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纳米碳酸钙的制备及在水基钻井液的应用研究

武元鹏,  田应佩,  罗平亚,  林元华

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文章导航 > 钻井液与完井液  > 2019 >  36(4): 407-413
武元鹏, 田应佩, 罗平亚, 林元华. 纳米碳酸钙的制备及在水基钻井液的应用研究[J]. 钻井液与完井液, 2019, 36(4): 407-413. doi: 10.3969/j.issn.1001-5620.2019.04.002
引用本文: 武元鹏, 田应佩, 罗平亚, 林元华. 纳米碳酸钙的制备及在水基钻井液的应用研究[J]. 钻井液与完井液, 2019, 36(4): 407-413. doi: 10.3969/j.issn.1001-5620.2019.04.002
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WU Yuanpeng, TIAN Yingpei, LUO Pingya, LIN Yuanhua. Preparation of Nanoparticle Calcium Carbonate and Study of Its Use in Water Base Drilling Fluids[J]. DRILLING FLUID & COMPLETION FLUID, 2019, 36(4): 407-413. doi: 10.3969/j.issn.1001-5620.2019.04.002
Citation: WU Yuanpeng, TIAN Yingpei, LUO Pingya, LIN Yuanhua. Preparation of Nanoparticle Calcium Carbonate and Study of Its Use in Water Base Drilling Fluids[J]. DRILLING FLUID & COMPLETION FLUID, 2019, 36(4): 407-413. doi: 10.3969/j.issn.1001-5620.2019.04.002
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纳米碳酸钙的制备及在水基钻井液的应用研究

doi: 10.3969/j.issn.1001-5620.2019.04.002

  • 1. 西南石油大学 材料科学与工程学院, 成都 610500;

  • 2. 油气藏地质及开发工程国家重点实验室, 成都 610500

基金项目: 

四川省青年科技基金（2016JQ0036），教育部霍英东青年教师基金（161103），四川省科技厅项目（2018GZYZF0073），成都市国际科技合作项目（2017-GH02-00005-HZ）

详细信息
    作者简介:

    武元鹏,教授,中国科学院成都有机化学研究所高分子化学与物理专业博士,主要研究方向为油气田用功能纳米材料;电话(028)83037404;E-mail:ypwu@swpu.edu.cn

  • 中图分类号: TE254.4

Preparation of Nanoparticle Calcium Carbonate and Study of Its Use in Water Base Drilling Fluids

  • 1. School of Materials Science and Engineering, Southwest Petroleum University, Chengdu, Sichuan 610500;

  • 2. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Chengdu, Sichuan 610500

    摘要
  • 摘要: 为了改善水基钻井液流变和滤失性能，采用表面原位聚合法制备了阴离子聚丙烯酰胺（APAM）表面修饰的碳酸钙纳米颗粒（CaCO3/APAM），并将其用于改善水基钻井液性能。对CaCO3/APAM结构进行了红外光谱（FTIR）、扫描电镜（SEM）等表征。流变和滤失实验表明，纳米颗粒的加入有效地提高了水基钻井液在低剪切速率下的黏度，钻井液剪切稀释性能得到提高。在80℃下，添加1% CaCO3/APAM的水基钻井液流性指数为0.72，动切力为0.45 Pa，滤失量为22.2mL，与基浆相比有显著改善。钻井液耐盐滤失表明，当盐浓度为1%时，添加1% CaCO3/APAM使钻井液滤失量降低了21.2%。滤饼微观形貌分析显示纳米颗粒通过填充于滤饼微孔隙中提高了滤饼致密性，使得滤失量下降。

     

    Abstract: To improve the rheology and filtration property of water base drilling fluids, a nanoparticle calcium carbonate surface modified with anionic polyacrylamide (APAM), CaCO3/APAM, has been prepared through surface in-situ polymerization. The CaCO3/APAM was characterized using FTIR and SEM to determine its molecular structures. In laboratory experiment, a water base drilling fluid treated with CaCO3/APAM had increased viscosity at low shear rate, indicating that the addition of CaCO3/APAM is helpful in improving the shear-thinning property of water base drilling fluids. At 80℃, a water base drilling fluid treated with 1% CaCO3/APAM had flow index of 0.72, yield point of 0.45 Pa and filter loss of 22.2 mL, three properties that were better than those of the base fluid. Addition of 1% CaCO3/APAM in a water base drilling fluid containing 1% salt reduced the filter loss of the drilling fluid by 21.2%. Analysis of the micro-structure of the mud cake showed that the nanoparticles, by filling into the spaces among the particles forming the mud cakes, improved the compactness of the mud cakes, thereby reducing the filter loss of the mud.

     

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出版历程
  • 收稿日期:  2019-05-05
  • 刊出日期:  2019-08-30

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