Preparation and Performance Evaluation of an Amine-based Silanol Shale Inhibitor
-
摘要: 针对高温深井钻井过程中钻井液用包被抑制剂耐温能力不足的问题,从改善高温下吸附能力角度出发,向超支化聚乙烯亚胺(HPEI)骨架分子中引入硅氧烷基团,研制出一种胺基硅醇抑制剂Si-HPEI,并对该抑制剂进行性能评价。结果表明,Si-HPEI抗黏土污染量达到35.0%以上,加量为0.5%的实验浆的滚动回收率达70.33%,抗温可达160℃,优于常规抑制剂。通过层间距测试、高温吸附性能、包被性能、疏水特性测试和微观形貌分析对Si-HPEI的作用机理进行分析。结果表明,分子链中引入硅氧烷的Si-HPEI水解后产生的硅羟基与黏土表面的硅羟基发生了缩聚反应,使Si-HPEI与黏土表面发生牢固地化学吸附,在高温下不易脱附,加强了黏土矿物片之间的作用力,有效包被黏土矿物,并改变黏土表面疏水性能,从而阻碍水分子侵入黏土层间而引起水化分散。
-
关键词:
Abstract: An amine-based silanol shale inhibitor Si-HPEI has been developed to deal with the problem of poor high-temperature stability of shale encapsulators encountered in high temperature deep well drilling. To improve the adsorptive capacity at elevated temperatures of a polymer, siloxane groups were introduced into the backbone of a hyperbranched polyethyleneimine (HPEI) molecule to produce an amine-based silanol shale inhibitor. Laboratory evaluation of Si-HPEI showed that Si-HPEI can tolerate clay contamination of up to 35.0%. Hot rolling test with a drilling fluid treated with 0.5% Si-HPEI gave a shale cuttings percent recovery of 70.33%. Si-HPEI functions at 160℃, making it a better high temperature shale inhibitor than conventional shale inhibitors. The working mechanisms of Si-HPEI were analyzed through laboratory experiments such as the measurement of the basal spacing of clays, the high temperature adsorption capacity, the encapsulation capacity, hydrophobicity and micromorphology. It was found in laboratory study that hydrolysis of Si-HPEI produces silanol groups which react through polycondensation with the silanol groups on the surfaces of clays, in this way the Si-HPEI is chemically adsorbed firmly on the surfaces of clay particles. This adsorption is so strong that it is not easy for the Si-HPEI molecules to detach from the clay particles and hence strengthens the forces between the clay particles, effectively encapsulates the clay particles and changes the hydrophobicity of the surfaces of the clays, thereby preventing water molecules from invading between clay platelets which causes hydration and dispersion of clays.-
Key words:
- Inhibitor /
- Drilling fluid /
- Addition agent /
- Amine-based silanol /
- Chemical adsorption
-
[1] 钟汉毅,邱正松,黄维安,等. 新型聚胺页岩水化抑制剂的研制及应用[J]. 西安石油大学学报(自然科学版),2013,28(2):72-77.ZHONG Hanyi, QIU Zhengsong, HUANG Wei'an, et al. Development and application of a new polyamine shale hydration inhibitor[J]. Journal of Xi'an Shiyou University (Natural Science Edition),2013,28(2):72-77. [2] 张洪伟, 左凤江, 田野, 等. 新型聚胺盐泥页岩抑制剂的研究及应用[J]. 油田化学,2012,29(4):390-393.ZHANG Hongwei, ZUO Fengjiang, TIAN Ye, et al. Investigation and application of new amine salt inhibitor[J]. Oilfield Chemistry,2012,29(4):390-393. [3] 郭文宇,彭波,操卫平,等. 钻井液用低聚胺类页岩抑制剂的结构与性能[J]. 钻井液与完井液,2015,32(1):26-29.GUO Wenyu, PENG Bo, CAO Weiping, et al. Molecular structure and performance of oligomeric amine shale inhibitor[J]. Drilling Fluid & Completion Fluid, 2015,32(1):26-29. [4] 宣扬,蒋官澄,宋然然,等. 超支化聚乙烯亚胺作为钻井液页岩抑制剂研究[J]. 中国石油大学学报(自然科学版),2017,41(6):178-186.XUAN Yang, JIANG Guancheng, SONG Ranran, et al. Study on hyperbranched poly(ethyleneimine) as shale inhibitor in water-based drilling fluid[J]. Journal of China University of Petroleum (Edition of Natural Science), 2017,41(6):178-186. [5] 储政. 国内聚胺类页岩抑制剂研究进展[J]. 化学工业与工程技术,2012,33(2):1-4.CHU Zheng. Research progress of polyamines shale inhibitor inland[J]. Journal of Chemical Industry & Engineering,2012,33(2):1-4. [6] 邢希金,王荐,冯桓榰,等. 新型胺基硅醇强抑制剂性能评价[J]. 石油化工应用,2015,34(12):88-91.XING Xijin, WANG Jian, FENG Huanzhi, et al. Appraise on new kind of amidocyanogen silanol inhibitor[J]. Petrochemical Industry Application,2015,34(12):88-91. [7] 邱正松,钟汉毅,黄维安. 新型聚胺抑制剂特性及作用机理[J]. 石油学报,2011,32(4):678-682.QIU Zhengson, ZHONG Hanyi, HUANG Weian. Properties and mechanism of a new polyamine shale inhibitor[J]. Acta Petrolei Sinica, 2011, 32(4):678-682. [8] 林家昱, 谢涛, 王晓鹏, 等.胺基硅醇JFC钻井液在渤海油田的应用研究[J]. 天然气与石油, 2018, 36(6):65-70.LIN Jiayu, XIE Tao, WANG Xiaopeng, et al. Research on amidocyanogen silicone JFC drilling fluid in Bohai oilfield[J].Natural Gas and Oil, 2018,36(6):65-70. [9] 张洪伟, 左凤江, 贾东民, 等.新型强抑制胺基钻井液技术的研究[J]. 钻井液与完井液, 2011, 28(1):14-17.ZHANG Hongwei, ZUO Fengjiang, JIA Dongmin, et al. Research on new strong inhibition amine based drilling fluid technology[J]. Drilling Fluid & Completion Field, 2011,28(1):14-17. [10] 褚奇, 罗平亚, 冯俊雄, 等.抗高温有机硅共聚物降滤失剂的合成与性能[J]. 石油化工, 2011, 40(9):991-996.CHU Qi, LUO Pingya, FENG Junxiong et al. Synthesis and properties of an organosilicon copolymer used as high temperature fluid loss control additive[J]. Petrochemical Technology,2011,40(9):991-996. [11] XIE Yanjun, Hill Callum A S, XIAO Zefang, et al. Silane coupling agents used for natural fiber/polymer composites:A review[J]. Composites Part A:Applied Science and Manufacturing,2010,41(7):806-819. [12] 王洪伟, 黄治华, 李新建, 等."适度抑制"及"储层保护"钻井液的研制及应用[J]. 断块油气田, 2014, 21(6):797-801.WANG Hongwei, HUANG Zhihua, LI Xinjian, et al. Development and application of drilling fluid with moderate inhibitory and reservoir protection[J].Fault-Block Oil & Gas Field,2014,21(6):797-801. [13] 张翔宇. 胺基硅醇强抑制封堵防塌钻井液体系研究与应用[J]. 天然气勘探与开发,2016,39(3):76-79.ZHANG Xiangyu. Plugging and anti-collapse drilling fluid system using amidocyanogen silanol inhibitor[J]. Natural Gas Exploration and Development, 2016,39(3):76-79. [14] 袁青松, 冯辉, 张栋, 等. 强封堵钻井液体系在河南页岩气钻井中的研究和应用[J]. 钻井液与完井液,2019, 36(1):29-35.YUAN Qingsong, FENG Hui, ZHANG Dong, et al. Study of a strong plugging drilling fluid used in shale gas drilling in He'nan province[J].Drilling Fluid & Completion Fluid,2019,36(1):29-35. [15] 张桂强,向兴金,刘霞,等. 一种硅胺基钻井液及其制备方法:CN,105670578A[P].2016-06-15.ZHANG Guiqiang, XIANG Xingjin, LIU Xia, et al. Silamine based drilling fluid and preparation method:CN,105670578A[P].2016-06-15. [16] 罗春芝, 王越支, 何晨晨, 等. 一种钻井液用聚有机硅胺抑制剂的制备方法:CN,106190062A[P]. 2016-12-07.LUO Chunzhi, WANG Yuezhi, HE Chenchen, et al. Preparation method of organic silicon amine inhibitor for drilling fluid:CN,106190062A[P].2016-12-07. [17] 褚奇,王立双,邓大伟. 一种钻井液用胺基硅醇抑制剂及制备方法:CN, 111117580A[P]. 2020-05-08.CHU Qi, WANG Lishuang, DENG Dawei. Amine silanol inhibitor for drilling fluid and preparation method:CN, 111117580A[P]. 2020-05-08. [18] 褚奇,李涛,邱在磊, 等. 一种钻井液用胺基硅醇抑制剂及制备方法:CN, 111116633A[P].2020-05-08.CHU Qi, LI Tao, QIU Zailei, et al. Amine silanol inhibitor for drilling fluid and preparation method:CN, 111116633A[P].2020-05-08. [19] PATEL A D, STAMATAKIS E, DACIS E. Shale hydration inhibition agent and method of use:US, 6484821B1[P]. 2003-08-25. [20] 钟汉毅,黄维安,邱正松,等. 聚胺与氯化钾抑制性的对比实验研究[J]. 西南石油大学学报(自然科学版), 2012,34(3):150-156.ZHONG Hanyi, HUANG Wei'an, QIU Zhengsong, et al. Experimental study of the shale inhibition between polyamine and potassium chloride[J]. Journal of Southwest Petroleum University(Science & Technology Edition),2012,34(3):150-156. [21] 褚奇,李涛,刘匡晓,等. 钻井液有机处理剂吸附性能的测定方法:CN,105277657A[P].2016-01-27.CHU Qi,LI Tao,LIU Kuangxiao,et al. Determination of adsorption properties of organic additives for drilling fluids:CN,105277657A[P].2016-01-27.
点击查看大图
计量
- 文章访问数: 470
- HTML全文浏览量: 141
- PDF下载量: 60
- 被引次数: 0