Volume 37 Issue 5
Oct.  2020
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Article Navigation >  DRILLING FLUID & COMPLETION FLUID  > 2020  >  37(5): 541-549
LI Gongrang, WANG Chengjun. Research Progress Made and Development Trend of Drilling Fluid Lubricants with Polar Adsorption Ability[J]. DRILLING FLUID & COMPLETION FLUID, 2020, 37(5): 541-549. doi: 10.3969/j.issn.1001-5620.2020.05.001
Citation: LI Gongrang, WANG Chengjun. Research Progress Made and Development Trend of Drilling Fluid Lubricants with Polar Adsorption Ability[J]. DRILLING FLUID & COMPLETION FLUID, 2020, 37(5): 541-549. doi: 10.3969/j.issn.1001-5620.2020.05.001
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Research Progress Made and Development Trend of Drilling Fluid Lubricants with Polar Adsorption Ability

doi: 10.3969/j.issn.1001-5620.2020.05.001

  • Drilling Technology Research Institute, Sinopec Shengli Oilfield Service Corporation, Dongying, Shandong 257000

  • Received Date: 2020-03-22
  • Publish Date: 2020-10-28
    Abstract
  • With more and more deep wells, ultra-deep wells, highly deviated wells, directional wells and horizontal wells drilled worldwide, demands on the lubricity of water base drilling fluids are increasing. Drilling lubricants with polar adsorption ability can effectively enhance the adsorption of the lubricant molecules on the friction surfaces, thereby improving the lubricity of the drilling fluid. This paper summarizes the progress made in the research of drilling lubricants with polar adsorption ability in recent years, including alcohol ethers, vegetable oil esters and their derivatives, long chain alkyl glucosides as well as extreme-pressure lubricants. The development trend of lubricants that can be adsorbed on the surfaces of drilling tools and lubricants with multiple adsorption points are then introduced. Generally speaking, the lubricity of a drilling lubricant is closely related to the polarity, type and quantity of the adsorptive groups in its molecular structure. Amino group and amide group, which have stronger polarity, have better adsorption on the surfaces of drilling tools or borehole walls than hydroxyl group and ether bond which have weak polarity. Under extreme pressures, lubricants containing sulfur, borate or phosphate can be adsorbed on the surfaces of drilling tools through chemical reaction, producing extreme lubricity. Nitrogen-containing heterocyclic compounds, on the other hand, can be adsorbed firmly on the surfaces of drilling tools, forming a complex adsorption film. Lubricants with multiple polar adsorptive groups can form multi-point adsorption on the surfaces of friction, effectively improving the strength of the lubricating film.

     

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  • [1]
    樊好福,司西强,王中华. 水基钻井液用绿色润滑剂研究进展及发展趋势[J]. 应用化工, 2019, 48(5):1192-1196.

    FAN Haofu,SI Xiqiang,WANG Zhonghua.Research progress and development trend of green lubricants for water based drilling fluids[J].Applied Chemical Industry, 2019, 19(2):1192-1196.
    [2]
    宣扬,钱晓琳,林永学,等. 水基钻井液润滑剂研究进展及发展趋势[J]. 油田化学,2017,34(4):721-726.

    XUAN Yang,QIAN Xiaolin,LIN Yongxue,et al. Research progress and development trend of lubricants for water based drilling fluids[J].Oilfield Chemistry,2017, 34(4):721-726.
    [3]
    魏昱,王骁男,安玉秀,等. 钻井液润滑剂研究进展[J]. 油田化学, 2017,34(4):727-733.

    WEI Yu, WANG Xiaonan, AN Yuxiu,et al.Research progress of lubricants for drilling fluids[J].Oilfield Chemistry,2017,34(4):727-733.
    [4]
    金军斌. 钻井液用润滑剂研究进展[J]. 应用化工, 2017, 46(4):770-774.

    JIN Junbin. Research advances of the lubricants for drilling fluid[J].Applied Chemical Industry, 2017, 46(4):770-774.
    [5]
    艾贵成,田效山,兰祖权,等. 超高温超高密度有机盐钻井液技术研究[J]. 西部探矿工程,2010(9):47-49. AI Guicheng,TIAN Xiaoshan,LAN Zuquan, et al. Research on organic salt based drilling fluid with ultra-high temperature and ultra-high density[J].WestChina Exploration Engineering, 2010

    (9):47-49.
    [6]
    王琳,董晓强,杨小华,等. 高密度钻井液用润滑剂SMJH-1的研制及性能评价[J]. 钻井液与完井液, 2016,33(1):28-32.

    WANG Lin,DONG Xiaoqiang,YANG Xiaohua,et al. Development and evaluation of a high density drilling fluid lubricant[J].Drilling Fluid & Completion Fluid, 2016,33(1):28-32.
    [7]
    高小芃,王伟亮,司西强,等. 长南气田水平井定向井段钻井液技术[J]. 山东化工,2016,45(8):79-84.

    GAO Xiaofan,WANG Weiliang,SI Xiqiang,et al. Drilling fluid technology of directional well section in changnan gas field horizontal well[J].Shandong Chemical Industry, 2016, 45(8):79-84.
    [8]
    徐德行. 长水平段水平井钻井难点与技术对策探讨[J]. 西部探矿工程, 2017(7):54-55. XU Dexing.Discussion on drilling difficulties and technical countermeasures of long horizontal wells[J]. West-China Exploration Engineering,2016

    , 45(8):79-84.
    [9]
    LAN P X,LACCINO L L,BAO X Y,et al. The effect of lubricant additives on the tribological performance of oil and gas drilling applications up to 200℃[J].Tribology International, 2020, 141, 1-11.
    [10]
    SYAHRULLAIL S,KAMITANI S,SHAKIRIN A. Performance of vegetable oil as lubricant in extreme pressure condition[J].Procedia Engineering, 2013(68):172-177.
    [11]
    ZHANG J,MENG Y G.Boundary lubrication by adsorption film[J]. Friction, 2015, 3(2):115-147.
    [12]
    HSU S, GATES R S.Boundary lubricating films:Formation and lubrication mechanism[J].Tribology International,2005, 38(3):305-312.
    [13]
    SOLTANAHMADI S,ESFAHANI E A,NEDELCU I, et al. Surface reaction films from amine based organic friction modifers and their influence on surface fatigue and friction[J]. Tribology Letters,2019, 67(80):1-15.
    [14]
    李小瑞,张宇,景晓琴,等. 一种高性能环保型钻井液润滑剂的研究与应用[J]. 钻井液与完井液, 2018, 35(4):46-50.

    LI Xiaorui,ZHANG Yu,JING Xiaoqin,et al. Evaluation and application of the high performance environmentally friendly drilling fluid lubricant HPRH[J]. Drilling Fluid & Completion Fluid,2018,35(4):46-50.
    [15]
    刘云峰,邱正松,杨鹏,等. 一种钻井液用高效抗磨润滑剂[J]. 钻井液与完井液, 2018, 35(9):8-13.

    LIU Yunfeng,QIU Zhengsong,YANG Peng, et al.A High-performance drilling fluid anti-wear lubricant[J]. Drilling Fluid & Completion Fluid,2018, 35(9):8-13.
    [16]
    孙启忠,胥洪彪,刘传情,等. 聚合醚润滑剂HLX的研究及应用[J]. 石油钻探技术,2003,31(1):42-43.

    SUN Qizhong,XU Hongbiao,LIU Chuanqing, et al. A high-performance drilling fluid anti-wear lubricant[J]. Petroleum Drilling Techniques,2003,31(1):42-43.
    [17]
    刘晓栋. 钻井液用页岩抑制剂聚醚多元醇研究进展[J]. 钻井液与完井液,2013,30(1):75-79.

    LIU Xiaodong.Research progress of polyether polyol based shale inhibitor for drilling fluid[J].Drilling Fluid & Completion Fluid, 2013, 30(1):75-79.
    [18]
    许明标,胥洪彪,王昌军,等. 新型钻井液用多元醇醚润滑剂的研究[J]. 油田化学,2002,19(4):302-303.

    XU Mingbiao,XU Hongbiao,WANG Changjun,et al. Research on novel polyether polyol based lubricant for drilling fluid[J].Oilfield Chemistry,2002,19(4):302-303.
    [19]
    吕开河. 钻井液用聚醚多元醇润滑剂SYT-2[J]. 油田化学,2004,21(2):97-99.

    LYU Kaihe.Polyether polyol based lubricant SYT-2 for drilling fluid[J].Oilfield Chemistry,2004,21(2):97-99.
    [20]
    肖稳发,向兴金,王昌军,等. 含醇醚水基钻井液体系的研究与应用[J]. 石油与天然气化工,2000,29(4):199-202.

    XIAO Wenfa,XIANG Xingjin,WANG Changjun,et al. Research and application of alcohol ether containing water-based drilling fluid system[J].Chemical Engineering of Oil & Gas,2000,29(4):199-202.
    [21]
    夏小春,胡进军,孙强,等. 环境友好型水基润滑剂GreenLube的研制与应用[J]. 油田化学,2013,30(4):491-495.

    XIA Xiaochun,HU Jingjun,SUN Qiang,et al. Development and application of environmental friendly water-based lubricant GreenLube[J].Oilfield Chemistry, 2013, 30(4):491-495.
    [22]
    刘娜娜,王菲,张宇,等. 钻井液润滑剂RH-B的制备与性能评价[J]. 西安石油大学学报(自然科学版), 2014, 29(1):89-93. LIU Nana,WANG Fei,ZHANG Yu,et al.Preparation and performance evaluation of lubricant RH-B for drilling fluid[J].Journal of Xi'an Shiyou University(Natural Science Edition),2014,29(1):89-93.
    [23]
    陈馥,张浩书,张启根,等. 钻井液用低生物毒性合成酯润滑剂的研究与应用[J]. 油田化学,2018,35(1):8-11.

    CHEN Fu,ZHANG Haoshu,ZHANG Qigen,et al. Research and application of synthetic ester based lubricant with low biological toxicity for drilling fluid[J].Oilfield Chemistry,2018,35(1):8-11.
    [24]
    逯贵广. 环保型钻井用高效润滑剂NH-HPL的制备与性能评价[J]. 西安石油大学学报(自然科学版), 2017,32(5):85-89. LU Guiguang. Preparation and evaluation of environmentally friendly efficient lubricant NH-HPL for drilling[J].Journal of Xi'an Shiyou University(Natural Science Edition),2017,32(5):85-89.
    [25]
    张文,杜昱熹,孔凡波. 一种乳液型钻井液润滑剂的制备及性能评价[J]. 石油与天然气化工,2016,45(4):73-76.

    ZHANG Wen,DU Yuxi,KONG Fanbo.Preparation and evaluation of an emulsion-type drilling lubricant[J]. Chemical Engineering of Oil & Gas,2016,45(4):73-76.
    [26]
    DONG X Q,WANG L,YANG X H,et al.Effect of ester based lubricant SMJH-1 on the lubricity properties of water based drilling fluid[J].Journal of Petroleum Science and Engineering,2015,135:161-167.
    [27]
    尚会建,段晓娜,李慧,等.烷基糖苷研究现状及展望[J]. 现代化工,2013,33(11):28-32.

    SHANG Huijian,DUAN Xiaona, LI Hui, et al.Research status and prospects of alkyl polyglycoside[J].Modern Chemical Industry,2013,33(11):28-32.
    [28]
    刘洋,张春峰,王丰收,等.烷基糖苷的最新研究进展[J]. 日用化学品科学,2016,39(4):25-29.

    LIU Yang,ZHANG Chunfeng,WANG Fengshou, et al.The novel research progress of alkyl glucoside[J]. Detergent & Cosmetics,2016,39(4):25-29.
    [29]
    邹新源,罗文利, 周新宇. 烷基糖苷衍生物的合成及其应用进展[J]. 应用化工,2015, 44(10):1916-1920.

    ZOU Xinyuan, LUO Wenli, ZHOU Xinyu. Synthesis and application development of alkyl glucoside derivatives[J]. Applied Chemical Industry, 2015, 44(10):1916-1920.
    [30]
    POBER K W. Lubricant for high pH water based mud system:WIPO 2015/099811. 2015.
    [31]
    ALBRECHT M S,COWAN K M,MCNEIL III R I,et al. Silica-based drilling mud comprising glycoside lubricants with amino-linked alkyl chains:U.S. patent 7320951[P]. 2008-01-22.
    [32]
    魏风勇,司西强,王中华,等. 烷基糖苷及其衍生物钻井液发展趋势[J]. 现代化工,2015, 35(5):48-51.

    WEI Fengyong,SI Xiqiang,WANG Zhonghua,et al. Progress of alkyl glucoside derivatives as drilling fluid[J]. Modern Chemical Industry,2015,35(5):48-51.
    [33]
    司西强,王中华,魏军,等. 阳离子烷基糖苷的绿色合成及性能评价[J]. 应用化工,2012,41(9):1526-1530.

    SI Xiqiang,WANG Zhonghua,WEI Jun,et al. Green synthesis and performance evaluation of cationic alkyl glucoside[J].Applied Chemical Industry,2012,41(9):1526-1530.
    [34]
    CHANG Z Y,BREEDEN D L,MCDONALD M J.The use of zinc dialkyl dithiophosphate as a lubricant enhancer for drilling fluids particularly silicate-based drilling fluids[C]. SPE 141327, 2011.
    [35]
    罗春芝, 刘霞. XCR水基极压润滑剂的研制及应用[J]. 钻井液与完井液, 2006, 23(6):22-28.

    LUO Chunzhi, LIU Xia. Preparation and application of water-based extreme pressure lubricant XCR[J].Drilling Fluid & Completion Fluid,2006, 23(6):22-28.
    [36]
    孟祥涛, 黄玮, 丛玉凤, 等. 醇胺型硼酸酯抗磨添加剂的制备[J]. 当代化工, 2015, 44(9):2113-2115.

    MENG Xiangtao, HUANG Wei, CONG Yufeng,et al. Preparation of alcohol amine borate antiwear additive[J]. Contemporary Chemical Industry,2015,44(9):2113-2115.
    [37]
    吴超, 贾晓鸣, 高亚男. 含硼水基润滑剂的制备及其性能研究[J]. 润滑与密封,2007,32(1):175-177.

    WU Chao, JIA Xiaoming, GAO Yanan.Preparation and tribological properties of B-containing water base lubricant additives[J].Lubrication Engineering,2007, 32(1):175-177.
    [38]
    SAFFARIA H R M, SOLTANIA R, ALAEIB M, et al. Tribological properties of water-based drilling fluids with borate nanoparticles as lubricant additives[J].Journal of Petroleum Science and Engineering,2017,171:253-259.
    [39]
    任天辉,薛群基. 含氮杂环化合物及其衍生物用作多功能润滑油添加剂的研究发展现状[J]. 摩擦学快报, 1994,14(4):370-381.

    REN Tianhui,XUE Qunji.Research and development status of nitrogen-containing heterocyclic compounds and their derivatives used as multifunctional lubricating oil additives[J].Tribology,1994,14(4):370-381.
    [40]
    BHATLACHARYA A.The role of certain substituted 2-amino-benzothiazoyl-thiocarbam ideas as additives in extreme pressure lubrication of steel bearing balls[J]. Wear,1990,13(6):345-349.
    [41]
    饶文琦,任天辉,李久盛,等. 六元含氮杂环化合物的分子结构对其抗磨性能的影响[J]. 摩擦学报,2001,21(2):118-121.

    RAO Wenqi,REN Tianhui,LI Jiusheng,et al. Effect of molecular structure of six-membered nitrogencontaining heterocyclic compound on its anti-wear ability[J].Tribology,2001,21(2):118-121.
    [42]
    吴超,梁珊,吴现棉,等. 硬脂酰苯并三氮唑的合成及其润滑性能研究[J]. 化学与生物工程,2008,25(12):26-28.

    WU Chao,LIANG Shan,WU Xianmian,et al.Study on the synthesis and lubricating properties of stearoyl benzotriazole[J].Chemistry & Bioengineering,2008,25(12):26-28.
    [43]
    欧阳平,张贤明,张渊博,等. 新型无硫磷含氮润滑材料的制备及其对钢钢摩擦副摩擦学性能的影响[J]. 材料科学与工程学报,2012,30(5):689-693.

    OU Yangping,ZHANG Xianming,ZHANG Yuanbo, et al.Preparation for the new nitrogen-containing lubricating material without phosphorus/sulphur and its effect on the tribologcial properties of steel-steel friction pairs[J].Journal of Materials Science &Engineering, 2012, 30(5):689-693.
    [44]
    王正,荣沙沙,陈以周,等. 一种新型噻唑类缓蚀润滑剂的合成及性能评价[J]. 长江大学学报(自科版), 2016,13(19):1-5. WANG Zheng,RONG Shaha,CHEN Yizhou,et al. Synthesis and performance evaluation of a new type of thiazole corrosion inhibitor lubricant[J].Journal of Yangtze University(National Science Edition),2016,13(19):1-5.
    [45]
    温福山,杜永霞,张涵,等. 双咪唑啉缓蚀剂的缓蚀性能评价[J]. 腐蚀与防护,2019,40(2):92-100.

    WEN Fushan,DU Yongxia,ZHANG Han,et al. Evaluation of corrosion inhibition of a bis-imidazoline corrosion inhibitor[J].Corrosion & Protection,2019,40(2):92-100.
    [46]
    刘红. 一种三氮唑双席夫碱对N80钢在HCl介质中的缓蚀作用[J]. 腐蚀与防护,2019,40(6):402-407.

    LIU Hong.Corrosion inhibition of triazole bis-schiff based to N80 steel in HCl acid medium[J].Corrosion & Protection,2019,40(6):402-407.
    [47]
    何毅,周艳秋,杨冉冉,等. 多吸附位点席夫碱缓蚀剂的合成及缓蚀效果[J]. 现代化工,2016,36(3):62-66.

    HE Yi,ZHOU Yanqiu,YANG Ranran,et al.Synthesis and performance evaluation of a new type of Schiff base corrosion inhibitor with multiple reaction centers for P110 steel[J].Modern Chemical Industry,2016, 36(3):62-66.
    [48]
    张世超,白致铭. 具有多吸附中心的缓蚀剂的合成及性能研究[J]. 腐蚀科学与防护技术, 2003, 15(2):79-81.

    ZHANG Shichao,BAI Zhiming.Synthesis and performance of corrosion inhibitors with multi adsorption centers[J].Corrosion Science and Protection Technology, 2003, 15(2):79-81.
    [49]
    钱晓琳,宣扬,林永学,等. 钻井液环保润滑剂SMLUB-E的研制及应用[J]. 石油钻探技术,2020,48(1):34-39.

    QIAN Xiaoling,XUAN Yang,LIN Yongxue,et al. Development and application of an environmental-friendly drilling fluid lubricant SMLUB-E[J].Petroleum Drilling Techniques,2020,48(1):34-39.
    [50]
    熊丽萍,卢慧,钟青玉,等. 含硫磷的水溶性三嗪添加剂对硬质合金的摩擦学性能研究[J]. 润滑与密封, 2016,41(7):33-37.

    XIONG Liping,LU Hui,ZHONG Qingyu,et al. Development and application of an environmentalfriendlydrilling fluid lubricant SMLUB-E[J].Petroleum Drilling Techniques,2016,41(7):33-37.
    [51]
    廖俊旭,鲁浩,戴康徐,等. 绿色含氮多功能润滑油添加剂的合成、表征及其润滑性能[J]. 精细化工, 2018,35(8):1415-1420.

    LIAO Junxu,LU Hao,DAI Kangxu,et al.Synthesis characterization and lubricating properties of green nitrogen-containing multifunctional lubricant additives[J]. Fine Chemicals,2018,35(8):1415-1420.
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