Volume 34 Issue 5
Sep.  2017
Turn off MathJax
Article Contents
Article Navigation >  DRILLING FLUID & COMPLETION FLUID  > 2017  >  34(5): 111-116
WANG Xu, JIA Wenfeng, REN Qianqian, WANG Baofeng, JIANG Tingxue, CHEN Zuo, KE Yangchuan. Development and Evaluation of a New Emulsified Gelled Acid[J]. DRILLING FLUID & COMPLETION FLUID, 2017, 34(5): 111-116. doi: 10.3969/j.issn.1001-5620.2017.05.021
Citation: WANG Xu, JIA Wenfeng, REN Qianqian, WANG Baofeng, JIANG Tingxue, CHEN Zuo, KE Yangchuan. Development and Evaluation of a New Emulsified Gelled Acid[J]. DRILLING FLUID & COMPLETION FLUID, 2017, 34(5): 111-116. doi: 10.3969/j.issn.1001-5620.2017.05.021
shu

Development and Evaluation of a New Emulsified Gelled Acid

doi: 10.3969/j.issn.1001-5620.2017.05.021

  • 1. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 100101;

  • 2. Sinopec Research Institute of Petroleum Engineering, Beijing 100101;

  • 3. China University of Petroleum, Beijing 102249

  • Received Date: 2017-05-30
  • Publish Date: 2017-09-30
    Abstract
  • Gelled acids have commonly been used as retarded acids in acid fracturing carbonate reservoirs. Gelled acids have good retarding and friction reducing performance, they cannot satisfy the requirements of deep acidification of high temperature reservoirs though, and a retarded acid with high temperature resistance and better retarding performance is required. Emulsified acids have these characteristics such as low filter loss, good retarding performance, and capable of generating long acid-eroded fractures, it is the poor high temperature stability of emulsified acids limits their application in acid fracturing operations. In this study, a gel acid and an emulsified acid were mixed together in the development of a new retarded acid, the so-called emulsified gelled acid (EGA). The formula and preparation method of an EGA resistant to 120℃ were determined through laboratory experiment. The stability, temperature resistance, high temperature rheology and acid-rock reaction have been evaluated. It showed that the EGA prepared was stable at room temperature, no segregation and demulsification have ever been observed after standing 48 hours. The EGA can maintain stable for 2 hours under 120℃. The viscosity of the EGA after sheared 80 min under 120℃ and 170 s-1 was 40 mPa·s. Kinetics of the reaction between the EGA and rocks indicated that the reaction rate of EGA with rocks was less than that of emulsified acid and gelled acid with rocks, respectively. These data demonstrate that EGA has good high temperature resistance, double retarding performance, and is worth popularizing.

     

    • FullText(HTML)
  • loading
    • References(16)
  • [1]
    李春杰,段吉国,尹仲英,等. 酸化含水油井的油外相乳化酸的研制和应用[J]. 大庆石油学院学报,2000, 24(3):37-39.

    LI Chunjie,DUAN Jiguo,YIN Zhongying,et al. Development and application of an acid/oil type emulsified acid to acidizing treatment of production well[J]. Journal of Daqing Petroleum Institute,2000, 24(3):37-39.
    [2]
    刘炜,张斌,常启新,等. 胶凝酸体系的性能研究及应用[J]. 精细石油化工进展,2013,14(1):12-14.

    LIU We i,ZHANG Bin,CHANG Qixin,et al. Performances and application of gelled acid system[J]. Advances in Fine Petrochemicals,2013,14(1):12-14.
    [3]
    张杰. 乳化酸酸液体系配方研究进展[J]. 应用化工, 2012,41(4):685-688.

    ZHANG Jie. Research progress of formula for emulsified acid fluid system[J].Applied Chemical Industry,2012, 41(4):685-688.
    [4]
    刘炜, 熊楠, 吴志鹏, 等. 缓速酸种类及乳化酸应用研究进展[J]. 精细石油化工进展,2010,11(9):12-15.

    LIU Wei,XIONG Nan,WU Zhipeng,et al. Review on types of retarded acid and application of emulsifionacid[J]. Advances in Fine Petrochemicals,2010,11(9):12-15.
    [5]
    王冬梅,张秋红,刘建梅,等. 酸液稠化剂TP-1的合成及性能[J]. 石油钻采工艺,2005,27(S1):72-73.

    WANG Dongmei,ZHANG Qiuhong,LIU Jianmei,et al. Synthetiseand performance of acid densifier TP-1[J]. Oil Drilling & Production Technology,2005,27(S1):72-73.
    [6]
    LEWIS R N. Properties and early field results of a liquid gelling agent for acid[R].SPE 7834,1978.
    [7]
    贾文峰,陈作,眭世元,等. 实验及模拟研究两性疏水缔合聚合物增黏机理[J]. 科学技术与工程,2017, 17(3):213-217.

    JIA Wenfeng,CHEN Zuo,SUI Shiyuan,et al. Thickeningmechanism of amphoteric hydrophobically associating polymerby experimental study and simulation[J].Science Technologyand Engineering, 2017,17(3):213-217.
    [8]
    车天勇,黄志宇. 抗高温乳化酸体系的实验室研制[J]. 石油与天然气化工,2004,33(4):274-277.

    CHE Tianyong,HUANG Zhiyu. Laboratory research of a new emulsified acid system[J].Chemical Engineering of Oil and Gas,2004,33(4):274-277.
    [9]
    陈红军,郭建春,赵金洲,等.W/O乳化酸体系稳定性实验研究[J]. 石油与天然气化工,2005,34(2):118-121.

    CHEN Hongjun, GUO Jianchun, ZHAO Jinzhou,et al. The research for the stability of W/O emulsifiedacid[J]. Chemical Engineering of Oil and Gas,2005,34(2):118-121.
    [10]
    周明,江万雄,陈欣,等. 一种乳化缓速酸解堵体系研究及室内评价[J]. 石油与天然气化工,2016,45(2):72-76.

    ZHOU Ming,JIANG Wanxiong,CHEN Xin,et al. Investigation and laboratory evaluation of an emulsification retarted acid solution system[J]. Chemical Engineering of Oil and Gas,2016,45(2):72-76.
    [11]
    陈磊,冯崇,宁雯宇,等. 外部因素对稠油乳状液稳定性的影响研究[J]. 当代化工,2014,43(5):691-693.

    CHEN Lei,FENG Chong,NING Wenyu,et al. Influence of external factors on heavy oil emulsion stability[J]. Contemporary Chemical Industry,2014,(5):691-693.
    [12]
    秦少雄,傅和清,张心亚,等. 乳液聚合过程中搅拌对产品质量的影响[J]. 现代涂料与涂装,2004,(4):42-43. QIN Shaoxiong,FU Heqing,ZHANG Xinya,et al. Influence of agitation during emulsion polymerization on product quality[J]. Modern Paint and Finishing,2004

    , (4):42-43.
    [13]
    袁青,李文杰,毕研霞,等. 新型耐温乳化酸的室内研制[J]. 石油化工应用,2015,34(1):111-114.

    YUAN Qing,LI Wenjie,BI Yanxia,et al. The experimental research of new emulsifiedacid with high temperature resistance[J].Petrochemical Industry Application,2015,34(1):111-114.
    [14]
    冯英,陈建波,李建波,等. 乳化酸配方室内研究[J]. 钻采工艺,2004,27(6):91-92.

    FENG Ying,CHEN Jianbo,LI Jianbo,et al. Laboratory study on emulsified acid formulation[J].Drilling & Production Technology,2004,27(6):91-92.
    [15]
    张谦, 陈大钧, 熊颖, 等. 抗高温乳化酸酸化技术的研究与应用[J]. 钻井液与完井液,2008,25(2):51-53.

    ZHANG Qian,CHEN Dajun,XIONG Ying,et al. The studies and application of acidification technology of high temperature emulsified acids[J].Drilling Fluid & Completion Fluid,2008,25(2):51-53.
    [16]
    原励,熊颖,蒋永,等.一种高温乳化酸的研制与评价[J]. 石油与天然气化工,2014,43(5):521-524.

    YUAN Li,XIONG Ying,JIANG Yong,et al. Development and evaluation of high temperature emulsified acid[J].Chemical Engineering of Oil and Gas, 2014,43(5):521-524.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (487) PDF downloads(169) Cited by()
    Proportional views
    Related

    Copyright 《Drilling Fluid & Completion Fluid》津ICP备13002319号-1

    Address：Editorial Department of Drilling Fluid and Completion Fluid, Bohai Drilling Engineering Institute, Yanshan South Road, Renqiu City, Hebei ProvinceChina Pos：062552

    Tel：（0317）2725487　2722354Email：zjyywjy@126.com

    Supported by: Beijing Renhe Information Technology Co. Ltd    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return