Development of an Ecological Drilling Fluid and Its Benefits to Saline-Alkaline Soil Reclamation
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摘要: 随着我国对西北部勘探开发力度的增加,同时对环保的要求也越来越严格,而传统处理工艺并不能使废弃钻井液达到低污染、低伤害的目的。针对废弃钻井液的污染问题,结合新疆多盐碱地的实际情况,利用盐碱土壤作为钻井液后期处理的场所,在基于天然材料的基础上研制了生态处理剂JH1、JH2、JH3,并开发出一套生态钻井液体系JH。并系统地评价了该体系的流变性、抗污染性、润滑性、抑制性和环保性能。实验结果表明,120℃下生态钻井液体系JH具有良好的流变性,API滤失量为3.4 mL,岩屑回收率为72.6%,线性膨胀率为11.54%,润滑系数为0.1058,具有较好的抗污染性能,能满足常规钻井的需要。生态钻井液环保性能较好,EC50为89 600 mg/kg,BOD5/CODCr为25.9%,易生物降解,重金属含量低于最低限值,满足排放限制标准。经过有机酸中和后施加在盐碱土壤上,有效改善了土壤的理化性质,土壤含盐量降幅达54.3%,pH值恢复至6.85,有机质含量增加了49.7%,N、P、K含量增幅59.25%~113.82%。Abstract: With more and more exploration performed in northwest China, environmental protection policy is becoming more rigorous. Conventional techniques are not able to treat waste muds to have acceptable contamination and damage levels. Xinjiang is rich in salinealkaline lands which can be used as waste mud disposal places. Three ecological additives, JH1, JH2 and JH3 have been developed from natural materials, and an ecological drilling fluid, JH has been formulated with the three additives. The rheology, resistance to contamination, lubricity, inhibitive capacity and environmental friendliness of the JH mud were systematically evaluated. The evaluation results showed that JH had good rheological property at 120℃, API filter loss of 3.4 mL, percent recovery of shale cuttings of 72.6% on hot rolling test, linear rate of expansion of 11.54%, friction coefficient of 0.1058, and good resistance to contamination. These data indicate that JH is able to satisfy the general requirements of drilling operation. The ecological data of JH are as follows:EC50=89 600 mg/kg, BOD5/CODCr=25.9%. JH is easy to biologically degrade. Heavy metal content of JH is low, satisfying the national discharge standards. The JH mud, after neutralization with organic acids, can be used to improve the quality of soil with great efficiency; a piece of saline-alkaline land was treated with the disposed waste JH mud, the saline content of the soil was reduced by 54.3%, pH of the soil restored to 6.85, organic matter content of the soil increased by 49.7%, and N, P, K contents in the soil were increased by a percentage between 59.25% and 113.82%, respectively.
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[1] 王眉山,郑毅. 中国废弃钻井液处理技术发展趋势[J]. 钻井液与完井液, 2009, 26(6):77-79.WANG Meishan,ZHENG Yi.Development trend of waste drilling fluid treatment technology in China[J]. Drilling Fluids & Completion Fluids,2009,26(6):77-79. [2] 王斌, 马兴旺,单娜娜,等. 新疆盐碱地土壤改良剂的选择与应用[J]. 干旱区资源与环境,2014,28(7):111-115.WANG Bing,MA Xingwang,SHAN Nana,et al. Selection and application of soil amendment for aalinealkali land in Xinjiang[J]. Journal of Arid Land Resources and Environment, 2014, 28(7):111-115. [3] WANG F,LIANG Z,DENG X.Management of Drilling Waste in an Environment and Economic Acceptable Manner[J].Advanced Materials Research, 2012, 518-523:3396-3402. [4] 孟苗,闫光绪,郭绍辉. 辽河油田废弃钻井液处理技术[J]. 钻井液与完井液, 2008,25(1):57-60.MENG Miao, YAN Guangxu, GUO Shaohui. Treatment technology of abandoned drilling fluid in Liaohe oilfield[J].Drilling Fluids & Completion Fluid,2008, 25(1):57-60. [5] 袁婧. 油污土壤降解细菌的分离鉴定及生长条件优化[D]. 东北林业大学,2011. YUAN Jing.Isolation and identification of oil-degrading soil degradation bacteria and optimization of growth conditions[D].Northeast Forestry University,2011. [6] 陈立荣,黄敏,蒋学彬,等.微生物-土壤联合处理废弃钻井液渣泥技术[J]. 天然气工业,2015,35(2):100-105.CHEN Lirong, HUANG Min, JIANG Xuebin, et al. Microbial-soil combined treatment of waste drilling fluid sludge technology[J].Natural Gas Industry, 2015, 35(2):100-105. [7] 冀忠伦. 废弃钻井液作为沙漠改良剂的应用研究[J]. 环境工程, 2010, 28(6):21-23.ZHAI Zhonglun.Application of waste drilling fluid as desert amendment[J].Environmental Engineering,2010, 28(6):21-23. [8] 代秋实, 潘一, 杨双春. 国内外环保型钻井液研究进展[J]. 油田化学, 2015, 32(3):435-439.DAI Qiushi, PAN Yi, YANG Shuangchun.Research progress of environmentally friendly drilling fluids at home and abroad[J]. Oilfield Chemistry, 2015, 32(3):435-439. [9] HOSSAIN M E, WAJHEEUDDIN M.The use of grass as an environmentally friendly additive in water-based drilling fluids[J].Petroleum Science,2016,13(2):292-303. [10] 胡进军,孙强,夏小春,等. 环境友好型水基钻井液GREEN-DRILL的研制与应用[J]. 石油钻探技术, 2014,42(2):75-79.HU Jinjun,SUN Qiang, XIA Xiaochun, et al. Development and application of environmentally friendly water-based drilling fluid GREEN-DRILL[J].Petroleum Drilling Technique,2014,42(2):75-79. [11] 高伟,邵玉翠,杨军,等. 盐碱地土壤改良剂筛选研究[J]. 中国农学通报,2011, 27(21):154-160.GAO Wei,SHAO Yucui,YANG Jun,et al. Screening of soil amendments in saline-alkali lands[J].Chinese Agricultural Science Bulletin,2011,27(21):154-160. [12] SY/T 6335-1997钻井液用页岩抑制剂评价方法[S]. SY/T 6335-1997 Evaluation method for shale inhibitors for drilling fluids[S]. [13] 邢希金, 王荐, 何松,等. 关于我国环保钻井液标准的探讨[J]. 石油工业技术监督, 2018,34(5):23-27.XING Xijin, WANG Jian, HE Song, et al. Discussion on environmental drilling fluid standards in China[J]. Petroleum Industry Technical Supervision, 2018,34(5):23-27. [14] CHAN K Y, VAN ZWIETEN L,MESZAROS I,et al. Using poultry litter biochars as soil amendments[J].Soil Research,2008, 46(5):437-444. [15] WALKER D J,CLEMENTE R,ROIG A,et al.The effects of soil amendments on heavy metal bioavailability in two contaminated Mediterranean soils[J]. Environmental Pollution, 2003, 122(2):303-312. [16] BALWANTS,BHUPINDERPAL S,ANNETTEL C.Characterisation and evaluation of biochars for their application as a soil amendment[J].Soil Research,2010, 48(7):516-525. [17] 石堃,崔大练,易杨,等. 菌糠土壤改良剂对滩涂盐碱土壤主要理化性质的影响[J]. 国土与自然资源研究, 2014(5):45-47. SHI Wei,CUI Dalian,YI Yang, et al.Effects of soil sorghum soil amendments on main physical and chemical properties of saline-alkali soils in tidal flats[J]. Studies in Terrestrial and Natural Resources,2014(5):45-47. [18] 陈义群, 董元华. 土壤改良剂的研究与应用进展[J]. 生态环境, 2008,17(3):1282-1289.CHEN Yiqun, DONG Yuanhua. Progress in research and application of soil amendments[J].Ecological Environment,2008, 17(3):1282-1289. [19] 《土壤农业化学常规分析方法》出版消息[J]. 土壤, 1982(5):195. "Preliminary analysis method of soil agricultural chemistry" published news[J]. Soil, 1982(5):195. [20] 贺海升, 王文杰, 朱虹,等. 盐碱地土壤改良剂施用对种子萌发和生长的影响[J]. 生态学报, 2008, 28(11):5338-5346.HE Haisheng, WANG Wenjie, ZHU Hong, et al. Effects of application of soil amendments on seed germination and growth in saline-alkali soils[J]. Chinese Journal of Ecology,2008, 28(11):5338-5346. [21] 李鹏程,苏学德,王晶晶,等. 腐植酸肥与菌肥配施对果园土壤性质及葡萄产量、品质的影响[J]. 中国土壤与肥料,2018(1):121-126. LI Pengcheng, SU Xuede, WANG Jingjing,et al.Effects of humic acid fertilizer and bacterial fertilizer on soil properties and grape yield and quality in orchard[J].China Soil and Fertilizer,2018(1):121-126. [22] 肖国举, 张萍, 郑国琦,等. 脱硫石膏改良碱化土壤种植枸杞的效果研究[J]. 环境工程学报,2010(10):2315-2320. XIAO Guoju, ZHANG Ping, ZHENG Guoqi, et al. Effect of desulfurization gypsum on improving alkalized soil planting alfalfa[J].Chinese Journal of Environmental Engineering,2010(10):2315-2320.
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