Volume 41 Issue 3
Jun.  2024
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Article Navigation >  DRILLING FLUID & COMPLETION FLUID  > 2024  >  41(3): 364-373
HE Minhui, YAO Ming, YAN Yubo, et al.Preparation and evaluation of an h2s corrosion inhibitor for znfe-ldhs oil well cement[J]. Drilling Fluid & Completion Fluid，2024, 41（3）：364-373 doi: 10.12358/j.issn.1001-5620.2024.03.012
Citation: HE Minhui, YAO Ming, YAN Yubo, et al.Preparation and evaluation of an h2s corrosion inhibitor for znfe-ldhs oil well cement[J]. Drilling Fluid & Completion Fluid，2024, 41（3）：364-373 doi: 10.12358/j.issn.1001-5620.2024.03.012
shu

Preparation and Evaluation of an H2S Corrosion Inhibitor for ZnFe-LDHs Oil Well Cement

doi: 10.12358/j.issn.1001-5620.2024.03.012
  • 1.

    School of New Energy and Materials, Southwest Petroleum University, Chengdu, Sichuan 610500

  • 2.

    National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500

  • 3.

    No.1 Cementing Company, CNPC Bohai Drilling Engineering Company Limited, Renqiu, Hebei 062552

  • Received Date: 2024-01-23
  • Rev Recd Date: 2024-03-02
  • Publish Date: 2024-06-30
    Abstract
  • In developing the highly acidic oil and gas resources which are abundant in China, the set cement in the wellbore will long endure the erosion of the acid media such as H2S, and the this seriously threatens the safe operation and production of the oil and gas wells. To deal with this problem, a ZnFe-LDHs type corrosion inhibitor against the corrosion by the H2S is developed through hydrothermal coprecipitation method. Set cement samples containing the selected ZnFe-LDHs are soaked in 5% Na2S solution at room temperature and 60 ℃ for 1 d, 3 d, 7 d, 14 d and 28 d, respectively. The ability of ZnFe-LDHs to resist H2S corrosion and the mechanisms of this resistance are then studied through compressive strength measurement, XRD and SEM. The study shows that the ZnFe-LDHs made at crystallization of 90 ℃ and Zn/Fe molar ratio of (1–4):1 has satisfactory corrosion control performance; it increases the compressive strength of the set cement and the compressive strength of the set cement increases with increase in the molar ratio of Zn/Fe, that is, the ZnFe-LDHs with Zn/Fe molar ratio of 4:1 has the best effect on the compressive strength of the set cement; the compressive strength of the set cement is increased by 10.11%. When the set cement sample are soaked in Na2S solution, the early strength of the set cement decreases. After soaking for 7 d, the compressive strength of the set cement soaked at room temperature and at 60 ℃ is increased by 8.73% and 4.96%, respectively. When the soaking time is longer than 7 d, the compressive strength of the set cement becomes stable, the reason for this is that ZnFe-LDHs is able to promote hydration reaction, and in the later stage of the soaking, ZnFe-LDHs react with Na2S to produce ZnS, thereby increasing the density of the set cement and preventing the corrosion of H2S to the set cement.

     

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