液体型妥尔油沥青酰胺树脂的合成及降滤失性能评价

赵冲; 张现斌; 邱正松; 钟汉毅; 张健; 赵颖; 高宁

doi:10.12358/j.issn.1001-5620.2021.05.012

液体型妥尔油沥青酰胺树脂的合成及降滤失性能评价

doi: 10.12358/j.issn.1001-5620.2021.05.012

赵冲^1,,
张现斌^{2, 3},
邱正松^1, ,,
钟汉毅¹,
张健^{2, 3},
赵颖^{2, 3},
高宁³

1.
中国石油大学（华东）石油工程学院, 山东青岛 266580
2.
天津市复杂条件钻井液企业重点实验室, 天津 300280
3.
中国石油集团渤海钻探工程有限公司, 天津 300280

基金项目: 中国石油天然气集团公司重大科技专项“油田用化工新材料产品开发”（2020E-28）；天津市科技计划项目“非常规和深层油气资源开发钻井液关键技术研究”（19PTSYJC00120）资助

详细信息

作者简介:
赵冲，1974年生，在读博士研究生，主要从事钻井液新技术研究工作。E-mail：zhaochong@cnpc.com.cn

通讯作者:
邱正松，E-mail：qiuzs63@sina.com

中图分类号: TE254.4
计量
- 文章访问数: 606
- HTML全文浏览量: 256
- PDF下载量: 55
- 被引次数: 0
出版历程
- 收稿日期: 2021-04-21
- 录用日期: 2020-03-11
- 网络出版日期: 2021-11-30
- 刊出日期: 2021-09-30

Synthesis of Liquid Tall Oil Asphalt Amide Resin and Evaluation of Its Filtration Control Performance

ZHAO Chong^1
,,
ZHANG Xianbin^{2, 3},
QIU Zhengsong^{1
, ,},
ZHONG Hanyi¹,
ZHANG Jian^{2, 3},
ZHAO Ying^{2, 3},
GAO Ning³

1.
School of Petroleum Engineering, China University of Petroleum (East China), Tsingtao, Shandong 266580
2.
Tianjin Key Laboratory of Complicated Conditions Drilling Fluids, Tianjin 300280
3.
CNPC Bohai Drilling Engineering Company Limited, Tianjin 300280

摘要

摘要: 为减少传统沥青类降滤失剂对环境的影响，并提高油基钻井液的高温封堵能力，以天然植物油加工尾料妥尔油沥青为原料，采用顺丁烯二酸酐和多元有机胺依次对其进行改性，所得产物溶于环保溶剂油，制备得到液体降滤失剂BZ-FLA。红外光谱分析和核磁共振分析表明，最终产物BZ-FLA主要为顺丁烯二酸酐改性的树脂酸和多元有机胺缩合而成的交联型妥尔油沥青酰胺树脂。分别评价液体降滤失剂在典型油基钻井液中以及无土相油基钻井液中的性能，结果表明，液体降滤失剂BZ-FLA抗温达180 ℃，加量为0.75%～1.0%时可将钻井液高温高压滤失量降至4.0 mL以内，与常规沥青降滤失剂加量3%的效果相当。BZ-FLA与沥青类和褐煤类降滤失剂复合使用，可进一步提高油基钻井液的封堵能力。BZ-FLA在无土相油基钻井液中降滤失效果同样显著。
- 油基钻井液 /
- 液体降滤失剂 /
- 妥尔油沥青 /
- 酰胺树脂 /
- 无土相 /
- 封堵
Abstract: To minimize the negative effects of conventional asphalt filter loss reducers on the environment and to enhance the plugging capacity of oil based drilling fluids at elevated temperatures, a liquid filter loss reducer BZ-FLA was produced by stepwise modifying a tall oil asphalt (a tail from natural oil processing) with maleic anhydride (MA) and polyamine, and then dissolving the product of the modification in an environmentally friendly solvent oil. IR spectroscopy and NMR analyses have proved that the final product of the aforementioned reaction, BZ-FLA, is a crosslinking tall oil asphalt amide resin which is a condensate of MA modified resin acid and polyamines. Evaluation of the performance of a typical oil based drilling fluid and a clay-free oil based drilling fluid both treated with BZ-FLA showed that BZ-FLA functions well at temperatures as high as 180 ℃. Filter loss of the typical oil based drilling fluid treated with 0.75%-1.0% BZ-FLA is less than 4.0 mL, comparable to the filtration control performance of 3% conventional asphalt filter loss reducer. Oil based drilling fluids treated with BZ-FLA, asphalt and lignite filter loss reducers exhibit enhanced plugging capacity. BZ-FLA is also equally effective in reducing filtration rate of clay-free oil based drilling fluids.
- Oil based drilling fluid /
- Liquid filter loss reducer /
- Tall oil asphalt /
- Amide resin /
- Clay-free /
- Plug

HTML全文

图 1 液体降滤失剂BZ-FLA的红外光谱分析

下载: 全尺寸图片幻灯片

图 2 液体降滤失剂BZ-FLA产品及中间产物的¹H-NMR图谱

下载: 全尺寸图片幻灯片

图 3 0.75%BZ-FLA与不同常规降滤失剂复配后的性能

下载: 全尺寸图片幻灯片

图 4 不同降滤失剂实验浆高温高压滤饼

下载: 全尺寸图片幻灯片

表 1 液体降滤失剂BZ-FLA加量对油基钻井液性能的影响

BZ-FLA/ %	实验条件	PV/ mPa·s	YP/ Pa	φ₆/φ₃	Gel/ Pa/Pa	FL_HTHP/ mL	h/ mm	ES/ V
0	热滚前	34	3.5	7/5	2.0/4.5			538
0	热滚后	40	4.5	9/8	4.0/5.0	9.6	4.0	438
0.50	热滚前	30	3.0	4/3	2.0/3.0			536
0.50	热滚后	42	7.0	8/7	4.0/5.0	3.6	1.0	729
0.75	热滚前	35	4.0	5/4	2.0/3.0			592
0.75	热滚后	45	10.0	11/9	4.5/5.0	3.6	1.0	764
1.0	热滚前	36	4.0	6/5	3.0/4.0			637
1.0	热滚后	46	12.0	13/11	6.0/8.0	2.8	1.0	964
1.5	热滚前	38	4.0	6/5	3.0/4.5			649
1.5	热滚后	73	32.5	25/20	10.0/20.0	2.4	1.0	1379
3.0	热滚前	40	5.0	7/6	3.0/4.5			674
3.0	热滚后	80	39.0	27/26	14.0/24.0			1429
3.0*	热滚前	38	2.0	6/5	3.0/5.0			721
3.0*	热滚后	51	7.0	12/11	5.5/6.0	4.6	2.5	469
注：*为沥青降滤失剂；h为泥饼厚度；热滚条件为150 ℃、16 h

下载: 导出CSV

表 2 液体降滤失剂BZ-FLA抗温能力评价

BZ-FLA/ %	T/ ℃	PV/ mPa·s	YP/ Pa	φ₆/φ₃	Gel/ Pa/Pa	FL_HTHP/ mL	h/ mm	ES/ V
0	常温	34	3.5	7/5	2.0/4.5			538
	150	40	4.5	9/8	4.0/5.0	9.6	4.0	438
	180	42	3.0	5/4	2.5/4.0	14.8	5.0	409
	200	51	2.0	3/2	1.5/2.0	28.6	6.5	389
0.75	常温	35	4.0	5/4	2.0/3.0			592
	150	45	10.0	11/9	4.5/5.0	3.6	1.0	764
	180	48	6.0	7/6	3.5/6.0	7.6	1.0	680
	200	38	3.0	4/3	2.0/8.0	22.0	1.5	587
1.0	常温	36	4.0	6/5	3.0/4.0			637
	150	46	12.0	13/11	6.0/8.0	2.8	1.0	964
	180	48	8.0	9/8	4.0/6.0	4.8	1.0	865
	200	43	4.0	5/4	2.5/10.0	16.8	1.5	768
3.0*	常温	38	2.0	6/5	3.0/5.0			721
	150	51	7.0	12/11	5.5/6.0	4.6	2.5	469
	180	60	3.5	5/4	3.0/3.5	8.8	3.0	427
	200	65	2.0	3/2	1.5/2.0	15.6	5.0	357
注：*为沥青降滤失剂；h为泥饼厚度

下载: 导出CSV

表 3 BZ-FLA高温高压渗透性封堵效果评价

降滤失剂	FL_HPHT/ mL（150 ℃）		FL_HPHT/ mL（180 ℃）
降滤失剂	170-55型砂盘	170-53型砂盘	170-55型砂盘	170-53型砂盘
0	5.6	7.6	6.8	8.6
0.75% BZ-FLA	2.4	3.2	2.8	3.2
1.0% BZ-FLA	2.2	3.0	2.4	2.8
3.0%沥青类	2.4	3.4	2.8	3.0
3.0%有机褐煤	2.8	3.6	3.0	3.6
0.75% BZ-FLA+ 3%沥青	1.2	2.0	2.2	2.4
0.75% BZ-FLA+ 3%有机褐煤	1.4	2.2	2.2	2.4
注：测试压力为6.9 MPa

下载: 导出CSV

表 4 BZ-FLA在高密度油基钻井液中的性能

ρ/ g/cm³	BZ-FLA/ %	T/ ℃	PV/ mPa·s	YP/ Pa	φ₆/φ₃	Gel/ Pa/Pa	FL_HTHP/ mL	ES/ V
2.2	0.75	常温	56.0	13.5	15/14	8.5/11.0		1096
		150	54.0	8.5	8/7	4.0/6.0	3.2	1359
		180	55.0	5.5	6/5	3.0/6.0	4.0	1402
2.2	1.0	常温	58.0	15.5	17/16	8.5/13.0		1245
		150	55.0	10.0	10/8	5.0/6.0	2.8	1365
		180	57.0	6.0	8/6	4.0/5.5	3.8	1564
2.4	0.75	常温	61.0	14.0	15/14	7.5/10.5		1331
		150	55.0	8.0	9/7	5.0/6.5	4.8	1457
		180	52.0	5.0	6/5	3.0/4.0	5.6	1679
2.4	1.0	常温	65.0	15	17/15	8.0/12.0		1386
		150	57.0	8.0	10/9	5.0/7.5	3.8	1498
		180	55.0	4.0	6/5	3.5/5.5	4.8	1708

下载: 导出CSV

表 5 BZ-FLA在无土相油基钻井液中的性能

BZ-FLA/ %	T/ ℃	PV/ mPa·s	YP/ Pa	φ₆/φ₃	Gel/ Pa/Pa	FL_HTHP/ mL	h/ mm	ES/ V
0	常温	55	7.0	7/6	3.5/5.5			1079
	150	46	6.0	6/5	3.5/5.0	8.4	2.5	1016
	180	50	3.0	4/3	2.0/4.0	9.2	3.0	871
1.0	常温	62	7.0	7/6	3.5/6.5			1186
	150	48	7.0	7/6	3.5/7.0	5.6	1.0	1004
	180	52	3.0	4/3	2.0/5.0	6.4	1.0	882
1.5	常温	63	7.5	8/7	4.0/7.0			1267
	150	50	7.0	8/7	4.0/7.0	3.6	1.0	1037
	180	54	4.5	6/5	3.0/6.5	4.0	1.0	967
2.0	常温	66	9.5	10/8	4.5/6.0			1386
	150	53	8.0	9/8	4.0/7.0	3.4	1.0	1128
	180	57	6.0	6/5	3.0/6.0	3.6	1.0	1015
注：h为泥饼厚度

下载: 导出CSV

参考文献(16)

[1]	吴雄军,林永学,宋碧涛,等. 顺北油气田奥陶系破碎性地层油基钻井液技术[J]. 钻井液与完井液,2020,37(6):701-708. doi: 10.3969/j.issn.1001-5620.2020.06.004 WU Xiongjun, LIN Yongxue, SONG Bitao, et al. Oil-base drilling fluid technology for ordovician fractured formation in Shunbei oil and gas field[J]. Drilling Fluid & Completion Fluid, 2020, 37(6):701-708. doi: 10.3969/j.issn.1001-5620.2020.06.004
[2]	王建华,闫丽丽,谢盛,等. 塔里木油田库车山前高压盐水层油基钻井液技术[J]. 石油钻探技术,2020,48(2):29-33. doi: 10.11911/syztjs.2020007 WANG Jianhua, YAN Lili, XIE Sheng, et al. Oil-base drilling fluid technology of Kuqa piedmont high-pressure brine formation in Tarim oilfield[J]. Petroleum Drilling Technology, 2020, 48(2):29-33. doi: 10.11911/syztjs.2020007
[3]	左京杰,张振华,姚如钢,等. 川南页岩气地层油基钻井液技术难题及案例分析[J]. 钻井液与完井液,2020,37(3):294-300. doi: 10.3969/j.issn.1001-5620.2020.03.005 ZUO Jingjie, ZHANG Zhenhua, YAO Rugang, et al. Technical difficulties and case analysis of oil base drilling fluid in shale gas formation in south Sichuan[J]. Drilling Fluid & Completion Fluid, 2020, 37(3):294-300. doi: 10.3969/j.issn.1001-5620.2020.03.005
[4]	YAN, Lili, WANG, Jianhua, ZHANG, Jiaqi, et al. Understanding and research on the drilling fluid technology for shale gas horizontal wells in south Sichuan, China. [C]// IPTC 19587, The International Petroleum Technology Conference, Dhahran, Kingdom of Saudi Arabia, 2020.
[5]	吴江,李龙,任冠龙,等. 海上复杂易垮塌地层高性能油基钻井液研发与应用[J]. 钻井液与完井液,2018,35(5):55-60. doi: 10.3969/j.issn.1001-5620.2018.05.011 WU Jiang, LI Long, REN Guanlong, et al. Development and application of high performance oil base drilling fluid in complex and collapse formation offshore[J]. Drilling Fluid & Completion Fluid, 2018, 35(5):55-60. doi: 10.3969/j.issn.1001-5620.2018.05.011
[6]	王晓军,白冬青,孙云超,等. 页岩气井强化封堵全油基钻井液体系——以长宁-威远国家级页岩气示范区威远区块为例[J]. 天然气工业,2020,40(6):107-114. WANG Xiaojun,BAI Dongqing,SUN Yunchao,et al. Taking Weiyuan block, Weiyuan national shale gas demonstration area- Changning as an example[J]. Natural Gas Industry, 2020, 40(6):107-114.
[7]	程荣超,王建华,闫丽丽,等. 油基钻井液用抗高温树脂类封堵剂的研制[J]. 当代化工研究,2021(5):160-162. CHENG Rongchao , WANG Jianhua, YAN Lili, et al. Development of high temperature resistant resin plugging agent for oil base drilling fluid[J]. Modern Chemical Research, 2021(5):160-162.
[8]	周研,蒲晓林. 油基钻井液用降滤失剂研究现状[J]. 化学世界,2020,61(1):7-15. ZHOU Yan, PU Xiaolin. Research status of fluid loss reducers for oil - based drilling fluids[J]. Chemistry World, 2020, 61(1):7-15.
[9]	黄贤斌, 蒋官澄, 邓正强. 水性丙烯酸树脂在油包水钻井液中的作用[J]. 钻井液与完井液, 2017, 34（2）: 26-32. HUANG Xianbin, JIANG Guancheng, DENG Zhengqiang. The role of waterborne acrylic resin in water-in-oil drilling fluid [J]. Drilling Fluid & Completion Fluid, 2017, 34（2）: 26-32.
[10]	MILLER J J. Metallic soaps of modified tall oil acids: US 20050137093 [P]. 2005.
[11]	MILLER J J. Metallic soaps of modified fatty acids and rosin acids and methods of making and using same: US 20070259790 [P]. 2007.
[12]	宋胜梅,王亚明,谢惠定. 松香结晶原因分析[J]. 林产化学与工业,2001,21(3):77-82. SONG Shengmei, WANG Yaming, XIE Huiding. Analyses on cause of rosin crystallization[J]. Chemistry and Industry of Forest Products, 2001, 21(3):77-82.
[13]	孙金声,黄贤斌,蒋官澄,等. 无土相油基钻井液关键处理剂研制及体系性能评价[J]. 石油勘探与开发,2018,45(4):713-718. SUN Jinsheng, HUANG Xianbin, JIANG Guancheng, et al. Development of key additives for organoclay-free oil-based drilling mud and system performance evaluation[J]. Petroleum Exploration & Development, 2018, 45(4):713-718.
[14]	黄贤斌,蒋官澄,邓正强. 水性丙烯酸树脂在油包水钻井液中的作用[J]. 钻井液与完井液,2017,34(2):26-32. HUANG Xianbin, JIANG Guancheng, DENG Zhengqiang. Application of aqueous acrylic resin in invert emulsion drilling fluids[J]. Drilling Fluid & Completion Fluid, 2017, 34(2):26-32.
[15]	张现斌,赵冲,王伟忠,等. 矿物油基钻井液低剪切流变行为调节技术研究[J]. 中国石油勘探,2015,20(4):63-70. doi: 10.3969/j.issn.1672-7703.2015.04.007 ZHANG Xianbin, ZHAO Chong, WANG Weizhong, et al. Technologies to modify low-shear rate rheology behaviors of mineral oil based drilling fluids[J]. China Petroleum Exploration, 2015, 20(4):63-70. doi: 10.3969/j.issn.1672-7703.2015.04.007
[16]	杨小华. 松香/油脂基二元酸及其聚酰胺固化剂的制备与性能研究[D]. 中国林业科学研究院, 2013 YANG Xiaohua. Synthesis, properties of rosin/oil based diacid and its polyamide curing agents [D]. Chinese Academy of Forestry, 2013.