutectic solvent as a potential shale inhibitor[J]. Energy Sources Part A:Recovery Utilization and Environmental Effects, 2022, 44(1):1402-1415. doi: 10.1080/15567036.2019.1643953
[25]	FARAG R M, SALEM A M, EL-MIDANY A A, et al. Bentonite Suspension Filtration and its Electro-Kinetics in the Presence of Additives[J]. Tenside Surfactants Detergents, 2021, 58(2):121-126. doi: 10.1515/tsd-2020-2257
[26]	ZHONG H Y, QIU Z S, ZHANG D M, et al. Inhibiting shale hydration and dispersion with amine-terminated polyamidoamine dendrimers[J]. Journal of Natural Gas Science and Engineering, 2016, 28:52-60. doi: 10.1016/j.jngse.2015.11.029
[27]	SMITH P S, BROWNE S V, HEINZ T J, et al. Drilling fluid design to prevent formation damage in high permeability quartz arenite sandstones[C]//SPE Annual Technical Conference and Exhibition. Denver: SPE: SPE-36430-MS.
[28]	RITA N, KHALID I, EFRAS M R. Rheological properties of drilling mud consist of cmc which is made by carton waste and chemical additive of Na₂CO₃ for reducing lost circulation[J]. IOP Conference Series. Materials Science and Engineering, 2020, 884:012027. doi: 10.1088/1757-899X/884/1/012027
[29]	AL-MALKI N, POURAFSHARY P, AL-HADRAMI H, et al. Controlling bentonite-based drilling mud properties using sepiolite nanoparticles[J]. Petroleum Exploration and Development, 2016, 43(4):717-723. doi: 10.1016/S1876-3804(16)30084-2
[30]	LIU Q, SANTAMARINA J C. Mudcake growth: model and implications[J]. Journal of Petroleum Science and Engineering, 2018, 162:251-259. doi: 10.1016/j.petrol.2017.12.044
[31]	MOHSENZADEH A, AL-WAHAIBI Y, AL-HAJRI R, et al. Effects of concentration, salinity and injection scenario of Ionic liquids analogue in heavy oil recovery enhancement[J]. Journal of Petroleum Science and Engineering, 2015, 133:114-122. doi: 10.1016/j.petrol.2015.04.036
[32]	BEG M, KESARWANI H, SHARMA S, et al. Impact of low-molecular-weight poly(4-styrenesulfonic acid-co-maleic acid) sodium salt on filtration and rheological parameters of nanoparticles-enhanced drilling fluid[J]. Journal of Vinyl and Additive Technology, 2022, 28(1):125-139. doi: 10.1002/vnl.21873