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三乙醇胺改性羟丙基瓜胶溶液流变性能

汤鲁馨,  方波,  张晓琪,  王依晴

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文章导航 > 钻井液与完井液  > 2020 >  37(3): 389-393
汤鲁馨, 方波, 张晓琪, 王依晴. 三乙醇胺改性羟丙基瓜胶溶液流变性能[J]. 钻井液与完井液, 2020, 37(3): 389-393. doi: 10.3969/j.issn.1001-5620.2020.03.021
引用本文: 汤鲁馨, 方波, 张晓琪, 王依晴. 三乙醇胺改性羟丙基瓜胶溶液流变性能[J]. 钻井液与完井液, 2020, 37(3): 389-393. doi: 10.3969/j.issn.1001-5620.2020.03.021
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TANG Luxin, FANG Bo, ZHANG Xiaoqi, WANG Yiqing. Research on Rheological Properties of Triethanolamine Modified Hydroxypropyl Guar Gum Solution[J]. DRILLING FLUID & COMPLETION FLUID, 2020, 37(3): 389-393. doi: 10.3969/j.issn.1001-5620.2020.03.021
Citation: TANG Luxin, FANG Bo, ZHANG Xiaoqi, WANG Yiqing. Research on Rheological Properties of Triethanolamine Modified Hydroxypropyl Guar Gum Solution[J]. DRILLING FLUID & COMPLETION FLUID, 2020, 37(3): 389-393. doi: 10.3969/j.issn.1001-5620.2020.03.021
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三乙醇胺改性羟丙基瓜胶溶液流变性能

doi: 10.3969/j.issn.1001-5620.2020.03.021

  • 华东理工大学化工学院流变学研究室, 上海 200237

基金项目: 

国家科技重大专项课题“储层改造关键流体研发”（2017ZX05023003）

详细信息
    作者简介:

    汤鲁馨,1995年生,华东理工大学在读研究生

    通讯作者:

    方波,教授,华东理工大学化学工程专业博士,主要从事化工流变学、流变学减阻、油田压裂液流变学等领域的研究。电话(021)64253361,E-mail:fangbo@ecust.edu.cn

  • 中图分类号: TE357.12

Research on Rheological Properties of Triethanolamine Modified Hydroxypropyl Guar Gum Solution

  • Laboratory of Chemical Engineering Rheology, East China University of Science and Technology, Shanghai 200237

    摘要
  • 摘要: 以三乙醇胺改性羟丙基瓜胶为稠化剂，三异丙醇胺/乳酸/丙三醇有机锆为交联剂，获得了交联凝胶。研究了交联凝胶流变性能及改性羟丙基瓜胶溶液交联过程流变性能，获得了黏度和黏弹性模量随时间的变化关系，考察了温度对交联过程的影响；并首次应用核磁共振成像分析仪研究了静态交联过程溶液性能，获得了弛豫时间随时间的变化关系。结果表明，交联凝胶具有明显的黏弹性和触变性，携砂性能良好；三乙醇胺改性羟丙基瓜胶溶液交联过程中黏度及黏弹性模量随时间的变化曲线可用4-参数交联过程流变动力学模型描述； 4-参数静态交联过程动力学方程能较好地描述静态交联过程中弛豫时间随时间的变化关系，模型参数具有明确的物理意义。

     

    Abstract: A crosslinked gel was obtained by using triethanolamine-modified hydroxypropyl guar gum as a thickener, and triisopropanolamine/lactic acid/glycerol organic zirconium as a crosslinking agent. The rheology properties of the cross-linked gels and the crosslinking processes of triethanolamine-modified hydroxypropyl guar solution were studied. The viscosity and viscoelastic modulus varying with time in crosslinking process were obtained. The effects of temperature on the crosslinking process were investigated. The solution properties in static cross-linking processes were studied by NMR imaging analyzer, and the relationship of relaxation time varying with time was obtained. The results show that the gels demonstrate obvious viscoelasticity and thixotropy and have good sand-carrying properties. The viscosity and viscoelastic modulus of the modified solution varying with time during the crosslinking process can be described by 4-parameter crosslinking process rheokinetic equation. And 4-parameter static cross-linking process kinetic equation can better describe the relaxation time varying with time in static cross-linking process. The model parameters have clear physical meaning.

     

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    • 参考文献(17)
  • [1] 侯慧玉, 曾广胜. 磺酰卤基羟丙基瓜尔胶的合成及其性能[J]. 合成树脂及塑料, 2017, 34(5):54-56

    , 64. HOU Huiyu, ZENG Guangsheng. Synthesis and properties of sulfonyl halide hydroxypropyl guar gum[J].China Synthetic Resin and Plastics, 2017, 34(5):54-56, 64.
    [2] 徐亮, 张龙, 杨建州. 瓜尔胶及其衍生物的应用研究进展[J]. 华东纸业, 2011, 42(3):51-54.

    XU Liang, ZHANG Long, YANG Jianzhou. Application research progress of guar gum and its ramitication[J]. Shanghai Paper Making, 2011, 42(3):51-54.
    [3] 王依晴, 闫俊妤, 方波, 等. 十二叔胺改性瓜尔胶交联过程的流变性质[J]. 油田化学, 2019, 36(1):68-73.

    WANG Yiqing, YAN Junyu, FANG Bo, et al. Crosslinking of dodecyl dimethyl tertiary amine modified guar gum and its rheological properties[J].Oilfield Chemistry, 2019, 36(1):68-73.
    [4] 王梓民, 吕雷, 张淑侠. 制备接枝共聚羟丙基瓜胶的新工艺[J]. 应用化工, 2016, 45(10):1922-1925.

    WANG Zimin, LYU Lei, ZHANG Shuxia. The new technology on preparation of graft copolymerized hydroxypropyl guar gum[J]. Applied Chemical Industry, 2016, 45(10):1922-1925.
    [5] 袁长忠, 潘永强, 杜春安, 等. 胜利油田瓜胶压裂液返排液回收利用水质指标[J]. 钻井液与完井液, 2016, 33(5):109-113.

    YUAN Changzhong, PAN Yongqiang, DU Chunan, et al. Quality index of water for recycling flowback fluid of guar gum fracturing fluid in Shengli oilfield[J].Drilling Fluid & Completion Fluid, 2016, 33(5):109-113.
    [6] Food Research; Reports from School of Agriculture Highlight Recent Findings in Food Research (Optimization of Quality Properties of Gluten-Free Bread by a Mixture Design of Xanthan, Guar, and Hydroxypropyl Methyl Cellulose Gums)[J].Food Weekly News, 2019.
    [7] KIM J H, MIN H J, PARK K, et al. Preparation and evaluation of a cosmetic adhesive containing guar gum[J]. Korean Journal of Chemical Engineering, 2017, 34(8):2236-2240.
    [8] HIREMATH J N, VISHALAKSHI B. Evaluation of a pH-responsive guar gum-based hydrogel as adsorbent for cationic dyes:kinetic and modelling study[J].Polymer Bulletin, 2015, 72(12):3063-3081.
    [9] POINOT T, GOVIN A, GROSSEAU P. Influence of hydroxypropylguars on rheological behavior of cementbased mortars[J].Cement and Concrete Research, 2014, 58:161-168.
    [10] GAURAV SHARMA, SHWETA SHARMA, AMIT KUMAR, et al. Guar gum and its composites as potential materials for diverse applications:A review[J]. Carbohydrate Polymers, 2018, 199.
    [11] 战振生, 尹恒, 杜彬, 等. 羟丙基瓜尔胶在离子液体中的制备[J]. 化学研究与应用, 2012, 24(9):1461-1464.

    ZHAN Zhensheng, YIN Heng, DU Bin, et al. Preparation of hydroxypropyl guar gum in ionic liquid[J]. Chemical Research and Application, 2012, 24(9):1461-1464.
    [12] 王克, 殷勤俭, 江波. 羟丙基瓜尔胶的制备及表征[J]. 化学研究与应用, 2004, 16(1):73-75.

    WANG Ke, YIN Qinjian, JIANG Bo. Preparation and characterization of hydroxypropyl guar gum[J]. Chemical Research and Application, 2004, 16(1):73-75.
    [13] 王江涛, 乌永兵, 营虎虎. 检测羟丙基瓜尔胶表观黏度影响因素的研究讨论[J]. 辽宁化工, 2017, 46(7):634-636.

    WANG Jiangtao, WU Yongbin, YING Huhu. Study on factors affecting the detection result of apparent viscosity of hydroxypropyl guar[J].Liaoning Chemical Industry, 2017, 46(7):634-636.
    [14] Ma M, Fang B, Lu Y, et al. Intrinsic rheo-kinetics on gelation process of hydrophobic amphoteric cellulose[J]. Journal of Dispersion Science and Technology, 2016, 37(8):1076-1082.
    [15] 樊悦, 金浩, 方波, 等. 芥酸酰胺丙基二甲基叔胺改性纤维素溶液的流变性能与交联性能[J]. 油田化学, 2019, 36(2):209-214.

    FAN Yue, JIN Hao, FANG Bo, et al. Rheological properties of erucamidopropyl dimethylamine modified carboxymethyl hydroxyethyl cellulose solutions[J]. Oilfield Chemistry, 2019, 36(2):209-214.
    [16] 吴磊, 崔伟香, 晏军, 等. 低温低伤害瓜胶压裂液破胶技术研究[J]. 应用化工, 2019, 48(4):834-837.

    WU Lei, CUI Weixiang, YAN Jun, et al. Research of gel breaking technology for low damage gum fracturing fluid at low temperature[J]. Applied Chemical Industry, 2019, 48(4):834-837.
    [17] 严芳芳, 方波, 卢拥军, 等. 有机锆交联羟丙基瓜胶流变动力学[J].高校化学工程学报, 2015, 29(4):802-808.

    YAN Fangfang, FANG Bo, LU Yongjun, et al. Rheokinetics of organic zirconium crosslinked hydroxypropyl guar gels[J].Journal of Chemical Engineering of Chinese Universities, 2015, 29(4):802-808.
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出版历程
  • 收稿日期:  2019-12-30
  • 刊出日期:  2020-06-28

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