Study and Application of Scale Inhibitive Solids-free Workover Fluid
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摘要: 为解决氯化钙型修井液与碳酸氢钠型地层水结垢的问题,通过对抑垢剂、缓蚀助排剂、防膨剂、加重剂等外加剂的研究与优选,研制出以氯化钙液体为基液、密度为1.20~1.55 g/cm3 的BH-1 抑垢型无固相修井液产品。经室内评价证实,该产品与碳酸氢钠型地层水配伍,对黏土矿物防膨率达97%,对油管钢的腐蚀速率与淡水相当,表面张力比淡水低43.8%,凝固点在-10~-55 ℃之间,与原油配伍,适用于硫酸钠、碳酸氢钠、氯化钙、氯化镁4 种类型地层水的油气水井压井作业。产品在库5-10 井等现场应用4 井次,均获得成功,显示出BH-1 抑垢型无固相修井液具有良好的应用前景。Abstract: Calcium chloride workover fluid was modified through optimization of additives used in the workover fluid, such as scale inhibitor, corrosion inhibitive cleanup additive, swelling inhibitor and weighting agent, in an effort to solve the problem of scaling caused by calcium chloride workover fluid and sodium bicarbonate formation water. As a result of the modification, a calcium chloride solids-free workover fluid of 1.20-1.55 g/cm3 was developed. By treatment with BH-1, a scale inhibitor, the workover fluid is compatible with sodium bicarbonate formation water. It is highly efficient in clay inhibition, and has rates of corrosion to tubing steel that are equivalent to fresh water. This workover fluid has surface tension that is less than 43.8% that of fresh water, and freezing point between -10℃--55℃. It is compatible with crude oil, and is suitable for use in wells having sodium sulphate water, sodium bicarbonate water, calcium chloride water and magnesium chloride water. This workover fluid had been successfully applied in four wells.
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Key words:
- Scale inhibition /
- Solids free /
- Workover fluid /
- Formation water
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