A Method for Evaluating the Thermal Stability of Cement Slurry Polymer Additives Based on Ubbelohde Viscometer Method
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摘要: 高温深井固井质量难以保证,其中一个重要原因是高温下水泥浆综合性能难以保证。目前多使用外加剂调节水泥浆高温性能,这类外加剂多为聚合物。高温下水泥浆的沉降稳定性、滤失量通过使用降失水剂进行调节,稠化时间通过使用缓凝剂进行调节。随着井深增加,井底温度和压力逐渐升高,高温下水泥浆的沉降稳定性、失水及稠化时间调控难度加大,然而少有对聚合物外加剂本身耐温性能的评价方法。因此基于高温下聚合物溶液黏度降低的机理,通过乌氏黏度计评价聚合物溶液黏度变化,推荐一种聚合物外加剂耐温能力评价方法,即测量外加剂高温养护前后分子量变化率(△M),△M绝对值越趋于0,表明耐温性能越好,以此指导高温固井注水泥工作中聚合物外加剂的优选。Abstract: An important cause for the quality of cementing high temperature and deep wells to be difficult to maintain is that the integrated performance of a cement slurry at elevated temperatures is difficult to maintain. Presently the high temperature performance is generally adjusted using cement additives, which are generally polymers. The settling stability and filtration rate of a cement slury at high temperatures are maintained with filter loss reducers, while the thickening time of a cement slurry is adjusted with retarding agents. As a well is drilling deeper and deeper, the downhole temperature and pressure are increasing, and it becomes more and more difficult to control the settling stability, filtration rate and thickening time of a cement slurry. Even so the methods of evaluating the performance of these polymer additives are rarely seen. A method is recommended for use in evaluating the thermal stability of polymer additives. This method is based on the mechanism of viscosity reduction of polymers at elevated temperatures and an Ubbelohde viscometer is used to measure the change of viscosity. By measuring the rate of change of molecular weight of additives before and after aging at a certain high temperature, △M, the thermal stability of a polymer can be measured; when △M is approaching zero, the thermal stability is good. This measurement can be used to guide the selection of high temperature cement slurry additives.
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Key words:
- Cement slurry /
- Filter loss reducer /
- Retarding agent /
- Temperature tolerance /
- Ubbelohde viscometer
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[1] 杨勇, 戴建文, 林荣壮, 等. 高温水泥浆沉降稳定性[J]. 钻井液与完井液, 2010, 27(6):55-57.YANG Yong, DAI Jianwen, LIN Rongzhuang, et al. Sedimentation stability of high temperature cement slurry[J]. Drilling Fluid & Completion Fluid, 2010, 27(6):55-57. [2] 严思明. 新型耐温油井水泥降失水剂体系的研究[D]. 西南石油大学, 2006. YAN Siming. Study on a new type of cement fluid loss agent system for oil wells[D]. Southwest Petroleum University, 2006 [3] 王振军, 何廷树. 缓凝剂作用机理及对水泥混凝土性能的影响[J]. 公路, 2006(7):149-154. WANG Zhenjun, HE Tingshu. The action mechanism of retarder and its effect on the performance of cement concrete[J]. Highway, 2006(7):149-154. [4] 郭胜来. 深井长封固段水泥浆体系关键技术研究[D]. 中国石油大学(华东), 2013. GUO Shenglai. Study on key technology of cement slurry system in long cementing section of deep well[D]. China University of Petroleum(Huadong), 2013. [5] 复旦大学高分子科学系. 高分子实验技术(第二版)[M]. 上海, 1996:22-27. Macromolecule Science College of Fudan University. Macromolecule experiment[M]. Shanghai, 1996:22-27. [6] 何冬月. 粘度法测定驱油用聚丙烯酰胺分子量常见问题分析[J]. 中国石油和化工标准与质量, 2011, 31(11):69. HE Dongy ue. Analysis of common problems in determination of molecular weight of polyacrylamide for oil displacement by viscosity method[J]. China Petroleum and Chemical Standard and Quality, 2011, 31(11):69. [7] API RP 10B油井水泥实验推荐方法[S]. 第22版, 1997. API RP 10B Recommended method for testing well cement[S]. Version 22, 1997. -

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