树枝状聚合物在钻井液中的应用研究进展

钟汉毅; 高鑫; 邱正松; 郭保雨; 赵冲; 沈广成

doi:10.3969/j.issn.1001-5620.2019.04.001

树枝状聚合物在钻井液中的应用研究进展

doi: 10.3969/j.issn.1001-5620.2019.04.001

钟汉毅^1,2,
高鑫^1,2,
邱正松^1,2,
郭保雨³,
赵冲⁴,
沈广成^1,2

1. 非常规油气开发教育部重点实验室, 山东青岛 266580;
2. 中国石油大学(华东) 石油工程学院, 山东青岛 266580;
3. 中石化胜利石油工程有限公司钻井工艺研究院, 山东东营 257064;
4. 中国石油集团渤海钻探泥浆技术服务分公司, 天津 300280

基金项目:

“十三五”国家科技重大专项“耐高温钻井液、压裂液性能控制方法研究”（2017ZX05005005-006），国家自然科学基金青年基金“基于压力控制靶向释放的微胶囊化钻井液润滑剂制备及作用机理”（51704322），山东省自然科学基金“超支化聚合物修饰的纳米二氧化硅设计、制备及稳定页岩作用机理”（ZR2017QEE011）

详细信息

作者简介:
钟汉毅,博士,副教授,毕业于中国石油大学(华东)油气井工程专业,研究方向为钻井液与完井液基础理论与技术。电话18853248274;E-mail:zhonghanyi@126.com

中图分类号: TE254.4
计量
- 文章访问数: 725
- HTML全文浏览量: 228
- PDF下载量: 294
- 被引次数: 0
出版历程
- 收稿日期: 2019-04-05
- 刊出日期: 2019-08-30

Progress in Applying and Studying Dendrimers in Drilling Fluids

1. MOE Key Laboratory of Unconventional Oil and Gas Development, Qingdao, Shandong 266580;
2. School of Petroleum Engineering, China University of Petroleum, Qingdao, Shandong 266580;
3. Drilling Technology Research Institute of Shengli Petroleum Engineering Co. Ltd. of Sinopec, Dongying, Shandong 257064;
4. Drilling Fluid Technology Services of CNPC Bohai Drilling Engineering Company Limited, Dagang, Tianjin 300280

摘要

摘要: 随着油气钻探领域的拓展，钻遇地层条件愈加复杂，为满足现代钻井工程"安全、快速、环保、高效"的技术要求，对当前钻井液处理剂的性能提出了更高的要求。树枝状聚合物以其独特的分子结构和优异的性能引起了人们广泛的关注，在众多领域都具备潜在的应用价值。笔者介绍了树枝状聚合物的分子结构特点、性能和主要合成方法，概述了树枝状聚合物应用于钻井液中的研究进展，分析了其在钻井液中的应用潜力，并对其在钻井液中的发展前景进行了展望，旨在为开发新型高效钻井液处理剂提供新的思路和方法。
- 树枝状聚合物 /
- 分子结构 /
- 页岩抑制剂 /
- 钻井液 /
- 井眼
Abstract: More and more complex formations are drilled presently to find more oil and gas. To satisfy the needs of modern drilling engineering for "safety, fast operation, environment protection and high efficiency", higher requirements are imposed on drilling fluid additives. Dendrimers with their unique molecular structures and superior properties, are finding more application in many fields. This paper introduces the characteristics of the molecular structure, the performance and main synthetic methods of dendrimers, summarizes the progresses made in the research work of applying dendrimers in drilling fluid, analyzes the potential of dendrimers applied in drilling fluid, and explains the vision of the authors for the development of dendrimers in drilling fluid industry in the future. This paper is aimed at providing new clues and new methods of developing novel high-performance drilling fluid additives.
- Dendrimer /
- Molecular structure /
- Shale inhibitor /
- Drilling fluid /
- Borehole

HTML全文

参考文献(66)

[1]	TOMALIA D A, BAKER H, DEWALD J, et al.A new class of polymers:starburst-dendritic macromolecules[J]. Polymer Journal, 1985(17):117-132.
[2]	KOJIMA C, REGINO C, UMEDA Y, et al.Influence of dendrimer generation and polyethylene glycol length on the biodistribution of PEGylated dendrimers[J]. International Journal of Pharmceutics, 2010(383):293-296.
[3]	REYES E A.Applications and laboratory studies of a new class of silica polymerization inhibitors of biorenewable origin[J].SPE 143662, 2011.
[4]	WANG J, SUN K, HAO W, et al.Structure and properties research on montmorillonite modified by flame-retardant dendrimer[J].Applied Clay Science, 2014(90):109-121.
[5]	EICHLER M, KATZUR V, SCHEIDELER L, et al. The impact of dendrimer-grafted modifications to model silicon surfaces on protein adsorption and bacterial adhesion[J].Biomaterials, 2011(32):9168-9179.
[6]	KAWAGUCHI T, WALKER K L, WⅡKINS C L, et al. Double exponential dendrimer growth[J].Journal of the American Chemical Society, 1995, 117(8):2159-2165.
[7]	GAO C, YAN D.Hyperbranched polymers:from synthesis to applications[J].Progress in Polymer Science, 2004, 29(3):183-275.
[8]	KORKOSZ R J, GILBERTSON J D, PRASIFKA K S, et al.Dendrimer templates for supported au catalysts[J]. Catalysis Today, 2007, 122(3):370-377.
[9]	SU P, WANG S, SHI Y, et al.Application of cellulose-polyamidoamine dendrimer-modified silica for microwave-assisted chitosan enzymolysis[J].Process Biochemistry, 2013, 48(4):614-619.
[10]	TOMALIA D A, FRÉCHET J M J.Discovery of dendrimers and dendritic polymers:a brief historical perspective[J].Journal of Polymer Science Part A Polymer Chemistry, 2002, 40(16):2719-2728.
[11]	迟瑞娟. 改性聚酰胺-胺的合成及破乳性能的研究[D]. 青岛:中国海洋大学, 2010. CHI Ruijuan.Studies on synthesis and demulsification performance of modified polyamidoamine[D].Qingdao:Ocean University of China, 2010.
[12]	顾惠民, 罗运军. 树枝形聚合物[M]. 北京:化学工业出版社, 2002. GU Huimin, LUO Yunjun.Dendritic polymers[M]. Beijing:Chemical Industry Press, 2002.
[13]	程冬玲. 树状大分子PAMAM的合成、表征和阻垢性能研究[D]. 青岛:中国石油大学(华东), 2009. CHENG Dongling.Synthesis, characterization, and antiscalant application of PAMAM dendrimers[D].Qingdao:China University of Petroleum (East China), 2009.
[14]	陈荣圻. 树枝状聚合物及其在染颜料工业中的应用初探[J]. 印染助剂, 2013, 30(2):1-12. CHEN Rongqi.Discussion on dendrimer and its application in dyes and pigments industry[J].Textile Auxiliaries, 2013, 30(2):1-12.
[15]	FRÉCHET J M J.Dendrimers and other dendric macromolecules:from building blocks to functional assembles in nanosciences and nanotechnology[J].Journal of Polymer Science Part A Polymer Chemistry, 2003, 41(23):3713-3725.
[16]	DECKER J J, CHVALUN S N, NAZARENKO S. Intercalation behavior of hydroxylated dendritic polyester in polymer clay nanocomposites prepared from aqueous solution[J].Polymer, 2011, 52(18):3943-3955.
[17]	JUANG T Y, CHEN Y C, TSAI C C, et al.Nanoscale organic/inorganic hybrids based on self-organized dendritic macromolecules on montmorillonites[J].Applied Clay Science, 2010(48):103-110.
[18]	FRÉCHET J M.Functional polymers and dendrimers:reactivity, molecular architecture, and interfacial energy[J].Science, 1994, 263(5154):1710-1715.
[19]	马茶, 李龙, 孙金声, 等. 含丹磺酰基树枝状化合物研究进展[J]. 有机化学, 2011, 31(12):1977-1988. MA Cha, LI Long, SUN Jinsheng, et al.Recent progress in dansyl-based dendrimers[J].Chinese Journal of Organic Chemistry, 2011, 31(12):1977-1988.
[20]	GRAYSON S M, FRÉCHET J M J.Convergent dendrons and dendrimers:from synthesis to applications[J]. Chemical Reviews, 2001, 101(12):3819-3867.
[21]	BOSMAN A W, JANSSEN H M, MEIJER E W. About dendrimers:structure, physical properties, and applications[J].Chemical Reviews, 1999, 99(7):1665-1688.
[22]	李龙, 马茶, 苑旭波, 等. 树枝状聚合物的合成及其在油田化学中的应用[J]. 现代化工, 2012, 32(6):16-21. LI Long, MA Cha, YUAN Xubo, et al.Synthesis and application of dendrimers in oilfield chemistry[J].Modern Chemical Industry, 2012, 32(6):16-21.
[23]	ZHANG Y N, ZHANG J Z, DU D L, et al.Preparation and characterization of dendritic amino polymers[J]. Procedia Engineering, 2011(18):19-24.
[24]	彭晓春, 彭晓宏, 赵建青, 等. 改性聚酰胺-胺阳离子树状聚合物的制备、表征及其絮凝脱水性能的研究[J]. 石油化工, 2005, 34(10):986-989. PENG Xiaochun, PENG Xiaohong, ZHAO Jianqing, et al.Preparation and characterization of novel polyamideamine modified cationic dendrimer and its flocculating and dewatering performances[J].Petrochemical Technology, 2005, 34(10):986-989.
[25]	DECKER J J, CHVALUN S N, NAZARENKO S. Intercalation behavior of hydroxylated dendritic polyesters in polymer clay nanocomposites preparation from aqueous solution[J].Polymer, 2011, 52(18):3943-3955.
[26]	郑性能, 叶仲斌, 郭拥军, 等. 两种聚酰胺-胺长链烷基季铵盐的合成和黏土稳定性能[J]. 油田化学, 2009, 26(1):38-41. ZHENG Xingneng, YE Zhongbin, GUO Yongjun, et al.Synthesis and clay stabilizing ability of ploy (amidoamine)quarternary ammonium salts with long chain alkyl groups[J].Oilfield Chemistry, 2009, 2(61):38-41.
[27]	刘长环, 曲红杰, 吕玲玲, 等. 一种树枝型聚醚的合成及其防蜡性能研究[J]. 化学与生物工程, 2008, 25(11):22-24. LIU Changhuan, QU Hongjie, LYU Lingling, et al.The synthesis of dendritic polyether and study on performance for paraffin control[J].Chemistry & Bioengineering, 2008, 25(11):22-24.
[28]	REYES E A.Applications and laboratory studies of a new class of silica polymerization inhibitors of bio-renewable origin[J].SPE 143662, 2011.
[29]	MILLER R F.Shale hydration inhibition agents and method of use:US, 8026198[P], 2011-09-27.
[30]	AMANULLAH M, ARAMCO A.Dendrimers and dendritic polymers-application for superior and intelligent fluid development for oil and gas field applications[J]. SPE 164162, 2013.
[31]	马英杰. 低聚酰胺-胺的合成及其抑制黏土膨胀性能研究[D]. 西安:西安石油大学, 2012. MA Yingjie.Synthesis and inhibiting clay expansion research of PAMAM[D].Xi'an:Xi'an Shiyou University, 2012.
[32]	O·拉富恩特塞尔达, B·布鲁赫曼, S·迈特罗-沃格尔, 等. 超支化聚赖氨酸作为页岩抑制剂的用途:CN, 103917623A[P], 2014-07-09. OSCAR L C, BERND B, SOPHIE M V, et al. Application of hyperbranched polylysine as a shale inhibitor.CN, 103917623A[P], 2014-07-09.
[33]	张国, 徐江, 詹美玲, 等. 新型聚胺水基钻井液研究及应用[J]. 钻井液与完井液, 2013, 30(3):23-26. ZHANG Guo, XU Jiang, ZHAN Meiling, et al. Research and application of polyamine water-based drilling fluid system[J].Drilling Fluid & Completion Fluid, 2013, 30(3):23-26.
[34]	TEIXEIRA G T, LOMBA R F T, FRANCISCO A D D S, et al.Hyperbranched polyglycerols, obtained from environmentally benign monomer, as reactive clays inhibitors for water-based drilling fluids[J].Journal of Applied Polymer Science, 2014, 131(12):1-7.
[35]	钟汉毅, 邱正松, 黄维安, 等.PAMAM树枝状聚合物抑制泥页岩水化膨胀和分散特性[J]. 中南大学学报(自然科学版), 2016, 47(12):4132-4140. ZHONG Hanyi, QIU Zhengsong, HUANG Weian, et al. Properties of PAMAM dendrimers in inhibiting shale hydration and dispersion[J].Journal o f Central South University(Science and Technology), 2016, 4(712):4132-4140.
[36]	ZHONG Hanyi, QIU Zhengsong, TANG Zhichuan, et al.Minimization shale hydration with the combination of hydroxyl-terminated PAMAM dendrimers and KCl[J]. Journal of Materials Science, 2016, 51(18):8484-8501.
[37]	TEIXEIRA G T, LOMBA R F T, FRANCISCO A D D S, et al.Hyperbranched polyglycerols, obtained from environmentally benign monomer, as reactive clays inhibitors for water-based drilling fluids[J]. Journal of Applied Polymer Science, 2014, 131(12):40384-40390.
[38]	宋然然, 蒋官澄, 宣扬, 等. 超支化聚乙烯亚胺作为高效水基钻井液页岩抑制剂的研究[J]. 油田化学, 2017, 34(3):390-396. SONG Ranran, JIANG Guancheng, XUAN Yang, et al. Hyper-branched polyethyleneimine using as efficient shale inhibitor for water-based drilling fluid[J].Oilfield Chemistry, 2017, 34(3):390-396.
[39]	宣扬, 蒋官澄, 宋然然, 等. 超支化聚乙烯亚胺作为钻井液页岩抑制剂研究[J]. 中国石油大学学报(自然科学版), 2017, 41(6):178-186. XUAN Yang, JIANG Guancheng, SONG Ranran, et al. Study on hyper-branched poly(ethyleneimine)as shale inhibitor in water-based drilling fluid[J].Journal of China University of Petroleum(Edition of Natural Science), 2017, 41(6):178-186.
[40]	BAI X, WANG H, LUO Y, et al.The structure and application of amine-terminated hyperbranched polymer shale inhibitor for water-based drilling fluid[J].Journal of Applied Polymer Science, 2017:45466.
[41]	王昊. 页岩气水基钻井液用超支化聚胺结构与性能研究[D]. 成都:西南石油大学, 2017. WANG Hao.Study on structure and properties of hyperbranched polyamines for shale gas-water drilling fluids[D].Chengdu:Southwest Petroleum University, 2017.
[42]	WANG Hao, PU Xiaolin.Structure and inhibition properties of a new amine-terminated hyperbranched oligomer shale inhibitor[J].Journal of Applied Polymer Science, 2019:136(21):47573.
[43]	谢刚, 罗平亚, 邓明毅. 一种超低分子量树枝状烷基六胺页岩抑制剂及其合成方法:CN, 106380407B[P], 2017-02-08. XIE Gang, LUO Pingya, DENG Mingyi.An ultra low molecular weight dendritic alkyl 6 amine shale inhibitor and synthetic method:CN, 106380407B[P], 2017-02-08.
[44]	XIE Gang, LUO Pingya, DENG Mingyi, et al. Hyperbranched polyamine as nano-plugging agent used in water-based drilling fluid[J].Nanoscience & Nanotechnology Letters, 2017, 29(5):506-513.
[45]	徐琳, 邓明毅, 郭拥军, 等.纳米封堵剂在钻井液中的应用进展研究[J]. 应用化工, 2016, 45(4):742-746. XU Lin, DENG Mingyi, GUO Yongjun, et al. Research on application of nano-plugging agent in drilling fluid[J]. Applied Chemical Industry, 2016, 4(54):742-746.
[46]	徐琳, 邓明毅, 郭拥军, 等. 纳米SiO₂接枝超支化聚酰胺的合成及性能评价[J]. 石油化工, 2016, 45(11):1352-1356. XU Lin, DENG Mingyi, GUO Yongjun, et al. Synthesis and performance evaluation of nano SiO₂ grafted with hyper-branched polyamide[J].Petrochemical Technology, 2016, 45(4):1352-1356.
[47]	张海冰, 邓明毅, 马喜平, 等. 端氨基超支化聚合物泥页岩抑制剂的合成与性能评价[J]. 石油化工, 2016, 45(9):1081-1086. ZHANG Haibing, DENG Mingyi, MA Xiping, et al. Synthesis and performance evaluation of aminoterminated hyperbranched polymer as shale inhibitor[J]. Petrochemical Technology, 2016, 45(9):1081-1086.
[48]	XIE G, LUO P, DENG M, et al.Hyperbranched polyamine as nano-plugging agent used in water-based drilling fluid[J].Nanoscience & Nanotechnology Letters, 2017, 29(5):506-513.
[49]	徐琳. 纳米SiO₂接枝超支化聚合物的合成及其在钻井液中的应用[D]. 成都:西南石油大学, 2017. XU Lin.Synthesis of nano-SiO₂ grafted hyperbranched polymer and its application in drilling fluid[D].Chengdu:Southwest Petroleum University, 2017.
[50]	王中华. 高性能钻井液处理剂设计思路[J]. 中外能源, 2013, 18(1):36-46. WANG Zhonghua.The design ideas for high-performance drilling fluid additives[J].Sino-Global Energy, 2013, 18(1):36-46.
[51]	王中华. 钻井液用超支化反相乳液聚合物的合成及其性能[J]. 钻井液与完井液, 2014, 31(3):14-18. WANG Zhonghua.Property of hyperbranched polymer synthesized through inverse emulsion polymerization[J]. Drilling Fluid & Completion Fluid, 2014, 31(3):14-18.
[52]	王中华. 一种超支化共聚物及其制备方法和应用:CN, 104250358[P].2014-12-31. WANG Zhonghua.A hyperbranched multi-polymer and its preparation method and application:CN, 104250358[P].2014-12-31.
[53]	张丽君, 王旭, 胡小燕, 等. 抗260℃超高温水基钻井液体系[J]. 钻井液与完井液, 2015, 32(4):5-8. ZHANG Lijun, WANG Xu, HU Xiaoyan, et al.Ultrahigh temperature water base drilling fluid[J].Drilling Fluid & Completion Fluid, 2015, 32(4):5-8.
[54]	刘书杰, 李相方, 邢希金, 等. 新型天然气水合物动力学抑制剂的研制与性能评价[J]. 中国海上油气, 2015, 27(6):69-73. LIU Shujie, LI Xiangfang, XING Xijin, et al. Development and performance evaluation of a new kinetic hydrate inhibitor[J].China Offshore Oil and Gas, 2015, 27(6):69-73.
[55]	陈玉川, 史博会, 李文庆, 等. 水合物动力学抑制剂的作用机理研究进展[J]. 化工进展, 2018, 37(5):1726-1743. CHEN Yuchuan, SHI Bohui, LI Wenqing, et al. Progress of influence mechanism of kintetic hydrate inhibitors[J].Chemical Industry and Engineering Progress, 2018, 37(5):1726-1743.
[56]	KLOMP U C.Method for inhibiting the pluggings of conduits by gas hydrates:US, 20030057158[P].2003.
[57]	LUCA D V, MALCOLM A K.Tetrahydrofuran hydrate crystal growth inhibition by hyperbranched poly(ester amide)s[J].Chemical Engineering Science, 2009, 64(13):3197-3200.
[58]	KLOMP U C.Method for inhibiting the plugging of conduits by gas hydrates:US, 6905605[P].2005-06-14.
[59]	KELLAND M A, MADY M F.Acylamide and amine oxide derivatives of linear and hyperbranched polyethylenimines. Part 1:comparison of tetrahydrofuran hydrate crystal growth inhibition performance[J].Energy & Fuels, 2016(30):3934-3940.
[60]	MARTIN F, HELENE K V.Gas hydrate inhibitor, method and use of hyperbranched polyester polyols as gas hydrate inhibitors:US, 20150252246[P].2015.
[61]	RIVERS G T, TIAN J, TRENERY J B.Kinetic gas hydrate inhibitors in completion fluids:US, 8048827[P]. 2011-11-01.
[62]	LIRIO Q, DAVID E C ANTONIO E C, et al.Denritic surfactants and extended surfactants for drilling fluid formulations:US, 20120241220[P].2012-09-27.
[63]	BALLARD D A.Highly Branched polymeric materials as coating on weighting agents:US, 7786053[P]. 2010-08-31.
[64]	SHI H, JIANG G C, WANG K, et al.Synthesis of a dendrimer as rheological modifier for deep-water drilling fluids and study of its interaction with organo-clay at different temperatures[J].Key Engineering Materials, 2018(792):111-118.
[65]	迟瑞娟, 毕彩丰, 赵宇, 等. 改性聚酰胺破乳剂的合成及破乳性能的研究[J]. 中国海洋大学学报, 2010, 40(8):107-110. CHI Ruijuan, BI Caifeng, ZHAO Yu, et al.The synthesis of M-polamidoamine demuslsifier and its demulsification for the O/W simulated oil-polluted water[J]. Periodical of Ocean University of China, 2010, 40(8):107-110.
[66]	王学川, 胡艳鑫, 郑书杰, 等. 超支化聚合物絮凝剂的合成与表征[J]. 精细石油化工, 2011, 28(3):36-40. WANG Xuechuan, HU Yanxin, ZHENG Shujie, et al. Synthesis and characterization of polymer flocculants[J]. Speciality Petrochemicals, 2011, 28(3):36-40.