Study and Application of a Double Esterified Modified Starch Filter Loss Reducer
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摘要: 针对常规改性淀粉黏度效应大、抗温能力差的缺点,采用酯化改性方式,以醋酸酐、三偏磷酸钠和玉米淀粉为原材料,合成出一种双酯化改性淀粉降滤失剂BZ-JLS,该产品具有良好的分散性和降滤失效果。室内研究结果表明,在150℃老化16 h后,加入1.5% BZ-JLS的基浆常温中压滤失量仅为9.4 mL,而且BZ-JLS具有良好的抗盐抗钙能力,生物毒性、生物降解性及金属含量等均符合环保指标。BZ-JLS在大港油区现场试验1口井,现场应用表明,BZ-JLS与淡水、盐水钻井液均具有良好的配伍性,钻井液黏度变化低,滤失量降低明显。Abstract: Conventional modified starch as a filter loss reducer, has the shortcomings of high viscosity effect and poor temperature stability. A double-esterified starch filter loss reducer BZ-JLS was developed to overcome these shortcomings. BZ-JLS was synthesized with acetic anhydride, sodium trimetaphosphate and corn starch. BZ-JLS has good dispersion capacity and filtration control property. Laboratory study showed that a base mud treated with 1.5% BZ-JLS after aging at 150 ℃ for 16 hours had API fluid loss of only 9.4 mL. BZ-JLS also shows good resistance to salt and calcium contamination. The biological toxicity, biodegradation property and metal content all meet the environmental requirements. Field application on a well drilled in Dagang Oilfield showed that BZ-JLS had good compatibility with fresh water and salt water. The mud was only slightly viscosified, while the filtration rate was significantly reduced.
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Key words:
- Drilling fluid /
- Esterification /
- Starch /
- Filtrate reducer /
- Environmental protection
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