水性丙烯酸树脂在油包水钻井液中的作用

黄贤斌; 蒋官澄; 邓正强

doi:10.3969/j.issn.1001-5620.2017.02.005

水性丙烯酸树脂在油包水钻井液中的作用

doi: 10.3969/j.issn.1001-5620.2017.02.005

黄贤斌^1,2,
蒋官澄^1,2,
邓正强^1,2

1. 中国石油大学(北京)石油工程学院教育部重点实验室, 北京 102249;
2. 中国石油大学(北京)油气资源与探测国家重点实验室, 北京 102249

基金项目:

国家自然科学创新研究群体项目"复杂油气井钻井与完井基础研究"（51221003）；国家"863"项目"海上大位移井水平井钻井液关键技术研究"（2012AA091502）；国家"863"项目"致密气藏高效钻井技术研究"（2013AA064803）；国家自然科学石油化工联合基金重点支持项目"页岩气钻探中的井壁稳定及高效钻完井基础研究"（U1262201）。

详细信息

作者简介:
黄贤斌,1988年生,在读博士研究生,国家公派加拿大阿尔伯塔大学联合培养在读博士,主要从事油基钻井液及油基钻井液处理剂研发等研究。E-mail:634640236@qq.com。

中图分类号: TE254.4
计量
- 文章访问数: 497
- HTML全文浏览量: 160
- PDF下载量: 143
- 被引次数: 0
出版历程
- 收稿日期: 2016-12-11
- 刊出日期: 2017-03-31

Application of Aqueous Acrylic Resin in Invert Emulsion Drilling Fluids

1. MOE Key Laboratory of Petroleum Engineering, China University of Petroleum, Beijing 102249;
2. State Key Laboratory of Oil and Gas Resource and Prospecting, China University of Petroleum, Beijing 102249

摘要

摘要: 现阶段广泛使用的油基钻井液降滤失剂沥青类和腐植酸类产品存在增黏严重、加量大、降滤失效果有限或抗温性能不理想等缺点。利用乳液聚合的方法，以苯乙烯、丙烯酸丁酯和丙烯酸作为单体，合成了一种水性丙烯酸树脂材料WAR，并使用红外光谱对其结构进行表征。热重分析表明单剂抗温可达237℃（失重2%）以上。分别在常规油基钻井液和无土相油基钻井液体系中，从乳液稳定性、流变性、降滤失性、封堵性和抗温性5个方面来综合评价WAR。实验结果表明：水性丙烯酸树脂对稳定乳液有非常积极的作用，放置24 h后基浆乳化率依然可达100%；WAR对油基钻井液流变性影响较小，具有突出的降滤失、封堵和抗温性能：180℃高温高压滤失量可以降至5 mL之内，且滤饼致密；180℃老化16 h后正向封堵率可达75%以上，反向封堵率可达70%以上；与氧化沥青进行对比实验表明，水性丙烯酸树脂综合性能优于氧化沥青。此外，文中分析了水性丙烯酸树脂在油包水钻井液中的作用机理。
- 降滤失剂 /
- 油基钻井液 /
- 水性丙烯酸树脂 /
- 乳液稳定
Abstract: Asphaltene and humic acid products widely used in oil base muds (OBMs) have deficiencies such as seriously viscosifying the OBMs, high concentration requirement, limited filtration control performance and poor high temperature stability. An aqueous acrylic resin, WAR, was developed for use in OBMs to solve these deficiencies. WAR was synthesized with monomers such as styrene, butyl acrylate, and acrylic acid through emulsion polymerization, and was characterized with IR spectrometry. WAR remained stable at 237℃ (weight loss by 2%), as proved by thermogravimetric analysis. WAR was evaluated in laboratory for its emulsion stability, rheology, filtration control performance, plugging capacity and high temperature stability both in conventional OBMs and clay-free OBMs. It was shown that WAR performed positively in stabilizing the properties of emulsions. Emulsions treated with WAR remained their whole emulsibility after 24 h of standing. WAR had very slight effect on the rheology of OBMs, and appreciable filtration control ability, plugging capacity and high temperature stability. HTHP filter loss tested at 180℃ was less than 5 mL, with the mud cake being dense. After aging at 180° C for 16 h, the percentage of forward plugging was more than 75%, and that of backward plugging was moer than 70%. Compared with oxidized asphalt, the aqueous acrylic resin had better overall performance as an OBM additive. The working mechanism of the aqueous acrylic resin in invert emulsion drilling fluids is also analyzed in this paper.
- Aqueous acrylic resin /
- Acrylic resin /
- Additive for oil base mud /
- Emulsion stabilization

HTML全文

参考文献(17)

[1]	张群正, 孙霄伟, 李长春, 等. 降滤失剂H-QA的制备与性能评价[J]. 石油钻采工艺, 2013, 35(1):40-44. ZHANG Qunzheng, SUN Xiaowei, LI Changchun, et al. Synthesis and performance test of fluid loss additive H-QA[J]. Oil Drilling & Production Technology, 2013, 35(1):40-44.
[2]	韩子轩, 蒋官澄, 李青洋, 等. 新型合成基钻井液降滤失剂合成及性能评价[J]. 东北石油大学学报, 2014, 38(5):86-92. HAN Zixuan, JIANG Guancheng, LI Qingyang, et al. The synthesis and performance evaluation of a new filter reducer for synthetic-based drilling fluid[J]. Journal of Northeast Petroleum University, 2014, 38(5):86-92.
[3]	BISHOP M D, RENEAU W P, EVANS F E, et al. Additives for oil-based drilling fluids:U.S. Patent 9, 328,280[P]. 2016-5-3.
[4]	ASTON M, MIHALIK P, TUNBRIDGE J, et al. Towards zero fluid loss oil based muds[C].SPE Annual Technical Conference and Exhibition. Society of Petroleum Engineers, 2002.
[5]	GUO H, VONCKEN J, OPSTAL T, et al.Investigation of the mitigation of lost circulation in oil-based drilling fluids by use of gilsonite[J].SPE Journal, 2014, 19(06):1184-1191.
[6]	冯萍,邱正松,曹杰. 交联型油基钻井液降滤失剂的合成及性能评价[J]. 钻井液与完井液, 2012, 29(1):9-11. FENG Ping, QIU Zhengsong, CAO Jie. Synthesis and evaluation of novel cross-linked fluid loss agent for oil base drilling fluid[J]. Drilling Fluid & Completion Fluid, 2012, 29(1):9-11.
[7]	高海洋,黄进军,崔茂荣,等. 新型抗高温油基钻井液降滤失剂的研制[J]. 西南石油学院学报, 2000, 22(4):61-64. GAO Haiyang, HUANG Jinjun, CUI Maorong, et al. Research on a new anti-high temperature fluid loss additive of oil-base drilling fluid[J]. Journal of Southwest Petroleum Institute, 2000, 22(4):61-64.
[8]	赵泽,王茂功,蒋官澄, 等. 国内外油基钻井液降滤失剂研究进展[J]. 应用化工, 2008, 43(6):1112-1115. ZHAO Ze, WANG Maogong, JIANG Guancheng, et al. Development on fluid loss additives of oil-based drilling fluids at home and abroad[J]. Applied Chemistry Industry, 2008, 43(6):1112-1115.
[9]	DEVILLE J P. Method for enhancing stability of oil based drilling fluids at high temperatures:U.S. Patent 8,062, 997[P]. 2011-11-22.
[10]	MILLER J J, MAGHRABI S S, WAGLE V B, et al. Suspension characteristics in invert emulsions:U.S. Patent 8,691,733[P]. 2014-4-8.
[11]	PICKERING S U. CXCVI.-emulsions[J]. Journal of the Chemical Society, Transactions, 1907, 91:2001-2021.
[12]	BINKS B P, FLETCHER P D I. Particles adsorbed at the oil-water interface:A theoretical comparison between spheres of uniform wettability and" Janus" particles[J]. Langmuir, 2001, 17(16):4708-4710.
[13]	MONFREUX-GAILLARD N, PERRIN P, LAFUMA F, et al. Reversible emulsions stabilized by amphiphilic polymers and application to drilling fluid:U.S. Patent 7, 262,152[P]. 2007-8-28.
[14]	叶丹滢. 丙烯酸酯核壳乳液成膜机理及涂膜性能的研究[D]. 北京:北京化工大学,2009. YE Danying. Mechanism of film formation of acrylic core-shell latex[D]. Beijing:Beijing University of Chemical Technology, 2009.
[15]	BANKER G S. Film coating theory and practice[J]. Journal of Pharmaceutical Sciences, 1966,55(1):81-89.
[16]	王晓明. 水性丙烯酸树脂涂料的研究[D]. 南京:南京航空航天大学,2012. WANG Xiaoming. Study of water-borne acrylic resin coating[D]. Nanjing:Nanjing University of Aeronautics and Astronautics, 2012.
[17]	CHATTOPADHYAY D K, ROHINI KUMAR D B, SREEDHAR B, et al. Thermal stability and dynamic mechanical behavior of acrylic resin and acrylic melamine coatings[J]. Journal of Applied Polymer Science, 2004, 91(1):27-34.