一种新型乳化胶凝酸的制备与性能评价

王旭; 贾文峰; 任倩倩; 王宝峰; 蒋廷学; 陈作; 柯扬船

doi:10.3969/j.issn.1001-5620.2017.05.021

一种新型乳化胶凝酸的制备与性能评价

doi: 10.3969/j.issn.1001-5620.2017.05.021

王旭^1,2,3,
贾文峰^1,2, ,,
任倩倩^1,2,3,
王宝峰^1,2,
蒋廷学^1,2,
陈作^1,2,
柯扬船³

1. 页岩油气富集机理与有效开发国家重点实验室, 北京 100101;
2. 中国石化石油工程技术研究院, 北京 100101;
3. 中国石油大学(北京), 北京 102249

基金项目:

中国石化石油工程技术服务有限公司重点项目“多重乳化酸体系研究”（SG16-38K）；中石化油田事业部项目“新型乳化胶凝酸在碳酸盐岩储层酸压先导试验”（YTXD-16014）；国家重大科技专项课题2“彭水地区高效钻井及压裂工程工艺技术优化技术”（2016ZX05061-010））；国家自然科学基金重大项目“页岩地层动态随机裂缝控制机理与无水压裂理论”（51490653）。

详细信息

作者简介:
王旭,1992年生,中国石油大学(北京)在读研究生。E-mail:945626709@qq.com。

通讯作者:
贾文峰,E-mail:jiawf@iccas.ac.cn

中图分类号: TE357.12
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- 被引次数: 0
出版历程
- 收稿日期: 2017-05-30
- 刊出日期: 2017-09-30

Development and Evaluation of a New Emulsified Gelled Acid

WANG Xu^1,2,3,
JIA Wenfeng^{1,2
, ,},
REN Qianqian^1,2,3,
WANG Baofeng^1,2,
JIANG Tingxue^1,2,
CHEN Zuo^1,2,
KE Yangchuan³

1. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 100101;
2. Sinopec Research Institute of Petroleum Engineering, Beijing 100101;
3. China University of Petroleum, Beijing 102249

摘要

摘要: 在碳酸盐岩储层酸压施工中，胶凝酸作为常用缓速酸体系，具有良好缓速效果和降摩阻效果，但不能满足高温储层深度酸化要求。因此，需要研发耐温和缓速性能更加优良的缓速酸液体。乳化酸具有滤失量小、缓速性能好、能产生较长酸蚀裂缝的特点，其高温稳定性差限制了进一步推广应用。本研究将胶凝酸和乳化酸合二为一，研发了一种新型双重缓速酸液体系——乳化胶凝酸（EGA）。室内实验确定了耐温120℃乳化胶凝酸配方与制备工艺，并对乳化胶凝酸体系的稳定性能、耐温性能、高温流变性能、酸岩反应等进行了评价研究。乳化胶凝酸室温下稳定放置48 h无分层破乳现象，120℃下可稳定2 h以上，120℃、170 s^-1下剪切80 min后黏度大于40 mPa·s，酸岩反应动力学实验表明乳化胶凝酸酸岩反应速率小于乳化酸及胶凝酸。说明乳化胶凝酸体系具有良好的耐温性能、耐温耐剪切性能、双重缓速性能，具有良好的推广应用前景。
- 乳化胶凝酸 /
- 制备 /
- 性能评价 /
- 缓蚀性能 /
- 缓速性能
Abstract: Gelled acids have commonly been used as retarded acids in acid fracturing carbonate reservoirs. Gelled acids have good retarding and friction reducing performance, they cannot satisfy the requirements of deep acidification of high temperature reservoirs though, and a retarded acid with high temperature resistance and better retarding performance is required. Emulsified acids have these characteristics such as low filter loss, good retarding performance, and capable of generating long acid-eroded fractures, it is the poor high temperature stability of emulsified acids limits their application in acid fracturing operations. In this study, a gel acid and an emulsified acid were mixed together in the development of a new retarded acid, the so-called emulsified gelled acid (EGA). The formula and preparation method of an EGA resistant to 120℃ were determined through laboratory experiment. The stability, temperature resistance, high temperature rheology and acid-rock reaction have been evaluated. It showed that the EGA prepared was stable at room temperature, no segregation and demulsification have ever been observed after standing 48 hours. The EGA can maintain stable for 2 hours under 120℃. The viscosity of the EGA after sheared 80 min under 120℃ and 170 s^-1 was 40 mPa·s. Kinetics of the reaction between the EGA and rocks indicated that the reaction rate of EGA with rocks was less than that of emulsified acid and gelled acid with rocks, respectively. These data demonstrate that EGA has good high temperature resistance, double retarding performance, and is worth popularizing.
- Emulsified gelled acid /
- Prepare /
- Performance evaluation /
- Corrosion inhibitive capacity /
- Retarding performance

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参考文献(16)

[1]	李春杰,段吉国,尹仲英,等. 酸化含水油井的油外相乳化酸的研制和应用[J]. 大庆石油学院学报,2000, 24(3):37-39. LI Chunjie,DUAN Jiguo,YIN Zhongying,et al. Development and application of an acid/oil type emulsified acid to acidizing treatment of production well[J]. Journal of Daqing Petroleum Institute,2000, 24(3):37-39.
[2]	刘炜,张斌,常启新,等. 胶凝酸体系的性能研究及应用[J]. 精细石油化工进展,2013,14(1):12-14. LIU We i,ZHANG Bin,CHANG Qixin,et al. Performances and application of gelled acid system[J]. Advances in Fine Petrochemicals,2013,14(1):12-14.
[3]	张杰. 乳化酸酸液体系配方研究进展[J]. 应用化工, 2012,41(4):685-688. ZHANG Jie. Research progress of formula for emulsified acid fluid system[J].Applied Chemical Industry,2012, 41(4):685-688.
[4]	刘炜, 熊楠, 吴志鹏, 等. 缓速酸种类及乳化酸应用研究进展[J]. 精细石油化工进展,2010,11(9):12-15. LIU Wei,XIONG Nan,WU Zhipeng,et al. Review on types of retarded acid and application of emulsifionacid[J]. Advances in Fine Petrochemicals,2010,11(9):12-15.
[5]	王冬梅,张秋红,刘建梅,等. 酸液稠化剂TP-1的合成及性能[J]. 石油钻采工艺,2005,27(S1):72-73. WANG Dongmei,ZHANG Qiuhong,LIU Jianmei,et al. Synthetiseand performance of acid densifier TP-1[J]. Oil Drilling & Production Technology,2005,27(S1):72-73.
[6]	LEWIS R N. Properties and early field results of a liquid gelling agent for acid[R].SPE 7834,1978.
[7]	贾文峰,陈作,眭世元,等. 实验及模拟研究两性疏水缔合聚合物增黏机理[J]. 科学技术与工程,2017, 17(3):213-217. JIA Wenfeng,CHEN Zuo,SUI Shiyuan,et al. Thickeningmechanism of amphoteric hydrophobically associating polymerby experimental study and simulation[J].Science Technologyand Engineering, 2017,17(3):213-217.
[8]	车天勇,黄志宇. 抗高温乳化酸体系的实验室研制[J]. 石油与天然气化工,2004,33(4):274-277. CHE Tianyong,HUANG Zhiyu. Laboratory research of a new emulsified acid system[J].Chemical Engineering of Oil and Gas,2004,33(4):274-277.
[9]	陈红军,郭建春,赵金洲,等.W/O乳化酸体系稳定性实验研究[J]. 石油与天然气化工,2005,34(2):118-121. CHEN Hongjun, GUO Jianchun, ZHAO Jinzhou,et al. The research for the stability of W/O emulsifiedacid[J]. Chemical Engineering of Oil and Gas,2005,34(2):118-121.
[10]	周明,江万雄,陈欣,等. 一种乳化缓速酸解堵体系研究及室内评价[J]. 石油与天然气化工,2016,45(2):72-76. ZHOU Ming,JIANG Wanxiong,CHEN Xin,et al. Investigation and laboratory evaluation of an emulsification retarted acid solution system[J]. Chemical Engineering of Oil and Gas,2016,45(2):72-76.
[11]	陈磊,冯崇,宁雯宇,等. 外部因素对稠油乳状液稳定性的影响研究[J]. 当代化工,2014,43(5):691-693. CHEN Lei,FENG Chong,NING Wenyu,et al. Influence of external factors on heavy oil emulsion stability[J]. Contemporary Chemical Industry,2014,(5):691-693.
[12]	秦少雄,傅和清,张心亚,等. 乳液聚合过程中搅拌对产品质量的影响[J]. 现代涂料与涂装,2004,(4):42-43. QIN Shaoxiong,FU Heqing,ZHANG Xinya,et al. Influence of agitation during emulsion polymerization on product quality[J]. Modern Paint and Finishing,2004 , (4):42-43.
[13]	袁青,李文杰,毕研霞,等. 新型耐温乳化酸的室内研制[J]. 石油化工应用,2015,34(1):111-114. YUAN Qing,LI Wenjie,BI Yanxia,et al. The experimental research of new emulsifiedacid with high temperature resistance[J].Petrochemical Industry Application,2015,34(1):111-114.
[14]	冯英,陈建波,李建波,等. 乳化酸配方室内研究[J]. 钻采工艺,2004,27(6):91-92. FENG Ying,CHEN Jianbo,LI Jianbo,et al. Laboratory study on emulsified acid formulation[J].Drilling & Production Technology,2004,27(6):91-92.
[15]	张谦, 陈大钧, 熊颖, 等. 抗高温乳化酸酸化技术的研究与应用[J]. 钻井液与完井液,2008,25(2):51-53. ZHANG Qian,CHEN Dajun,XIONG Ying,et al. The studies and application of acidification technology of high temperature emulsified acids[J].Drilling Fluid & Completion Fluid,2008,25(2):51-53.
[16]	原励,熊颖,蒋永,等.一种高温乳化酸的研制与评价[J]. 石油与天然气化工,2014,43(5):521-524. YUAN Li,XIONG Ying,JIANG Yong,et al. Development and evaluation of high temperature emulsified acid[J].Chemical Engineering of Oil and Gas, 2014,43(5):521-524.