Rheology of Triisopropanolamine Modified Xanthan Water Solution

LAN Chengcheng; FANG Bo; LU Yongjun; QIU Xiaohui

doi:10.3969/j.issn.1001-5620.2019.03.019

Volume 36 Issue 3

Jun. 2019

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LAN Chengcheng, FANG Bo, LU Yongjun, QIU Xiaohui. Rheology of Triisopropanolamine Modified Xanthan Water Solution[J]. DRILLING FLUID & COMPLETION FLUID, 2019, 36(3): 371-377. doi: 10.3969/j.issn.1001-5620.2019.03.019

Citation:

LAN Chengcheng, FANG Bo, LU Yongjun, QIU Xiaohui. Rheology of Triisopropanolamine Modified Xanthan Water Solution[J]. DRILLING FLUID & COMPLETION FLUID, 2019, 36(3): 371-377. doi: 10.3969/j.issn.1001-5620.2019.03.019

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Rheology of Triisopropanolamine Modified Xanthan Water Solution

doi: 10.3969/j.issn.1001-5620.2019.03.019

1. Laboratory of Rheologyof the College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237;
2. Langfang Branch of PetroChina Research Institute of Petroleum Exploration and Development, Langfang, Hebei 065007

Received Date: 2019-01-05
Publish Date: 2019-06-30

Abstract

Abstract

To improve the rheology of xanthan solution, a high viscosity polyhydroxy amphoteric xanthan (TIPA-XG) was developed through the etherization of xanthan polymer (XG). The etherizing agent used was a cationic polyhydroxy agent developed with triisopropanolamine and epichlorohydrin. The XG and TIPA-XG were characterized with IR spectroscopy, element analysis and XRD spectroscopy. The rheological characteristics of the TIPA-XG solution and the XG solution, including steady state viscosity, flow curve,thixotropy, viscoelasticity as well as the high temperature tolerance and shear resistance of the two solutions were studied and compared. It was found that TIPA-XG has higher viscosity than XG; the viscosity of a 0.6% TIPA-XG solution was 320.45 mPa·s, 332% higher than that of the XG solution, which was 74.12 mPa·s. The flow curves of the XG and the TIPA-XG solutions can all be described by the non-linear co-rotational Jeffreys constitutive equation. The viscoelasticity and thixotropy of the TIPA-XG solution were all greater than those of the XG solution. When sheared at 80℃ for 90 min, 0.6% TIPA-XG solution had a remaining viscosity of 142.88 mPa·s, which was 2.26 times of the remaining viscosity of the 0.6% XG solution (63.27 mPa·s) under the same conditions, indicating that TIPA-XG has better high temperature stability that XG.
- Xanthan,
- Polyhydroxy amphoteric xanthan,
- Rheology,
- High temperature and shearing resistance

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References(29)

References

[1]	赵万金,李海亮,杨午阳. 国内非常规油气地球物理勘探技术现状及进展[J].中国石油勘探,2012,17(4):36-40. ZHAO Wanjin,LI Hailiang,YANG Wuyang. Current status and progress of unconventional oil and gas geophysical exploration technology in China[J]. China Petroleum Exploration,2012,17(4):36-40.
[2]	翟光明.关于非常规油气资源勘探开发的几点思考[J]. 天然气工业,2008,28(12):1-3. ZHAI Guangming. Speculations on the exploration and development of unconventional hydro-carbon resources[J]. Natural Gas Industry,2008,28(12):1-3.
[3]	黄鑫,董秀成,肖春跃,等. 非常规油气勘探开发现状及发展前景[J]. 天然气与石油,2013,30(6):38-41. HUANG Xin,DONG Xiucheng,XIAO Chunyue,et al. Current situation and prospect of exploration and development in unconventional hydrocarbon[J]. Natural Gas and Oil,2013,30(6):38-41.
[4]	WANG Ping,JIANG Ruizhong,WANG Shichao,et al. Lessons learned from north America and current status of unconventional gas exploration and exploitation in China[R]. SPE 153071, 2012.
[5]	赵立强,牟媚,罗志锋,等. 中国致密油储层改造理念及技术展望[J]. 西南石油大学学报(自然科学版), 2016,38(6):111-118.
[6]	ZHAO Liqiang,MOU Mei,LUO Zhifeng,et al. The outlook for China's tight oil reservoir stimulation concept and technology[J].Journal of Southwest Petroleum University(Science & Technology Edition),2016,38(6):111-118.
[7]	CAIRNS P,MILES M J,MORRIS V J. Intermolecular bindingof xanthan gum and carob gum[J].Nature,1986, 322(6074):89-90.
[8]	ROSALAM S,ENGLAND R. Review of xanthan gum production from unmodified starches by, Xanthomonas comprestris sp.[J].Enzyme & Microbial Technology, 2006,39(2):197-207.
[9]	WANG L L,ZHU F R,LU D N. Rheological properties of sodium alginate and xanthan pastes on cotton with reactive dye in screen printing[J]. Textile Research Journal,2013,83(17):1873-1884.
[10]	明华,卢拥军,翟文,等. 黄原胶压裂液特性与应用前景分析[J]. 精细石油化工,2016,33(1):66-70.
[11]	MING Hua,LU Yongjun,ZHAI Wen,et al. The properties and the analysis of application prospect of xanthan gum fracturing fluid[J].Speciality Petrochemicals,2016,33(1):66-70.
[12]	霍宝玉,彭商平,于志纲,等. 一种深水水基无黏土恒流变钻井液体系[J].钻井液与完井液,2013,30(2):29-32. HUO Baoyu,PENG Shangping,YU Zhigang,et al.Deep water water-based clay-free constant rheological drilling fluid system[J]. Drilling Fluid & Completion Fluid,2013,30(2):29-32.
[13]	杜冠乐,王菲,尹东阳,等. 黄原胶的化学改性及溶液黏度特征[J]. 化学工程师,2014, 28(4):46-49. DU Guanle,WANG Fei,YIN Dongyang,et al. Chemical modification and solut ion viscosity characteristics of Xanthan gum[J]. Chemical Engineer, 2014,28(4):46-49.
[14]	李咏富,哈益明,陶乐仁,等. 辐射接枝共聚物XGg- NVP溶胀性能及其对苯酚吸附特性的研究[J]. 核农学报,2011,25(1):97-104. LI Yongfu,HA Yiming,TAO Leren,et al. Swelling and phenol absorbing property of xanthan gum-g-Nvinylpyrrolidone prepared by irradiation[J]. Journal of Nuclear Agricultural Sciences,2011,25(1):97-104.
[15]	BANERJEE J,SRIVASTAVA A,SRIVASTAVA A,et al. Synthesis and characterization of xanthan gum-g-Nvinyl formamide with a potassium monopersulfate/Ag(I) system[J]. Journal of Applied Polymer Science,2006, 101(3):1637-1645.
[16]	侯晓晖,王煦,王玉斌. 水基压裂液聚合物增稠剂的应用状况及展望[J]. 西南石油学院学报(自然科学版), 2004,26(5):60-62. HOU Xiaoxu,WANG Xu,WANG Yubin. Application and prospects of polymer thickener used in water-base fracturing fluids[J].Journal of Southwest Petroleum Institute(Science&Technology Edition),2004,26(5):60-62.
[17]	HAMCERENCU M,DESBRIERES J,POPA M,et al. New unsaturated derivatives of xanthan gum:synthesis and characterization[J].Polymer,2007,48(7):1921-1929.
[18]	TIAN Meng,FANF Bo,JIN Leiping,et al. Rheological and drag reduction properties of hydroxypropyl xanthan gum solutions[J].Chin J Chem Eng,2015,23(9):1440-1446.
[19]	张洪,卢拥军,方波,等. 阳离子黄原胶的合成及性能评价[J]. 油田化学,2017,34(1):33-37. ZHANG Hong,LU Yongjun,,FANG Bo,et al. Synthesis and property evaluation of cationic xanthan gum[J]. Oilfield Chemistry,2017,34(1):33-37.
[20]	钱晓琳,苏建政,吴文辉,等. 疏水改性黄原胶HMXGC8水溶液黏度特征[J].油田化学,2007,24(2):154-157. QIAN Xiaolin,SU Jianzheng,WU Wenhui,et al. Aqueous solution viscosity properties of hydrophobically modified xanthan gum HMXG-C8[J]. Oilfield Chemistry, 2007,24(2):154-157.
[21]	LIU S,ZHANG H,FANG B,et al. Rheological and microrheological characterization of a novel amphoteric xanthan gum[J]. Journal of Dispersion Science& Technology,2017,53(2):274-285.
[22]	蓝程程,卢拥军,邱晓惠,等. 羧甲基黄原胶溶液流变减阻特性研究[J]. 油田化学,2018(1):47-52. LAN Chengcheng,LU Yongjun,QIU Xiaohui,et al. Rheologcal and drag reduction properties of carboxymethyl xanthan gum solution[J]. Oilfield Chemistry,2018 ,35(1):47-52.
[23]	刘双,张洪,方波,等. 羧甲基羟丙基黄原胶及其流变特性[J]. 钻井液与完井液,2017,34(5):106-110. LIU Shuang,ZHANG Hong,FANG Bo,et al. Carboxymethyl hydroxypropyl xanthan gum and its rheological properties[J]. Drilling Fluid & Completion Fluid,2017,34(5):106-110.
[24]	ZHANG H,FANG B,LU Y,et al.Rheological properties of water-soluble cross-linked xanthan gum[J]. Journal of Dispersion Science & Technology,2016,38(3):361-366.
[25]	ADHIKARY P,SINGH R P. Synthesis, characterization, and flocculation characteristics of hydrolyzed and unhydrolyzed polyacylamide grafted xanthan gum[J]. J Appl Polym Sci,2004, 94(4):1411-1419.
[26]	朱仪玫,方波,卢拥军,等. 环氧氯丙烷改性纤维素溶液的流变与减阻性能[J]. 钻井液与完井液,2016, 33(6):95-100. ZHU Yimei,FANG Bo,LU Yongjun,et al. Study on the rheology and drag reducing performance of epoxy chloropropane modified cellulose solution[J]. Drilling Fluid & Completion Fluid,2016,33(6):95-100.
[27]	刘双,张洪,邱晓惠,等. 黄原胶及其衍生物的耐温耐剪切性能[J].钻井液与完井液,2018,35(1):119-123. LIU Shuang,ZHANG Hong,QIU Xiaohui,et al. Temperature resistance and shear resistance of xanthan gum and its derivatives[J]. Drilling Fluid & Completion Fluid,2018,35(1):119-123.
[28]	史璐皎.阳离子黄原胶压裂液体系及流变性能研究[D]. 北京化工大学,2017. SHI Lujiao. Study on rheological properties of cationic xanthan gum fracturing fluid system[D]. Beijing University of Chemical Technology, 2017.
[29]	苏秀霞,诸晓锋,程磊,等.黄原胶辐射接枝共聚物对Cd~2+的吸附研究[J].环境工程学报,2010,4(2):297-300. SU Xiuxia,ZHU Xiaofeng,CHENG Lei,et al. Study on adsorption behavior of xanthan gum co-irradiation graft copolymer for Cd~2+ ion[J]. Chinese Journal of Environmental Engineering,2010,4(2):297-300.

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Rheology of Triisopropanolamine Modified Xanthan Water Solution

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