一种固井用腐植酸-AMPS/DMAM/FA接枝共聚物降失水剂

宋维凯; 王清顺; 侯亚伟; 汪蕾; 田野; 赵军

doi:10.3969/j.issn.1001-5620.2017.01.019

一种固井用腐植酸-AMPS/DMAM/FA接枝共聚物降失水剂

doi: 10.3969/j.issn.1001-5620.2017.01.019

中海油田服务股份有限公司油田化学研究院, 河北燕郊 065201

基金项目:

中海油服重点科研项目“泰国湾区块260℃水泥浆研究”（YHB14YF007）的部分内容。

详细信息

作者简介:
宋维凯,工程师,1982年生,2007年毕业于长江大学石油工程专业,现在从事油井水泥添加剂和固井水泥浆体系的研究工作。电话(010)84522115;E-mail:songwk@cosl.com.cn。

中图分类号: TE256.6
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出版历程
- 收稿日期: 2016-11-17
- 刊出日期: 2017-01-31

AMPS/DMAM/FA-A Graft Copolymer Humic Acid Fluid Loss Reducer for Well Cementing

Oilfield Chemistry R & D Institute, COSL, Yanjiao, Hebei 065201

摘要

摘要: 采用自由基聚合法将AMPS、N，N-二甲基丙烯酰胺（DMAM）、反丁烯二酸（FA）进行接枝共聚，在AMPS∶DMAM∶FA为1∶0.38∶0.08，单体总量与腐值酸钠的质量比为1∶0.2、引发温度为60℃，单体溶液的pH为7的条件下，合成了一种抗高温油井水泥降失水剂G85L，为黑色黏稠液体，固含量为20%。通过单体残留分析与红外表征证明了合成产物为接枝共聚物，并通过热重分析证明该产品抗温达265℃。参考API RP 10B-2 2013进行实验，评价了该产品在水泥浆中的各项性能，结果表明，该产品不仅在中低温有较好的控制失水能力，当加量为4%时可以将API失水量降至40 mL，而且在高温条件下也具有较强的控制失水能力，200℃下失水量可以控制在50 mL以内，并且对水泥浆的稠化时间、抗压强度无副作用，与多种水泥浆体系配伍性好，是一种普适性优良的抗高温产品。
- 固井 /
- 降失水剂 /
- 腐植酸 /
- 接枝共聚 /
- 高温
Abstract: A high temperature cement slurry fluid loss reducer, G85L, was synthesized with 2-acrylamido-2-methyl propane sulfonic acid (AMPS), N,N-dimethylacrylamide (DMAM) and fumaric acid (FA) through radical polymerization under the following conditions:AMPS:DMAM:FA=1:0.38:0.08, mass ratio of total monomers to sodium humate=1:0.2, initiation temperature 60℃, and pH (of the monomer solution)=7. G85L was a viscous black liquid containing 20% solids. Analysis of the residual monomers and IR characterization showed that the synthesized product was a graft copolymer, and thermogravimetric analysis indicted that the property of the G85L remained stable at 265℃. Filtration experiment (done in accordance with API RP 10B-2 2013) demonstrated that addition of 4%G85L reduced filter loss of cement slurry to 40 mL at low temperatures, and to less than 50 mL at 200℃. No evidences of side effect of G85L on the thickening time and compressive strength of cement slurry have been observed during experiments. G85L shows good compatibility with many cement slurry formulations and is a universal high temperature filter loss reducer for cement slurries.
- Well cementing /
- Filter loss reducer /
- Humic acid /
- Graft copolymerization /
- High temperature

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参考文献(9)

[1]	刘景丽, 郝惠军, 李秀妹,等. 油井水泥降失水剂接枝改性聚乙烯醇的研究[J]. 钻井液与完井液,2014,31(5):78-80. LIU Jingli, HAO Huijun, LI Xiumei, et al. Study on graft modified PVA-A cement slurry fluid loss reducer[J]. Drilling Fluid & Completion Fluid, 2014, 31(5):78-80.
[2]	王清顺. 油井水泥用合成聚合物降失水剂现状及发展趋势[J]. 钻井液与完井液,2007,24(2):67-69. WANG Qingshun. Present situation and development trend of synthetic polymer fluid loss additive for oil well cement[J]. Drilling Fluid & Completion Fluid, 2007,24(2):67-69.
[3]	于永金, 刘硕琼, 刘丽雯, 等. 高温水泥浆降失水剂DRF-120L的制备及评价[J]. 石油钻采工艺,2011,33(3):24-27. YU Yongjin, LIU Shuoqiong, LIU Liwen, et al. Preparation and evaluation of high temperature cement slurry loss reduction additive DRF-120L[J]. Oil Drilling & Production Technology,2011,33(3):24-27.
[4]	刘丹丹,邓何,郭庆时,等. 腐植酸在油田钻井液中的应用[J]. 腐植酸,2012(3):11-16. LIU Dandan, DENG He, GUO Qingshi, et al.The application of humic acid in oil field drilling fluids[J]. Humic Acid,2012 (3):11-16.
[5]	史博,易菊珍,张黎明. 腐植酸类功能材料的研究进展[J]. 腐植酸,2015(3):1-7. SHI Bo, YI Juzhen, ZHANG Liming.The research progress on functional materials based on humic acids[J]. Humic Acid, 2015 (3):1-7.
[6]	GAO L J, WANG S Q, ZHAO X F. Synthesis and characterization of agricultural controllable humic acid superabsorbent[J]. Journal of Environmental Sciences, 2013(25):69-76.
[7]	TANG Y B, CHEN F Y, YE W, et al. A novel rectoritebased composite adsorbent for removing heavy metal ions and PAHs[J]. Journal of Chemical and Pharmaceutical Research, 2014, 6(8):102-111.
[8]	郝延顺, 杨决算, 邓倩珊, 等. NaHm/AMPS/AM/AA接枝共聚物降滤失剂的合成[J]. 广东化工, 2014(15):12-13. HAO Yanshun, YANG Juesuan, DENG Qianshan, et al. Synthesis of NaHm/AMPS/AM/AA graft copolymer fluid loss additive[J]. Guangdong Chemical Industry, 2014 (15):12-13.
[9]	王中华. 腐植酸接枝共聚物超高温钻井液降滤失剂合成[J]. 西南石油大学学报(自然科学版),2010,32(4):149-155. WANG Zhonghua.Synthesis of humic acid graft copolymer drilling fluid loss additive in ultra high temperature[J]. Journal of Southwest Petroleum University(Science & Technology Edition),2010,32(4):149-155.