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油基钻井液劣质固相絮凝剂双十六烷基二甲基氯化铵

景岷嘉,  李武泉,  蒋官澄

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文章导航 > 钻井液与完井液  > 2021 >  38(2): 164-169
景岷嘉, 李武泉, 蒋官澄. 油基钻井液劣质固相絮凝剂双十六烷基二甲基氯化铵[J]. 钻井液与完井液, 2021, 38(2): 164-169. doi: 10.3969/j.issn.1001-5620.2021.02.006
引用本文: 景岷嘉, 李武泉, 蒋官澄. 油基钻井液劣质固相絮凝剂双十六烷基二甲基氯化铵[J]. 钻井液与完井液, 2021, 38(2): 164-169. doi: 10.3969/j.issn.1001-5620.2021.02.006
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JING Minjia, LI Wuquan, JIANG Guancheng. Research on Dihexadecyldimethyl Ammonium Chloride As A Poor Solid flocculant for Oil-based Drilling Fluid[J]. DRILLING FLUID & COMPLETION FLUID, 2021, 38(2): 164-169. doi: 10.3969/j.issn.1001-5620.2021.02.006
Citation: JING Minjia, LI Wuquan, JIANG Guancheng. Research on Dihexadecyldimethyl Ammonium Chloride As A Poor Solid flocculant for Oil-based Drilling Fluid[J]. DRILLING FLUID & COMPLETION FLUID, 2021, 38(2): 164-169. doi: 10.3969/j.issn.1001-5620.2021.02.006
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油基钻井液劣质固相絮凝剂双十六烷基二甲基氯化铵

doi: 10.3969/j.issn.1001-5620.2021.02.006

  • 1. 中国石油集团川庆钻探工程有限公司钻采工程技术研究院, 四川广汉 618300;

  • 2. 中国石油大学(北京)油气资源与探测国家重点实验室, 北京 102249;

  • 3. 中国石油大学(北京)石油工程教育部重点实验室, 北京 102249

详细信息
    作者简介:

    景岷嘉,工程师,硕士,1982年生,毕业于西南石油大学应用化学专业,现在从事钻井液技术研究工作。电话(0838)5151116;E-mail:jingmj_ccde@cnpc.com.cn

  • 中图分类号: TE254.4

Research on Dihexadecyldimethyl Ammonium Chloride As A Poor Solid flocculant for Oil-based Drilling Fluid

  • 1. Drilling & Production Technology Research Institute of CCDE, Guanghan, Sichuan 618300;

  • 2. State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum(Beijing), Beijing 102249;

  • 3. MOE Key Laboratory of Petroleum Engineering, China University of Petroleum(Beijing), Beijing 102249

    摘要
  • 摘要: 劣质固相对油基钻井液的性能影响大，且由于其粒径小难以被固控设备清除。絮凝剂能通过絮凝作用增大劣质固相粒径，但几乎都用于水基钻井液而少有用于油基钻井液。以高岭土作为油基钻井液劣质固相，通过静置观察、浊度分析、显微镜观察等方法，研究了双十六烷基二甲基氯化铵（DCDAC）对高岭土的絮凝作用。结果表明，DCDAC能加快高岭土的沉降速度，当加量为5%时，高岭土在48 h后基本沉淀完毕；静置5 h后，高岭土悬浮液的浊度降低率接近80%；通过光学显微镜观察发现，当DCDAC加量不小于4%时，高岭土出现明显的团聚行为；通过体系实验发现，离心后油基钻井液的密度及固相含量与DCDAC加量成反比，固相清除率与DCDAC的加量成正比，塑性黏度与动切力随着DCDAC的增加呈现出先降低后增大的趋势，说明DCDAC对油基钻井液中的高岭土有良好的絮凝作用，可用于清除油基钻井液中的劣质固相。

     

    Abstract: Drilled cuttings of low quality have great influence on the properties of oil base drilling fluids and are difficult to remove because of their small particle sizes. Flocculants can be used to enlarge the particle sizes of the drilled cuttings through flocculation but are generally used in water base drilling fluid and seldomly are used in oil base drilling fluids. An oil base drilling fluid contaminated with kaolin as the poor-quality solids was studied for the flocculating performance of dihexadecyl dimethyl ammonium chloride (DCDAC) to flocculate kaolin. Observation of the contaminated and DCDAC treated oil base drilling fluid under stationary state, turbidity analysis and observation under microscope of the drilling fluid showed that DCDAC is able to accelerate the settling of kaolin particles; at 5% of DCDAC in the kaolin containing oil base drilling fluid, all the kaolin particles settled to the bottom in 48 hours. After kept stationary for 5 hours, the percent decrease of the turbidity of a kaolin suspension was nearly 80%. Observation under microscope of the drilling fluid showed that when the concentration of DCDAC in the oil base drilling fluid was greater than or equal to 4%, the kaolin particles showed obvious agglomeration behavior. It was also found in the laboratory experiment that the density and solids content of an oil base drilling fluid after centrifugation are inversely proportional to the concentration of DCDAC, while the percent removal of solids is in direct proportion to the concentration of DCDAC. With the increase of the concentration of DCDAC in the oil base drilling fluid, the plastic viscosity and yield point of the drilling fluid were first decreasing and then increasing. All these phenomena shown in laboratory experiment indicate that DCDAC has good flocculating capacity to kaolin in oil base drilling fluids, and can be used in removing low quality solids from oil base drilling fluids.

     

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    • 参考文献(16)
  • [1] DEARING HARRY, SIMPSON JAY, HUDDLE DOUG, et al. Flexible drilling fluid formulation and application[J]. AADE-04-DF-HO-28, 2004:6-7.
    [2] 鄢捷年. 钻井液工艺学[M]. 北京:中国石油大学出版社, 2006:314-339. YAN Jienian. Drilling fluid technology[M]. Beijing:China University of Petroleum Press, 2006:314

    -339.
    [3] HART P J, SNYDER R K. Method for on-site treatment of oil and gas well waste fluids:US, US7022240 B2[P]. 2006.
    [4] 陈永红, 刘光全, 许毓. 化学破乳法处理废弃油基泥浆室内实验研究[J]. 石油与天然气化工, 2012, 41(5):522-525.

    CHEN Yonghong, LIU Guangquan, XU Yu. Laboratory experiment research on waste oil-based drilling fluid treatment with chemical demulsification[J]. Chemical Engineering of Oil and Gas, 2012, 41(5):522-525.
    [5] 王星媛, 欧翔, 明显森. 威202H3平台废弃油基钻井液处理技术[J]. 钻井液与完井液, 2017, 34(2):64-69.

    WANG Xingyuan, OU Xiang, MING Xiansen. Disposing waste oil base drilling fluid from the Wei202H3 platform[J]. Drilling Fluid & Completion Fluid, 2017, 34(2):64-69.
    [6] 苏勤, 何青水, 张辉, 等. 国外陆上钻井废弃物处理技术[J]. 石油钻探技术, 2010, 38(5):106-110.

    SU Qin, HE Qingshui, ZHANG Hui, et al. Foreign onshore drilling waste treatment technology[J]. Petroleum Drilling Techniques, 2010, 38(5):106-110.
    [7] 卓龙成, 王波, 张金焕, 等. 苏北盆地ZC油田废弃钻井液再利用调剖工艺[J]. 石油钻探技术, 2018,46(4):109-114.

    ZHUO Longcheng, WANG Bo, ZHANG Jinhuan, et al. Profile control for wasted drilling fluid recycling in ZC oilfield of the Subei basin[J].Petroleum Drilling Techniques, 2018, 46(4):109-114.
    [8] 李学庆, 杨金荣, 尹志亮, 等. 油基钻井液含油钻屑无害化处理工艺技术[J]. 钻井液与完井液, 2013, 30(4):81-83.

    LI Xueqing, YANG Jinrong, YIN Zhiliang, et al. Novel Harmless Treating Technology of Oily Cuttings[J]. Drilling Fluid & Completion Fluid, 2013, 30(4):81-83.
    [9] 凡帆, 杨斌, 吴满祥. 页岩气油基钻屑萃取处理技术[J]. 钻井液与完井液, 2018, 35(5):78-82.

    FAN Fan, YANG Bin, WU Manxiang. Extraction Disposal of Oil Cuttings in Shale Gas Drilling[J]. Drilling Fluid & Completion Fluid, 2018, 35(5):78-82.
    [10] 付雄涛, 吴洪特, 汪军, 等. 废弃油基钻井液中油相回收室内研究[J]. 钻井液与完井液, 2013, 30(3):34-36.

    FU Xiongtao, WU Hongte, WANG Jun, et al. Research on Oil Separation from Waste Oil-base Drilling Fluid[J]. Drilling Fluid & Completion Fluid, 2013, 30(3):34-36.
    [11] 陈刚, 王鹏, 赵毅, 等. 废弃钻井液处理技术研究与应用进展[J]. 钻井液与完井液, 2020, 37(1):1-8.

    CHEN Gang, WANG Peng, ZHAO Yi, et al.Progress in study and application of waste mud disposal technologies[J].Drilling Fluid & Completion Fluid, 2020, 37(1):1-8.
    [12] 王建瑶, 曾建国, 孙富全, 等. 一种油井水泥用抗分散絮凝剂[J]. 钻井液与完井液, 2018, 35(5):90-93.

    WANG Jianyao, ZENG Jianguo, SUN Fuquan, et al. Study on a dispersion resistant flocculant used in oil well cement slurry[J].Drilling Fluid & Completion Fluid, 2018, 35(5):90-93.
    [13] 赵俊, 孙泽宁, 王景, 等. 一种环保型钻井液絮凝剂的研制与评价[J]. 钻井液与完井液, 2020, 37(4):427-430.

    ZHAO Jun, SUN Zening, WANG Jing, et al.The development and evaluation of an environmentally friendly drilling flocculant[J].Drilling Fluid & Completion Fluid, 2020, 37(4):427-430.
    [14] 谢水祥, 蒋官澄, 陈勉, 等. 废弃油基钻井液资源回收与无害化处置[J]. 环境科学研究, 2011(5):68-75. XIE Shuixiang, JIANG Guancheng, CHEN Mian, et al. Resource recycling and harmless treatment for waste oil-based drilling fluid[J]. Research of Environmental Sciences, 2011

    (5):68-75.
    [15] 李振泉, 王增林, 张磊, 等. 阳离子和两性表面活性剂对石英表面润湿性的影响[J]. 高等学校化学学报, 2011, 32(10):23-27.

    LI Zhenquan, WANG Zenglin, ZHANG Lei, et al. Effects of cationic and zwitterionic surfactants on wetting of quartz surfaces[J]. Chemical Journal of Chinese Universities, 2011, 32(10):23-27.
    [16] GU X, ZHANG F, LI Y, et al. Investigation of cationic surfactants as clean flow improvers for crude oil and a mechanism study[J]. Journal of Petroleum Science & Engineering, 2018, 164:87-90.
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  • 收稿日期:  2020-10-13

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