Volume 35 Issue 5
Sep.  2018
Turn off MathJax
Article Contents
XIONG Min, MA Chunxu, HOU Yawei, ZHANG Hao, SHI Ligang, ZHANG Tongmei. Surface Properties of High-Performance Microbeads and Their Effects on the Performance of Cement Slurry[J]. DRILLING FLUID & COMPLETION FLUID, 2018, 35(5): 98-102. doi: 10.3969/j.issn.1001-5620.2018.05.019
Citation: XIONG Min, MA Chunxu, HOU Yawei, ZHANG Hao, SHI Ligang, ZHANG Tongmei. Surface Properties of High-Performance Microbeads and Their Effects on the Performance of Cement Slurry[J]. DRILLING FLUID & COMPLETION FLUID, 2018, 35(5): 98-102. doi: 10.3969/j.issn.1001-5620.2018.05.019

Surface Properties of High-Performance Microbeads and Their Effects on the Performance of Cement Slurry

doi: 10.3969/j.issn.1001-5620.2018.05.019
  • Received Date: 2018-07-18
  • Publish Date: 2018-09-30
  • Surface properties of high-performance hollow glass microbeads (HGM) used in cement slurry were studied using SEM, XPS, silicon molybdenum yellow spectrophotometry, turmeric paper and titration methods, and the effects of HGM on the properties of cement slurry evaluated. It was found that the particles of HGM are in spherical shapes of different sizes. Some of the spheres have cavities on their surfaces. The composition of HGM, apart from glass, includes small amount of organic coupling agents on the surfaces of HGM. Also on the surfaces of HMG are soluble adhesive substances such as sodium silicate and sodium borate. The amount of the adhesive substances is different in different batches of HGM. Too many adhesive substances on the surfaces of HGM have bad effects on the properties of cement slurry. In the adhesive substances, the soluble boron content is the main factor affecting the properties of cement slurry, and should be controlled when selecting HGM for well cementing. According to laboratory experiment, borax does not affect signifcantly the properties of cement slurry if the content of borax is less than 0.38%, thus, HGM with borax content in this range is preferred in terms of oil well cementing.

     

  • loading
  • [1]
    刘建辉, 冯建林, 许传华. 高性能空心玻璃微珠的应用研究[J]. 化学工程与装备, 2011,(5):33-35. LIU Jianhui, FENG Jianlin, XU Chuanhua. Study on the application of high performance hollow microsphere[J]. Chemical Engineering & Equipment, 2011

    (5):33-35.
    [2]
    彭寿, 王芸, 彭程, 等. 空心玻璃微珠制备方法及应用研究进展[J]. 硅酸盐通报, 2012, 31(6):1-6.

    PENG Shou, WANG Yun, PENG Cheng, et al. The Research Progress on Preparation Method and Application of Hollow Glass Microsphere[J]. Bulletin Ulletin of The Chinese Ceramic Society, 2012, 31(6):1-6.
    [3]
    张宏军. 中空玻璃微球超低密度水泥浆体系评价与应用[J]. 石油钻采工艺, 2011, 33(6):41-44.

    ZHANG Hongjun. Hollow galss particles super low density slurry evaluation and application[J]. Oil Drilling & Production Technology, 2011, 33(6):41-44.
    [4]
    马春旭, 侯亚伟, 赵琥, 等. 人造微珠表面改性及其在水泥浆中的应用[J]. 科学技术与工程, 2014, 14(6):127-129.

    MA Chunxu, HOU Yawei, ZHAO Hu, et al. Artificial microsphere surface modification and application in cement slurry[J]. Science Technology and Engineering, 2014, 14(6):127-129.
    [5]
    曾建国, 孙福全, 高永会, 等. 高温高性能低密度水泥浆的室内研究[J]. 钻井液与完井液, 2011, 28(3):47-49.

    ZENG Jianguo, SUN Fuquan, GAO Yonghui, et al. Laboratory study of high-temperature resistance and highperformance low-density cement slurry[J]. Drilling Fluid & Completion Fluid, 2011, 28(3):47-49.
    [6]
    JITEN CHATTERJI, ROGER S CROMWELL, DARREL C BRENNEIS, et al. Methods of cementing pipe in well bores and low density cement compositions therefor:United States, US6979366 B2[P]. 2005-9-27.
    [7]
    王亚平, 许春雪, 代阿芳, 等. 硅钼黄分光光度法测定地下水中偏硅酸的不确定度评定[J]. 岩矿测试, 2010, 29(5):601-606.

    WANG Yaping, XU Chunxue, DAI Afang, et al. Uncertainty evaluation for the determination of metasilicic acid in groundwater samples by molybdosilicate yellow spectrophotometry[J]. Rock and Mineral Analysis, 2010, 29(5):601-606.
    [8]
    乔蓉. 分光光度法测定炉渣中的二氧化硅[J]. 金属材料与冶金工程, 2009, 13(5):57-59.

    QIAO Rong. Determination of Silicon Dioxide in Slag by the Spectrophotometric Method[J]. Metal Materials and Metallurgy Engineering, 2009, 13(5):57-59.
    [9]
    郑瑞芝, 陈岚, 王键, 等. 硅钼黄法测定海水中硅消除P干扰的研究[J]. 海洋环境科学, 2010, 29(6):917-919.

    ZHENG Ruizhi, CHEN Lan, WANG Jian, et al. Eliminating P interference in determination of Si in seawater with silicomolybdic yellow method[J]. Marine Environmental Science, 2010, 29(6):917-919.
    [10]
    刘崇建, 黄柏宗, 徐同台, 等. 油气井注水泥理论与应用[M]. 北京:石油工业出版社, 2001. LIU Chongjian, HUANG Bozong, XU Tongtai, et al.Theory and application of cementing in oil and gas wells[M]. Beijing:Petroleum Industry Press, 2001.
    [11]
    GINTAUTAS. Effect of Na2f nSiO2 Nanodispersion on the strength and durability of portland cement matrix[J]. Materials Science, 2010, 16(1):86-93.
    [12]
    郭胜来, 步玉环, 步万荣, 等. 硅酸钠对固井施工安全的影响[J]. 中国石油大学学报(自然科学版), 2014, 38(1):105-110. GUO Shenglai, BU Yuhuan, BU Wanrong, et al. Effects of sodium silicate on safety of cementing operation[J]. Journal of China University of Petroleum, 2014, 38(1):105-110.
    [13]
    JEFFREY J T. Influence of nucleation seeding on the hydration mechanisms of tricalcium silicate and cement[J]. The Journal of Physical Chemistry, 2009, 113(11):4327-4334.
    [14]
    李海英, 姚新奎, 闫斌斌, 等. 原料乳中硼酸、硼砂快速检测方法研究[J]. 新疆农业科学, 2011, 48(1):157-159.

    LI Haiying, YAO Xinkui, YAN Binbin, et al. Study on a new method for rapid detection of boricacid and borax[J]. Xinjiang Agricultural Sciences, 2011, 48(1):157-159.
    [15]
    郑彬, 郑春梅. 分光光度法测定食品中的硼砂[J]. 现代预防医学, 2004, 31(3):446-447.

    ZHENG Bin, ZHENG Chunmei. Determination of barax in foods by spectrophotometry[J]. Modern Preventive Medicine, 2004, 31(3):446-447.
    [16]
    黄丽, 刘成梅, 罗舜菁, 等. 硼砂的危害及检测方法研究进展[J]. 食品科技, 2011. HUANG Li, LIU Chengmei, LUO Shunjing, et al. Research in borax's hazard and its detection methods[J]. Food Science & Technology, 2011.
    [17]
    邹建龙, 屈建省, 许涌深, 等. 油井水泥缓凝剂研究进展[J]. 油田化学, 2008, 25(4):386-390.

    ZOU Jianlong, QU Jiansheng, XU Yongshen, et al. Developments of retarders for oil well cementing compositions[J]. Oilfield Chemistry, 2008, 25(4):386-390.
    [18]
    和传健. 胶乳水泥浆体系的研究与应用[D]. 杭州:浙江大学材料与化学工程学院, 2002. HE Chuanjian. Research and Application of Latex Cement Slurry System[D]. Hangzhou:College of Materials Science and Chemical Engineering, Zhejiang Universit, 2002.
    [19]
    陈涓, 彭朴, 汪燮卿. 化学交联聚乙烯醇的降滤失机理[J]. 油田化学, 2002, 19(2):101-104.

    CHEN Juan, PENG Pu, WANG Xieqing. Mechanisms involved in fliud loss control of oilwell cement slurries by chemically crosslinked polyvinyl alcohol[J]. Oilfield Chemistry, 2002, 19(2):101-104.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (420) PDF downloads(180) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return