A Dispersion Resistant Flocculant used in Oil Well Cement Slurry
-
摘要: 国内油田注水区块频发的水侵,严重地破坏了水泥石强度和胶结质量。针对该问题,采用自由基聚合的方式合成出一种适用于油井水泥的抗分散絮凝剂BCY-100S。通过Zeta电位分析和热重分析测定了BCY-100S的絮凝性和耐热性,并评价了其对水泥浆抗水侵性能的作用和稠化性能。结果表明,BCY-100S耐温可达324℃,加入BCY-100S的水泥浆具备一定絮凝性,能够在80℃下,受到水的冲刷作用而不离析、不分散,与未加入BCY-100S的普通水泥浆相比,具有显著的抗水冲刷性能。除此之外,抗分散絮凝剂BCY-100S对稠化时间无影响,符合油井水泥性能要求。为各油田解决地层流体对水泥浆“溶解迁移”和“质量互换”的问题提供了一种新的方法。Abstract: Frequent water invasion in water injection blocks in China gravely undermine the strength and bonding quality of set cement. A dispersion resistant flocculant BCY-100S has been developed to deal with these problems. BCY-100S is produced through radical polymerization and is used in preparing cement slurries for oil well cementing. The flocculating capacity and heat resistance of BCY- 100S were measured through zeta-potential analysis and TGA. The effects of BCY-100S on the performance of cement slurry to resist water invasion and on the thickening property of cement slurry were tested. It was found that BCY-100S functions normally at temperatures up to 324℃. Cement slurries treated with BCY-100S have to some flocculating ability. The BCY-100S treated cement slurries did not disperse or segregate when flushed with water at 80℃. Compared with cement slurries that were not treated with BCY- 100S, the cement slurries treated with BCY-100S were able to resist water flooding. BCY-100S does not affect the thickening time of cement slurry, which is a requirement of oil well cement property. Considering the effects of formation fluids on set cement, such as "migration after dissolution" and "mass interchange", the use of BCY-100S has provided a new method of resolving these problems.
-
Key words:
- Well cementing /
- Dispersion resistance /
- Flocculant /
- Thickening property
-
[1] 邱燮和. 超浅调整井固井防水窜技术[J]. 钻井液与完井液, 2013, 30(4):84-87.QIU Xiehe.Water block cementing technology for ultrashallow adjustment wells[J].Drilling Fluid & Completion Fluid, 2013, 30(4):84-87. [2] 姚晓. 中国油田调整井固井防水窜技术评述[J]. 钻采工艺, 2002, 25(1):17-20.YAO Xiao.Evaluation of technology of preventing water channeling during cementing of adjustment well in china[J].Drilling & Production Technology,2002,25(1):17-20. [3] 姚晓. 调整井固井水窜的根源及现行防窜技术评析[J]. 钻井液与完井液, 2001, 18(5):13-16.YAO Xiao.Causes of water channeling during cementing and its preventing technology[J].Drilling Fluid & Completion Fluid, 2001, 18(5):13-16. [4] 邬钢, 巢贵业, 高春华. 镇-泾油田防水窜固井工艺技术难点及对策[J]. 科技情报开发与经济, 2008, 18(24):128-130.WU Gang, CHAO Guiye, GAO Chunhua.Analysis and countermeasure of cementing technology in zhenjing oilfield[J].Sci-Tech Information Development & Economy, 2008, 18(24):128-130. [5] 孙美华, 李心武.89105井膨胀水泥防水窜固井工艺[J]. 石油钻采工艺, 2007, 37(S1):37-39.SUN Meihua, LI Xinwu.Anti-channeling cementing technology of expansion cement for well no 89105[J].Oil Drilling & Production Technology, 2007, 37(S1):37-39. [6] 刘娟. 水下不分散混凝土抗分散剂的研究[D]. 长沙:湖南大学, 2005. LIU Juan.The research on anti-washout admixture of nondispersive underwater concrete[D].Chang Sha:Hunan Uniyersity, 2005. [7] 任拓. 水下不分散混凝土的工程应用[D]. 大连:大连理工大学, 2002. REN Tuo.The research on engineering application of non-dispersive underwater concrete[D].Dalian:Dalian University of Technology, 2002. [8] 冯爱丽, 覃维祖, 王宗玉. 絮凝剂品种对水下不分散混凝土性能影响的比较. 石油工程建设,2002,28(4):6-10.FENG Aili, QIN Weizu, WANG Zongyu.Comparison of some kinds of wadding congeal that influence the property of non-scattering concrete[J].Petroleum Engineering Construction, 2002, 28(4):6-10. -

计量
- 文章访问数: 669
- HTML全文浏览量: 196
- PDF下载量: 223
- 被引次数: 0