Rheological Improvement of Nano-phase Silicon Cement Slurry with Polyglycol
-
摘要: 为解决纳米硅水泥浆冷浆极强触变性的问题,测量了聚乙二醇PEG200、PEG400、PEG600加入纳米硅水泥浆,且加量分别为1%、2%和3%时的冷浆流变读数,通过对比静切力、塑性黏度和动切力优选出最优配量的PEG,对比了加入最优配量PEG前后,纳米硅水泥石性能的变化,并从反应机理方面分析了纳米硅乳液加入PEG前后的红外光谱图。结果显示,加量为2%的PEG200对纳米硅水泥浆触变性的改善效果最好,触变性改善效果提高5倍以上,加入2% PEG200前后的纳米硅水泥石性能基本一致;PEG与纳米二氧化硅的作用机理不仅有氢键作用,还有醚键配位作用,能够改善纳米二氧化硅防气窜水泥浆的触变性。研究结果表明,加量为2%的PEG200解决了纳米硅水泥浆冷浆极强触变性的问题,同时也保证了纳米硅水泥浆原有的性能。Abstract: To resolve the very high thixotropy problem encountered in using nanometer silicon cement slurry, three cement slurries were treated with 1%, 2% and 3% of PEG200, PEG400 and PEG600, respectively, and their rheological properties were tested and measured. The optimum concentration of PEG was determined by comparison of gel strength, plastic viscosity and yield point of the three cement slurries. The properties of the set nanometer silicon cement slurries before and after treatment with the optimized concentration of PEG were compared, and the IR spectrogram of the nanometer silicon emulsion before and after treatment with PEG were analyzed from the point of view of reaction mechanism. It was found that the properties of the set nanometer silicon cement slurry remained unchanged before and after being treated with 2% PEG200, indicating that addition of 2% PEG200 is best for improving the thixotropy of nanometer silicon cement slurry, the efficiency of thixotropy improvement was increased by more than 5 times. It was also found that the mechanisms of the PEG-nanometer SiO2 reaction include not only hydrogen bonding, but also ether bonding, both of which improve the thixotropy of the anti-channeling nanometer SiO2 cement slurry. Treatment of nanometer silicon cement slurry with 2% PEG200 resolved the very high thixotropy problem associated with nanometer silicon cement slurry, and the original properties of the cement slurry can also be maintained.
-
Key words:
- Nanometer silicon cement slurry /
- Thixotropy /
- Nanometer silicon emulsion /
- Polyglycol
-
[1] 何毅, 白锦锦, 姚文宇, 等. 纳米二氧化硅改性固井用胶乳水泥体系性能研究[J]. 应用化工, 2016(3):445-449. HE Yi, BAI Jinjin, YAO Wenyu, et al. Properties of nano-silica modified cemented cement cement system[J]. Chemical Industry, 2016(3):445-449. [2] 李茂英, 李加林, 曾庆军. 纳米硅粉改善水泥土抗腐蚀性能机理研究[J]. 路基工程, 2008(5):40-42. LI Maoying, LI Jialin, ZENG Qingjun. Study on mechanism of nano-silicon fly to improve cement-soil anti-corrosion performance[J]. Subgrade Engineering, 2008(5):40-42. [3] 王统利, 郑黎明, 董柯, 等. 纳米二氧化硅制备及在环境领域的应用[J]. 辽宁化工, 2018(3):245-247. WANG Tongli, ZHENG Liming, DONG Ke, et al. Preparation of nano-silica and its application in environmental field[J]. Liaoning Chemical Industry, 2018(3):245-247. [4] 王鹏程. 纳米二氧化硅的分散与表面改性[D]. 广州:华南理工大学, 2011. WANG Pengcheng. Dispersion and surface modification of nano-silica[D]. Guangzhou:South China University of Technology, 2011. [5] 中国石油集团工程技术研究院. 油井水泥试验方法. 中华人民共和国国家质量监督检验检疫总局;中国国家标准化管理委员会[S]. 2012:164. China National Petroleum Corporation Engineering and Technology Research Institute. Oil well cement test methods. The General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; China Standardization Administration[S]. 2012:164. [6] 褚奇, 杨枝, 李涛, 等. 硅烷偶联剂改性纳米SiO2封堵剂的制备与作用机理[J]. 钻井液与完井液, 2016,33(4):47-50.ZHU Qi, YANG Zhi, LI Tao, et al. Preparation and action mechanism of silane coupling agent modified nano-SiO2 sealing agent[J]. Drilling Fluid & Completion Fluid, 2016,33(4):47-50. [7] 陈和生, 孙振亚, 邵景昌. 八种不同来源二氧化硅的红外光谱特征研究[J]. 硅酸盐通报, 2011(4):934-937. CHEN Hesheng, SUN Zhenya, SHAO Jingchang. Infrared spectral characteristics of eight different sources of silica[J]. Journal of Silicate Notification, 2011(4):934-937. [8] 孟凡宁, 齐永新, 于晶, 等. 聚丁二烯型聚氨酯/纳米二氧化硅弹性体的制备及红外光谱表征[J]. 合成橡胶工业, 2016(5):400-403. MENG Fanning, QI Yongxin, YU Jing, et al. Preparation and characterization of polybutadiene-based polyurethane/nano-silica elastomer[J]. Synthetic Rubber Industry, 2016(5):400-403. [9] 张建斌, 李强, 刘占英, 等. 聚乙二醇及其水溶液吸收SO2机理研究[J]. 化学工程, 2010(12):76-79. ZHANG Jianbin, LI Qiang, LIU Zhanying, et al. Mechanism of SO2 absorption by polyethylene glycol and its aqueous solutions[J]. Chemical Engineering, 2010(12):76-79. [10] 赵晓坤. 浅谈影响红外吸收光谱强度的因素[J]. 内蒙古石油化工, 2007(12):179-181. ZHAO Xiaokun. Factors influencing the intensity of infrared absorption spectra[J]. Inner Mongolia Petrochemical Industry, 2007(12):179-181. -

计量
- 文章访问数: 661
- HTML全文浏览量: 156
- PDF下载量: 233
- 被引次数: 0