非酸解堵技术在渤海油田的应用

张丽平; 张璐; 兰夕堂; 刘长龙; 邹剑; 高尚

doi:10.3969/j.issn.1001-5620.2018.02.019

非酸解堵技术在渤海油田的应用

doi: 10.3969/j.issn.1001-5620.2018.02.019

中海石油(中国)有限公司天津分公司, 天津 300452

基金项目:

国家重大专项课题"渤海油田高效采油工程及配套技术示范"（2016ZX05058003）。

详细信息

作者简介:
张丽平,工程师,1987年,2008年毕业于中国石油大学(北京)石油工程专业,现从事油田增产措施相关研究工作。电话15922173026;E-mail:zlp0317@126.com。

中图分类号: TE357.2
计量
- 文章访问数: 786
- HTML全文浏览量: 237
- PDF下载量: 216
- 被引次数: 0
出版历程
- 收稿日期: 2017-10-05
- 刊出日期: 2018-03-30

Application of Non-acid Block Removing Technology in Bohai Oilfield

Tianjin Branch of CNOOC, Tanggu, Tianjin 300452

摘要

摘要: 针对渤海油田疏松砂岩储层常规酸化易导致储层岩石骨架破坏，且受管柱结构和修井作业的限制残酸无法及时返排产生二次沉淀，同时高电导率的返排液无法直接进入处理流程，严重制约酸化工艺现场应用等问题，研究出一种兼顾油层解堵和油层保护，且具备较低残液电导率的非酸解堵体系。该体系主要含有20%复合多羧基螯合剂A及5%含氟络合物C，缓慢释放出H⁺、F^-，体系pH值在6~7之间，具有高效缓速性，同时有效保护岩石骨架，通过螯合金属离子达到阻垢抑垢、减少二次沉淀的效果，且具有较低的腐蚀性，返排液具备较低的离子浓度及电导率，可实现返排残酸直接进入平台流程就地、高效地处理。该体系在渤海油田进行了现场试验，效果显著，具有良好的应用前景。
- 油井酸化 /
- 缓速溶蚀 /
- 二次沉淀 /
- 反应残液 /
- 电导率
Abstract: A non-acid block removing fluid has been developed to deal with several problems encountered in the development of unconsolidated sandstone reservoirs in Bohai oilfield. The problems include failure of rock matrices in conventional acidizing job, secondary precipitation caused by residue acids that are unable to timely flow back because of the limits from configuration of pipe string and workover jobs, and flowback fluids with high electric conductivity that cannot be directly disposed of. All these problems pose serious restrictions on reservoir acidizing operations. The newly developed non-acid block removing fluid is also able to protect the reservoir from being damaged. The residue of this non-acid block removing fluid has lower electric conductivity. The non-acid block removing fluid, containing 20% compound polycarboxylic chelating agent A and 5% fluorine complex C, can slowly release H⁺ and F^-, and maintain its pH value between 6 and 7, showing high retarding property and capability of protecting rock matrices. By chelating metallic ions, scales are prohibited and secondary precipitation is minimized. The non-acid block removing fluid has low corrosivity, and the flowback fluid has low ionic concentrations and electric conductivity, which are beneficial to the on-the-spot and efficient disposal of the flowback residue acid in the platform process. This non-acid block removing fluid has been tried out in Bohai oilfield with remarkable efficiency, showing good application prospect.
- Oil well acidizing /
- Unconsolidated sandstone /
- Retarding /
- Secondary precipitation /
- Electric conductivity

HTML全文

参考文献(13)

[1]	苏崇华. 疏松砂岩储层伤害机理及应用——以HND-1/2为例[D]. 成都:西南石油大学,2011. SU Chonghua.Loose sand reservoir damage mechanismand its application to HND-1/2 oilfields[D]. Cheng Du:Southwest Petroleum University,2011.
[2]	徐加放,李小迪,孙泽宁,等. 疏松砂岩储层敏感性评价方法[J]. 中国石油大学学报(自然科学版), 2014,38(5):130-134. XU Jiafang,LI Xiaodi,SUN Zening,et al.Evaluation methodology of formation sensitivity for unconsolidated sandstones[J].Journal of China University of Petroleum, (Natural science edition),2014,38(5):130-134.
[3]	李丹,伊向艺,王彦龙,等. 压裂用纳米体膨颗粒裂缝封堵性能实验研究[J]. 钻井液与完井液,2017,34(4):112-116. LI Dan,YI Xiangyi,WANG Yanlong,et al. Experimental study on fracture plugging performance of volumetric expansion nano particles used in well fracturing[J].Drilling Fluid & Completion Fluid,2017, 34(4):112-116.
[4]	陈朝晖,谢一婷,邓勇. 疏松砂岩油藏出砂应力敏感实验研究[J]. 石油钻探技术,2013,41(1):61-64. CHEN Zhaohui,XIE Yiting,DENG Yong. Experimental study on sanding stress sensitivity in unconsolidated sandstone reservoirs[J].Petroleum Drilling Techniques,2013,41(1):61-64.
[5]	田野. 高升油田多氢酸酸化技术研究及应用[D]. 大庆:东北石油大学,2016. TIAN Ye.Application of mulit-hydrogen acid acidify cation in gaosheng oil field[D].Da Qing:Northeast Petroleum University,2016.
[6]	汪本武,刘平礼,张璐,等. 一种单步法在线酸化酸液体系研究及应用[J]. 石油与天然气化工,2015,44(3):79-83. WANG Benwu,LIU Pingli,ZHANG Lu,et al. Research and application of a single step online acidification acid system[J].Chemical Engineering of Oil & Gas,2015,44(3):79-83.
[7]	郭海军,段明,张健,等. 酸化返排液对原油乳化液稳定性的影响[J]. 油田化学,2008,25(2):130-133. GUO Haijun,DUAN Ming,ZHANG Jian,et al.Study on stability of crude oil emul sions influenced by acidizing returns[J].Oilfield Chemistry,2008,25(2):130-133.
[8]	刘平礼,兰夕堂,王天慧,等. 砂岩储层酸化的新型螯合酸液体系研制[J]. 天然气工业,2014,34(4):72-75. LIU Pingli,LAN Xitang,WANG Tianhui,et al. Development and research of a novel chelating acid system for sandstone reservoir acidification[J].Matual Gas Industry,2014,34(4):72-75.
[9]	CAO Yingxia, YANG Jian,LI Jie.Study of inhibition hedp and pbtoa[J].Journal of Tongji University, 2004, 32(4):556-560.
[10]	ALSABAGH A M,MIGAHED M A,AWAD H S. Reactivity of polyester aliphatic amine surfactants as corrosion inhibitors for carbon steel in formation water (deep well water)[J]. Corrosion Science,2006,48(4):813-828.
[11]	许帅. 咪唑啉型缓蚀剂的合成及性能评价[D]. 成都:西南石油大学, 2016. XU Shuai.Synthetise and performance evaluation of imidazoline corrosion inhibitors[D].Chen Du:Southwest Petroleum University,2016.
[12]	马红,黄达全,李广环,等. 瓜胶压裂返排液重复利用的室内研究[J]. 钻井液与完井液,2017,34(4):122-126. MA Hong,HUANG Daquan,LI Guanghuan,et al. Laboratory study on recycling of flowback fluid of guar gun fracturing fluid[J].Drilling Fluid & Completion Fluid,2017,34(4):122-126.
[13]	郭钢,薛小佳,李楷,等. 压裂液存留液对致密油储层渗吸替油效果的影响[J]. 钻井液与完井液,2016, 33(6):121-126. GUO Gang,XUE Xiaojia,LI Kai,et al.Effect of retained fracturing fluid on the imbibition oil displacement effciency of tight oil reservoir[J].Drilling Fluid & Completion Fluid,2016,33(6):121-126.